{"id":109413,"date":"2017-11-02T06:30:15","date_gmt":"2017-11-01T22:30:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=109413"},"modified":"2017-10-31T19:39:13","modified_gmt":"2017-10-31T11:39:13","slug":"adv-mater-%e5%85%b7%e6%9c%89%e9%ab%98%e6%95%88%e6%b0%b4%e6%b0%a7%e5%8c%96%e6%80%a7%e8%83%bd%e7%9a%84%e5%85%ad%e6%96%b9%e7%9b%b8%e6%a2%ad%e5%9e%8b%e8%b5%a4%e9%93%81%e7%9f%bf","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=109413","title":{"rendered":"Adv. Mater. : \u5177\u6709\u9ad8\u6548\u6c34\u6c27\u5316\u6027\u80fd\u7684\u516d\u65b9\u76f8\u68ad\u578b\u8d64\u94c1\u77ff"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u89e3\u6c34\u662f\u751f\u4ea7\u4f5c\u4e3a\u71c3\u6599\u548c\u5316\u5de5\u539f\u6599\u7684\u6c22\u7684\u91cd\u8981\u9014\u5f84\u4e4b\u4e00\u3002\u975e\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u50ac\u5316\u5242\u4f5c\u4e3a\u964d\u4f4e\u8fc7\u7535\u538b\u4e14\u63d0\u9ad8\u80fd\u6e90\u6548\u7387\u7684\u5408\u9002\u5907\u9009\uff0c\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u5174\u8da3\u3002\u7531\u4e8e\u8d64\u94c1\u77ff(\u03b1-Fe2<\/sub>O3<\/sub>)\u5177\u6709\u5ec9\u4ef7\u73af\u4fdd\u3001\u50a8\u91cf\u4e30\u5bcc\u3001\u8010\u8150\u8680\u7b49\u7279\u6027\uff0c\u5229\u7528\u5176\u4f5c\u4e3a\u4ea7\u6c27\u53cd\u5e94(OER)\u7535\u50ac\u5316\u5242\u7684\u524d\u666f\u8bf1\u4eba\u3002\u7136\u800c\uff0c\u03b1-Fe2<\/sub>O3<\/sub>\u7535\u50ac\u5316\u5242\u5f88\u5c11\u5728OER\u4e2d\u4f7f\u7528\u6216\u663e\u793a\u51fa\u8f83\u4f4e\u7684\u8d85\u7535\u52bf(\u03b7)\uff0c\u7a76\u5176\u539f\u56e0\u4e3b\u8981\u662f\u4e24\u65b9\u9762\uff1a1) (110)\u6676\u9762\u5177\u6709\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u4ee4\u4eba\u6ee1\u610f\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f46\u5177\u5907\u4e3b\u8981\u53cd\u5e94\u6d3b\u6027\u6676\u9762(110)\u7684Fe2<\/sub>O3<\/sub>\u6676\u4f53\u7ed3\u6784\u8f83\u5c11\uff1b2)\u5c06\u52a9\u50ac\u5316\u5242\u548c\u63ba\u6742\u7269\u4e0eFe2<\/sub>O3<\/sub>\u590d\u5408\u7684\u540c\u65f6\u4fdd\u7559\u5176\u72ec\u7279\u7684\u6676\u4f53\u6027\u8d28\u3001\u5f62\u8c8c\u548c\u53cd\u5e94\u6d3b\u6027\uff0c\u5c1a\u65e0\u6709\u6548\u4e14\u53ef\u884c\u7684\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u5927\u5b66Zhu Zhonghua\u6559\u6388<\/strong>\u548c\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66Kostya Ostrikov\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u5236\u5907\u51fa\u5177\u6709OER\u53cd\u5e94\u4e3b\u8981\u6d3b\u6027\u9762\u4e14\u6210\u672c\u4f4e\u5ec9\u7684\u516d\u65b9\u76f8\u516b\u9762\u4f53\u8d64\u94c1\u77ff\uff0c\u5e76\u5728Adv. Mater.\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cHexagonal Sphericon Hematite with High Performance for Water Oxidation<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4f5c\u8005\u4f9d\u6b21\u5c06\u8fd1\u539f\u5b50\u7ea7\u7684Ce\u7269\u79cd\u548c\u954d\u7eb3\u7c73\u7c92\u5b50\u5747\u5300\u5206\u5e03\u5230\u8d64\u94c1\u77ff\u7684\u9009\u62e9\u6027\u4f4d\u70b9\uff0c\u7ee7\u800c\u5f15\u53d1\u590d\u6742\u7684\u534f\u540c\u6548\u5e94\uff0c\u63d0\u9ad8\u4e86\u6574\u4f53\u50ac\u5316OER\u7684\u6027\u80fd\u3002\u4e0a\u8ff0\u5ec9\u4ef7\u7684\u516d\u65b9\u76f8\u68ad\u578b\u8d64\u94c1\u77ff(Fe\u224898%)\u53ea\u9700\u8981\u8f83\u4f4e\u8fc7\u7535\u52bf(\u03b7)(0.34 V)\u5373\u53ef\u8fbe\u523010 mA\u00b7cm-2<\/sup>\uff0c\u4f18\u4e8e\u5546\u4e1aIrO2<\/sub>\u548c\u6602\u8d35\u7684\u94b4\u57fa\u3001\u954d\u57fa\u548c\u9502\u57fa\u7535\u50ac\u5316\u5242\u3002
\n [\u81f4\u6b49\uff1a\u5f88\u62b1\u6b49\uff0c\u672a\u80fd\u627e\u5230\u901a\u8baf\u4f5c\u8005Zhu Zhonghua\u7684\u786e\u5207\u4e2d\u6587\u540d\u5b57\uff0c\u5c0f\u7f16\u8868\u793a\u8bda\u631a\u7684\u6b49\u610f\uff01]<\/strong><\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 FC-2\u548c\u5bf9\u7167Fe2<\/sub>O3<\/sub>\u6676\u4f53\u7684\u5f62\u8c8c\u548c\u5fae\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a) FC-2\u548cFe2<\/sub>O3<\/sub>\u7684XRD\u8c31\u7ebf\uff1b<\/p>\n

