{"id":108372,"date":"2017-10-27T06:30:41","date_gmt":"2017-10-26T22:30:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=108372"},"modified":"2017-10-24T22:08:43","modified_gmt":"2017-10-24T14:08:43","slug":"%e9%99%88%e5%b0%91%e4%bc%9f%e5%91%a8%e4%bc%9f%e5%ae%b6nano-energy%ef%bc%9a%e5%88%86%e7%ba%a7%e7%bb%93%e6%9e%84%e7%9f%b3%e5%a2%a8%e7%83%af%e5%a4%9a%e5%ad%94%e5%be%ae%e7%b1%b3%e6%a3%92%e8%b4%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=108372","title":{"rendered":"\u9648\u5c11\u4f1f&\u5468\u4f1f\u5bb6Nano Energy\uff1a\u5206\u7ea7\u7ed3\u6784\u77f3\u58a8\u70ef\u591a\u5b54\u5fae\u7c73\u68d2\u8d1f\u8f7dMo2C\u7528\u4f5c\u9ad8\u6548\u6790\u6c22\u7535\u50ac\u5316\u5242"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u4f5c\u4e3a\u6c34\u5206\u89e3\u5168\u53cd\u5e94\u4e2d\u7684\u4e00\u4e2a\u534a\u53cd\u5e94\uff0c\u662f\u5c06\u592a\u9633\u80fd\u3001\u98ce\u80fd\u7b49\u53ef\u518d\u751f\u80fd\u6e90\u8f6c\u5316\u4e3a\u5316\u5b66\u80fd\u7684\u91cd\u8981\u9014\u5f84\u4e4b\u4e00\u3002\u5c3d\u7ba1\u76ee\u524d\u4ee5\u94c2\u57fa\u50ac\u5316\u5242\u4e3a\u4ee3\u8868\u7684\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u7535\u50ac\u5316\u6761\u4ef6\u4e0b\u5177\u6709\u6700\u9ad8\u7684\u7535\u89e3\u6c34\u5236\u6c22\u6548\u7387\uff0c\u5176\u9ad8\u6602\u7684\u4ef7\u683c\u548c\u7a00\u7f3a\u7684\u50a8\u91cf\u4e25\u91cd\u963b\u788d\u4e86\u5176\u5927\u89c4\u6a21\u5de5\u4e1a\u5316\u8fdb\u7a0b\u3002\u4e0e\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7ec4\u6210\u5143\u7d20\u50a8\u91cf\u4e30\u5bcc\u3001\u6210\u672c\u4f4e\u5ec9\uff0c\u53c8\u5177\u6709\u4e0e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u76f8\u8fd1\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5177\u6709\u4ee3\u66ff\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u8fdb\u884c\u5927\u89c4\u6a21\u7535\u89e3\u6c34\u5236\u6c22\u7684\u6f5c\u529b\u3002<\/p>\n \u5728\u4f17\u591a\u975e\u8d35\u91d1\u5c5e\u6790\u6c22\u50ac\u5316\u5242\u4e2d\uff0c\u8fc7\u6e21\u91d1\u5c5e\u78b3\u5316\u7269\u7531\u4e8e\u5177\u6709\u4f4e\u5ec9\u7684\u6210\u672c\u548c\u8f83\u9ad8\u7684\u7535\u50ac\u5316\u6790\u6c22\u6d3b\u6027\u800c\u500d\u53d7\u5173\u6ce8\u3002\u5c24\u5176\u662f\u5176\u4e2d\u7684\u78b3\u5316\u94bc\uff08Mo2<\/sub>C\uff09\u5177\u6709\u4e0e\u94c2\u7c7b\u4f3c\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u8fd9\u4e00\u672c\u5f81\u7279\u6027\u4f7f\u5176\u6781\u6709\u5e0c\u671b\u6210\u4e3a\u94c2\u57fa\u50ac\u5316\u5242\u5728\u7535\u89e3\u6c34\u6790\u6c22\u53cd\u5e94\u4e2d\u7684\u66ff\u4ee3\u54c1\u3002\u7136\u800c\uff0c\u76ee\u524d\u7edd\u5927\u591a\u6570\u7814\u