{"id":108694,"date":"2017-10-27T06:30:07","date_gmt":"2017-10-26T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=108694"},"modified":"2017-10-28T11:20:16","modified_gmt":"2017-10-28T03:20:16","slug":"%e4%b8%ad%e5%8d%97%e6%b0%91%e6%97%8f%e5%a4%a7%e5%ad%a6%e5%9c%a8%e7%94%9f%e7%89%a9%e8%b4%a8%e8%bd%ac%e5%8c%96%e6%96%b9%e9%9d%a2%e5%8f%96%e5%be%97%e9%87%8d%e5%a4%a7%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=108694","title":{"rendered":"\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5728\u751f\u7269\u8d28\u8f6c\u5316\u65b9\u9762\u53d6\u5f97\u91cd\u5927\u8fdb\u5c55"},"content":{"rendered":"<p>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5728\u56fd\u9645\u5316\u5b66\u9876\u7ea7\u671f\u520a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7(<em><i>Journal of the American Chemical Society<\/i><\/em>)\u53d1\u8868\u539f\u521b\u6027\u6210\u679c\u201c\u4eff\u751f\u5149\u50ac\u5316\u9009\u62e9\u6027\u6c27\u5316\u751f\u7269\u8d28\u5e73\u53f0\u5206\u5b505-\u7f9f\u7532\u57fa\u7ce0\u919b\u9009\u62e9\u6027\u6c27\u5316\u4e3a2,5-\u544b\u5583\u4e8c\u7532\u9178\uff08Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using O<sub>2<\/sub>\u00a0and a photocatalyst of Co-thioporphyrazine bonded to g-C<sub>3<\/sub>N<sub>4<\/sub>\uff09\u3002\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u8be5\u6821\u5b66\u751f\u5f90\u5e05\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5f20\u6cfd\u4f1a\u526f\u6559\u6388\u548c\u9093\u514b\u4fed\u6559\u6388\u3002\u6b64\u5916\uff0c\u8be5\u9879\u7814\u7a76\u5de5\u4f5c\u5f97\u4e86\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u7684\u6731\u6000\u52c7\u6559\u6388\u548cSteven E. Bottle\u6559\u6388\u5efa\u8bae\u4e0e\u5e2e\u52a9\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-108695\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72471-33.png\" alt=\"\" width=\"600\" height=\"234\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72471-33.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72471-33-300x117.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe\u7247\u6765\u6e90\uff1a\u6587\u7ae0\uff0chttp:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b08861<\/strong><\/p>\n<p>\u5728\u5316\u77f3\u8d44\u6e90\u65e5\u76ca\u67af\u7aed\u7684\u80cc\u666f\u4e0b\uff0c\u53d1\u5c55\u53ef\u518d\u751f\u751f\u7269\u8d28\u8d44\u6e90\u4ee3\u66ff\u4e0d\u53ef\u518d\u751f\u7684\u5316\u77f3\u8d44\u6e90\uff0c\u7528\u4e8e\u751f\u4ea7\u6db2\u4f53\u71c3\u6599\u548c\u5316\u5b66\u54c1\u5f15\u8d77\u4e86\u56fd\u5185\u5916\u6781\u5927\u7684\u5173\u6ce8\u30022,5-\u544b\u5583\u4e8c\u7532\u9178 (FDCA)\u88ab\u7f8e\u56fd\u80fd\u6e90\u90e8\u786e\u8ba4\u4e3a\u7528\u4e8e\u5efa\u7acb\u672a\u6765\u201c\u7eff\u8272\u201d\u5316\u5b66\u5de5\u4e1a\u768412\u79cd\u4f18\u5148\u5316\u5408\u7269\u4e4b\u4e00, \u662f\u66ff\u4ee3\u77f3\u6cb9\u884d\u751f\u7269\u751f\u4ea7\u5851\u6599\uff0c\u6a61\u80f6\u7b49\u5316\u5de5\u4ea7\u54c1\u7684\u91cd\u8981\u539f\u6599\u3002\u6c2e\u63ba\u6742\u78b3\u6750\u6599\u4e2d\u6c2e\u5bf9\u4e8e\u8d1f\u8f7d\u91d1\u5c5e\u6216\u91d1\u5c5e\u6709\u673a\u914d\u5408\u7269\u6d3b\u6027\u63d0\u9ad8\u3001\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u90fd\u6709\u7740\u975e\u5e38\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5f20\u6cfd\u4f1a\u526f\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u524d\u671f\u5de5\u4f5c\u5236\u5907\u4e86\u6c2e\u5316\u94b4\u50ac\u5316\u5242\uff08Co-N<sub>x<\/sub>\uff09\u53d1\u73b0\u8be5\u7c7b\u50ac\u5316\u5242\u5728\u50ac\u5316\u785d\u57fa\u82ef\u8fd8\u539f\u53ca\u5076\u8054\u5177\u6709\u8f83\u5546\u4e1a\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728Science\u5b50\u520a\uff08High