b,c) \u516b\u9762\u4f53Fe2<\/sub>O3<\/sub>\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

d,e) \u516d\u65b9\u76f8\u68ad\u578bFC-2\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

f) FC-2 \u516d\u65b9\u76f8\u53cc\u9525\u7c92\u5b50\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

g,h) FC-2\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

i,j) FC-2\u6cbf[001]\u548c[100]\u8f74\u7684\u9009\u533a\u7535\u5b50\u884d\u5c04(SAED)\u56fe\u8c31\u3002<\/p>\n

\u56fe2 Ce\u548cNi\u5728FC-2\u6676\u4f53\u4e2d\u7684\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

a) FC-2\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n

b-f) FC-2\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\uff1b<\/p>\n

g,h) FC-2\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe3 FC-2 \u7535\u50ac\u5316\u5242\u7684OER\u6027\u80fd\u4ee5\u53ca\u548c\u5176\u4ed6\u7535\u50ac\u5316\u5242\u7684\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

a) FC-2\u3001Fe-Ce\u3001Fe-Ni\u548cIrO2<\/sub>\u7684OER\u7ebf\u626b\u66f2\u7ebf(O2<\/sub>\u9971\u548c\u76840.1 M KOH\u6eb6\u6db2)\uff1b<\/p>\n

b) FC-2\u3001Fe-Ce\u3001Fe-Ni\u548cIrO2<\/sub>\u7684Tafel\u659c\u7387\uff1b<\/p>\n

c) FC-2\u3001Fe-Ce\u3001Fe-Ni\u548cIrO2<\/sub>\u7684OER\u8d28\u91cf\u6d3b\u6027\u548c\u4f4d\u70b9\u6d3b\u6027(\u03b7 = 0.35 V)\uff1b<\/p>\n

d) FC-2\u7684OER\u7a33\u5b9a\u6027(O2\u9971\u548c\u76840.1 M KOH\u6eb6\u6db2)\u3002<\/p>\n