7a76\u5de5\u4f5c\u805a\u7126\u4e8e\u5c06\u78b3\u5316\u94bc\u4e0e\u975e\u91d1\u5c5e\u5143\u7d20\uff08\u5982N\uff09\u63ba\u6742\u7684\u78b3\u6750\u6599\u5f62\u6210\u590d\u5408\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u800c\u7eaf\u76f8\u78b3\u5316\u94bc\u4e0e\u4e0d\u542b\u63ba\u6742\u5143\u7d20\u7684\u78b3\u6750\u6599\u6784\u6210\u7684\u590d\u5408\u50ac\u5316\u5242\u4f53\u7cfb\u5374\u5f80\u5f80\u53ea\u80fd\u53d6\u5f97\u8f83\u5dee\u7684\u6790\u6c22\u6548\u679c\u3002\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u5316\u5b66\u5236\u5907\u8fc7\u7a0b\u4e2d\u8fc7\u591a\u7684\u78b3\u6750\u6599\u8986\u76d6\u5728\u78b3\u5316\u94bc\u8868\u9762\u7684\u94bc\u539f\u5b50\u6d3b\u6027\u4f4d\u70b9\u4e0a\uff0c\u4f7f\u8868\u9762\u66b4\u9732\u7684\u6d3b\u6027\u4f4d\u70b9\u6570\u76ee\u4e0b\u964d\uff0c\u4ece\u800c\u5bfc\u81f4\u50ac\u5316\u6d3b\u6027\u5927\u5e45\u964d\u4f4e\u3002\u56e0\u6b64\uff0c\u9700\u8981\u8bbe\u6cd5\u589e\u52a0\u78b3\u5316\u94bc\u50ac\u5316\u5242\u8868\u9762\u4ee5\u94bc\u539f\u5b50\u4e3a\u7ec8\u7aef\u7684\u6d3b\u6027\u4f4d\u70b9\u6570\u76ee\uff0c\u4ece\u800c\u5145\u5206\u53d1\u6325\u51fa\u78b3\u5316\u94bc\u57fa\u50ac\u5316\u5242\u7684\u7535\u50ac\u5316\u6790\u6c22\u6d3b\u6027\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66<\/strong>\u7684\u9648\u5c11\u4f1f\u6559\u6388<\/strong>\u548c\u534e\u5357\u7406\u5de5\u5927\u5b66<\/strong>\u7684\u5468\u4f1f\u5bb6\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4\u5728Nano Energy<\/strong>\u4e0a\u5171\u540c\u53d1\u8868\u4e86\u4e00\u7bc7\u540d\u4e3a\u201cMolybdenum Carbide on Hierarchical Porous Carbon Synthesized from Cu-MoO2<\/sub> as Efficient Electrocatalysts for Electrochemical Hydrogen Generation<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u4ee5Cu-MoO2<\/sub>\u5fae\u7c73\u68d2\u4f5c\u4e3a\u63d0\u4f9b\u94bc\u6e90\u548c\u94dc\u6a21\u677f\u7684\u524d\u9a71\u4f53\uff0c\u5728\u9ad8\u6e29\u4e0b\u5f15\u5165CH4<\/sub>\u6c14\u4f53\u4f5c\u4e3a\u78b3\u6e90\uff0c\u7ecf\u524d\u9a71\u4f53\u4e2d\u94dc\u7ec4\u5206\u7684\u50ac\u5316\u5f62\u6210\u7531\u4e09\u7ef4\u4ea4\u8054\u7684\u77f3\u58a8\u70ef\u7247\u6784\u6210\u7684\u591a\u5b54\u77f3\u58a8\u70ef\u5fae\u7c73\u68d2\uff08CLCN\uff09\uff0c\u6700\u540e\u7ecf\u523b\u8680\u9664\u53bb\u4f53\u7cfb\u4e2d\u7684\u94dc\u5f62\u6210Mo2<\/sub>C\/ CLCN\u590d\u5408\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u8be5Mo2<\/sub>C\/ CLCN\u50ac\u5316\u5242\u7684\u7535\u50ac\u5316\u6790\u6c22\u6d3b\u6027\u53ca\u7a33\u5b9a\u6027\u8fdc\u9ad8\u4e8e\u540c\u7b49\u6761\u4ef6\u4e0b\u4e0d\u542b\u975e\u91d1\u5c5e\u63ba\u6742\u5143\u7d20\u65f6\u7684\u7eaf\u76f8Mo2<\/sub>C\u50ac\u5316\u5242\u3002\u57280.5 