performance of a cobalt\u2013nitrogen complex for the reduction and reductive coupling of nitro compounds into amines and their derivatives\uff09\u3002\u5728\u4ece\u57fa\u7840\u4e0a\uff0c\u5f20\u6cfd\u4f1a\u526f\u6559\u6388\u548c\u9093\u514b\u4fed\u6559\u6388\u5408\u4f5c\uff0c\u5229\u7528\u8868\u9762\u6742\u5316\u6280\u672f\u5b9e\u73b0\u542b\u786b\u6c2e\u6742\u91d1\u5c5e\u535f\u5549\u4e0e\u6c2e\u5316\u78b3\u5b9e\u73b0\u6709\u6548\u8d1f\u8f7d\u53ef\u4ee5\u5728\u5e38\u6e29\u3001\u5e38\u538b\u4e0b\u9ad8\u9009\u62e9\u6027\u6c27\u5316\u751f\u7269\u8d28\u5e73\u53f0\u5206\u5b505-\u7f9f\u7532\u57fa\u7ce0\u919b\u4e3a2\uff0c5-\u544b\u5583\u4e8c\u7532\u9178\uff0c\u8bc1\u5b9e\u4e86\u5355\u7ebf\u6001\u4e3a\u8be5\u53cd\u5e94\u9ad8\u9009\u62e9\u7684\u5173\u952e\u56e0\u7d20\u3002<\/p>\n<p>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5f20\u6cfd\u4f1a\u526f\u6559\u6388\u5728\u751f\u7269\u8d28\u50ac\u5316\u8f6c\u5316\u3001\u7eff\u8272\u5316\u5b66\u7b49\u9886\u57df\u53d6\u5f97\u4e86\u8f83\u4e3a\u7a81\u51fa\u6210\u679c\uff0c\u4ee5\u901a\u8baf\u4f5c\u8005\u5728<em><i>Ch<\/i><\/em><em><i>em. Soc. Rev.<\/i><\/em>, <em><i>Science Advances<\/i><\/em>\u00a0\uff08Science \u5b50\u520a,\u00a0<em><i>JACS<\/i><\/em><em><i>,<\/i><\/em><em><i>\u00a0\u00a0ACS Catal., Appl. Catal. B-Envrion., J. Catal., Green Chem., ChemSusChem, J. Mater.Chem. A<\/i><\/em>\u00a0\u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u658760\u4f59\u7bc7\u3002\u76ee\u524d\u6240\u53d1\u8868\u8bba\u6587\u4ed6\u5f15\u6b21\u65702100\u4f59\u6b21\uff0cH\u6307\u657028\uff0c\u5176\u4e2d1\u7bc7\u901a\u8baf\u4f5c\u8005\u8bba\u6587\u5165\u90092013\u5e74\u5ea6\u4e2d\u56fd\u767e\u7bc7\u6700\u5177\u56fd\u9645\u5f71\u54cd\u5b66\u672f\u8bba\u6587\uff0c8\u7bc7\u901a\u8baf\u4f5c\u8005\u8bba\u6587\u5165\u9009\u7f8e\u56fd\u79d1\u6280\u4fe1\u606f\u6240\u57fa\u672c\u79d1\u5b66\u6307\u6807\u6570\u636e\u5e93\uff08ESI\uff09\u9ad8\u88ab\u5f15\u7528\u8bba\u6587\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b08861\" target=\"_blank\" rel=\"noopener\">Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using O<sub>2<\/sub>\u00a0and a photocatalyst of Co-thioporphyrazine bonded to g-C<sub>3<\/sub>N<\/a><sub><a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b08861\">4 <\/a>\uff08JACS\uff0c2017\uff0cDOI\uff1a10.1021\/jacs.7b08861\uff09<\/sub><\/p>\n<p>\u672c\u6587\u7531\u4e2d\u5357\u6c11\u65cf\u5927\u5b66 \u539f\u5b50 \u6295\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n<p><strong><b>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong><strong><b>\u4e0a<\/b><\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><b>\u6d4b\u8bd5\u8c37<\/b><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5728\u56fd\u9645\u5316\u5b66\u9876\u7ea7\u671f\u520a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7(Journal of the American Chemical Society)\u53d1\u8868\u539f\u521b\u6027\u6210\u679c\u201c\u4eff\u751f\u5149\u50ac\u5316\u9009\u62e9\u6027\u6c27&#8230;<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2480],"class_list":["post-108694","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2480"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/108694"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=108694"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/108694\/revisions"}],"predecessor-version":[{"id":108702,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/108694\/revisions\/108702"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=108694"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=108694"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=108694"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}