\u56fe4 FC-2\u901a\u8fc7\u7535\u8377\u91cd\u65b0\u5206\u914d\u548c\u6c27\u7a7a\u4f4d\u6548\u5e94\u589e\u5f3a\u7535\u50ac\u5316\u6d3b\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) FC-2\u548cCeO2<\/sub>\u7684Ce 3d XPS\u5149\u8c31\uff1b<\/p>\n

b) \u6837\u54c1\u754c\u9762\u7684\u6c27\u7a7a\u4f4d\u6d53\u5ea6\uff1b<\/p>\n

c) FC-2\u3001Fe2<\/sub>O3<\/sub>\u548cCeO2<\/sub>\u7684O 1s XPS\u5149\u8c31\uff1b<\/p>\n

d) FC-2\u3001Fe-Ce\u548cFe-Ni\u7684EIS\u8c31\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5229\u7528\u7b80\u5355\u7684\u6eb6\u5242\u70ed-\u6d78\u6e0d\u6cd5\u5236\u5907\u51fa\u4e86Ce-Ni\u4fee\u9970\u516d\u65b9\u516b\u9762\u4f53\u8d64\u94c1\u77ff(FC-2)\uff0c\u76f8\u6bd4\u5bf9\u7167\u7684\u03b1-Fe2<\/sub>O3<\/sub>\u548cIrO2<\/sub>\u50ac\u5316\u5242\uff0c\u5728KOH\u6eb6\u6db2\u4e2dFC-2\u7684OER\u6027\u80fd\u66f4\u52a0\u51fa\u8272\u3002Ce\u7269\u79cd\u548c\u954d\u7eb3\u7c73\u7c92\u5b50\u5747\u5300\u5206\u5e03\u5230\u8d64\u94c1\u77ff\u7684\u9009\u62e9\u6027\u4f4d\u70b9\u5f15\u53d1\u4e86\u590d\u6742\u7684\u534f\u540c\u6548\u5e94\uff0c\u63d0\u9ad8\u4e86\u6574\u4f53\u50ac\u5316OER\u7684\u6027\u80fd\u3002\u4e0a\u8ff0\u5ec9\u4ef7\u7684\u7535\u50ac\u5316\u5242\u5177\u6709\u8f83\u4f4e\u7684\u03b7(0.34 V)\u548c\u5854\u83f2\u5c14\u659c\u7387(45 mV\u00b7dec-1)\uff0c\u4f18\u4e8e\u76ee\u524d\u62a5\u9053\u7684\u975e\u8d35\u91d1\u5c5eOER\u7535\u50ac\u5316\u5242\u3002\u57fa\u4e8e\u516d\u65b9\u76f8\u68ad\u578b\u8d64\u94c1\u77ff(FC-2)\u4e14\u5ec9\u4ef7\u3001\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u7684OER\u7535\u50ac\u5316\u5242\u4e3a\u5f00\u53d1\u4e0d\u540c\u7684\u8d64\u94c1\u77ff\u57fa\u50ac\u5316\u5242\u53e6\u8f9f\u8e4a\u5f84\uff0c\u6709\u671b\u5728\u591a\u9886\u57df\u4e2d\u5f97\u5230\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHexagonal Sphericon Hematite with High Performance for Water Oxidation<\/a><\/strong>\u00a0(Adv. Mater., 2017, DOI: 10.1002\/adma.201703792)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/strong><\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a><\/strong>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u89e3\u6c34\u662f\u751f\u4ea7\u4f5c\u4e3a\u71c3\u6599\u548c\u5316\u5de5\u539f\u6599\u7684\u6c22\u7684\u91cd\u8981\u9014\u5f84\u4e4b\u4e00\u3002\u975e\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u50ac\u5316\u5242\u4f5c\u4e3a\u964d\u4f4e\u8fc7\u7535\u538b\u4e14\u63d0\u9ad8\u80fd\u6e90\u6548\u7387\u7684\u5408\u9002\u5907\u9009\uff0c\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u5174\u8da3\u3002\u7531\u4e8e\u8d64\u94c1\u77ff(\u03b1-…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-109413","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/109413"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=109413"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/109413\/revisions"}],"predecessor-version":[{"id":109571,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/109413\/revisions\/109571"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=109413"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=109413"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=109413"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}