M H2<\/sub>SO4<\/sub>\u4e2d\uff0cMo2<\/sub>C\/ CLCN\u5177\u6709\u4f4e\u7684\u8d77\u59cb\u7535\u4f4d\uff08-85 mV\uff09\u548c\u5854\u83f2\u5c14\u659c\u7387\uff0848.2 mV\/dec\uff09\uff0c\u8fbe\u523010 mA\/cm2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4ec5\u9700\u8981145 mV\u7684\u8fc7\u7535\u4f4d\uff0c\u5e76\u80fd\u5728\u9ad8\u8fbe50 mA\/cm2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4fdd\u630112\u5c0f\u65f6\u800c\u4e0d\u53d1\u751f\u663e\u8457\u7684\u7535\u6d41\u5bc6\u5ea6\u8870\u51cf\uff0c\u5373\u5177\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0cCu-MoO2<\/sub>\u524d\u9a71\u4f53\u4e2d\u7684\u94dc\u7ec4\u5206\u5bf9\u4e8e\u7535\u50ac\u5316\u6790\u6c22\u6d3b\u6027\u7684\u663e\u8457\u63d0\u5347\u5177\u6709\u4e3e\u8db3\u8f7b\u91cd\u7684\u4fc3\u8fdb\u4f5c\u7528\uff1a(1) \u94dc\u7ec4\u5206\u80fd\u8c03\u63a7\u524d\u9a71\u4f53\u7684\u5f62\u8c8c\uff0c\u4f7fCu-MoO2<\/sub>\u524d\u9a71\u4f53\u5177\u6709\u5fae\u7c73\u68d2\u7684\u51e0\u4f55\u6784\u578b\uff1b(2) \u94dc\u50ac\u5316\u4e86CH4<\/sub>\u6c14\u4f53\u7684\u9ad8\u6e29\u5206\u89e3\u8fc7\u7a0b\u4ee5\u53ca\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u5728\u524d\u9a71\u4f53\u8868\u9762\u5f62\u6838\u3001\u751f\u957f\u4e43\u81f3\u6700\u540e\u5f62\u6210\u5206\u7ea7\u7ed3\u6784\u591a\u5b54\u5fae\u7c73\u68d2\u7684\u8fc7\u7a0b\uff0c\u7ecf\u523b\u8680\u9664\u53bb\u94dc\u540e\u8be5\u4f53\u7cfb\u5f62\u6210\u4e86\u591a\u5b54\u7684Mo2<\/sub>C\/ CLCN \u5fae\u7c73\u68d2\uff1b(3) \u94dc\u7684\u5b58\u5728\u6291\u5236\u4e86Mo2<\/sub>C\u5728\u9ad8\u6e29\u4e0b\u7684\u6676\u7c92\u751f\u957f\uff0c\u4ece\u800c\u5f97\u5230\u5c0f\u5c3a\u5bf8\u7684Mo2<\/sub>C\u6676\u7c92\uff1b(4) \u5305\u8986\u5728Mo2<\/sub>C\u8868\u9762\u7684\u94dc\u5bf9Mo2<\/sub>C\u8868\u9762\u7684\u94bc\u6d3b\u6027\u4f4d\u70b9\u8d77\u5230\u4fdd\u62a4\u4f5c\u7528\uff0c\u80fd\u6709\u6548\u9632\u6b62\u4f5c\u4e3a\u7ec8\u7aef\u7684\u94bc\u539f\u5b50\u88ab\u539f\u4f4d\u751f\u6210\u7684\u78b3\u6750\u6599\u8986\u76d6\u800c\u5bfc\u81f4\u50ac\u5316\u5242\u6d3b\u6027\u4e0b\u964d\uff0c\u6700\u540e\u518d\u7528\u523b\u8680\u7684\u65b9\u6cd5\u9664\u53bb\u94dc\u5373\u53ef\u4f7f\u8fd9\u4e9b\u94bc\u6d3b\u6027\u4f4d\u70b9\u91cd\u65b0\u66b4\u9732\u51fa\u6765\u3002\u8fd9\u9879\u5de5\u4f5c\u91c7\u7528\u539f\u4f4d\u6a21\u677f\u6cd5\u4fdd\u62a4\u50ac\u5316\u5242\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4e3a\u6784\u7b51\u9ad8\u6548\u7684\u591a\u7ec4\u5206\u590d\u5408\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u542f\u793a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1. DFT\u8ba1\u7b97\u6790\u6c22\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316<\/strong><\/p>\n (a) \u7406\u8bba\u4e0a\u5728Mo2<\/sub>C\u8868\u9762\u7684\u6c22\u5438\u9644\u81ea\u7531\u80fd\u3002<\/p>\n (b) \u8868\u9762\u78b3\u539f\u5b50\u9971\u548c\u7684Mo2<\/sub>C\u7684\u6c22\u5438\u9644\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3002<\/p>\n DFT\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0cMo2<\/sub>C\/ CLCN\u50ac\u5316\u5242\u8868\u9762\u7684Mo\u539f\u5b50\u662f\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u7684\u4e3b\u8981\u6d3b\u6027\u4f4d\u70b9\u3002\u5f53\u8fd9\u4e9bMo\u539f\u5b50\u88ab\u539f\u4f4d\u751f\u6210\u7684\u78b3\u6750\u6599\u8986\u76d6\u65f6\uff0c\u50ac\u5316\u5242\u8868\u9762\u7684\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u53d8\u5f97\u5f02\u5e38\u56f0\u96be\u3002<\/p>\n \u56fe2. Mo2<\/sub>C\/ CLCN\u590d\u5408\u50ac\u5316\u5242\u7684\u5408\u6210\u8fc7\u7a0b<\/strong><\/p>\n <\/p>\n \u56fe3. Cu-MoO2<\/sub>\u3001Cu-Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C\/ CLCN\u7684\u5f62\u8c8c\u53ca\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n (a,e) Cu-MoO2<\/sub>\uff1b(b,f) Cu-Mo2<\/sub>C\/ CLCN\uff1b(c,d,g) Mo2<\/sub>C\/ CLCN\u7684SEM\u56fe\u50cf\u53caC\u3001Mo\u3001Cu\u7684\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n (h) Cu-MoO2<\/sub>\u3001Cu-Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C\/ CLCN\u4e2d\u7684C\u3001Mo\u3001Cu\u5143\u7d20\u6bd4\u4f8b\u3002<\/p>\n \u56fe4. Cu-MoO2<\/sub>\u3001Cu-Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C\/ CLCN\u7684\u7ed3\u6784\u3001\u6210\u5206\u8868\u5f81\u53ca\u6bd4\u8868\u9762\u79ef\u6d4b\u8bd5<\/strong><\/p>\n Cu-MoO2<\/sub>\u3001Cu-Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C\/ CLCN\u7684(a) XRD\u56fe\u8c31\uff1b(b) \u62c9\u66fc\u5149\u8c31\uff1b(c) Cu 2p\u548c(d) Mo 3d\u7684\u9ad8\u5206\u8fa8XPS\u56fe\u8c31\uff1b(e) N2<\/sub>\u7684\u7b49\u6e29\u5438\u9644\/\u8131\u9644\u66f2\u7ebf\uff1b(f) \u5b54\u5f84\u5206\u5e03\u56fe\u3002<\/p>\n \u56fe5. Mo2<\/sub>C\/ CLCN\u7684\u5f62\u8c8c\u53ca\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n (a-c) Mo2<\/sub>C\/ CLCN\u7684(HR)TEM\u56fe\u50cf\uff0c\u56fe(a)\u4e2d\u7684\u63d2\u56fe\u4e3aMo2<\/sub>C\/ CLCN\u7684\u7535\u5b50\u884d\u5c04\u56fe\u8c31\u3002<\/p>\n (d) Mo2<\/sub>C\/ CLCN\u788e\u7247\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n (e) Mo2<\/sub>C\/ CLCN\u4e2dMo\u3001C\u7684\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n \u56fe6. \u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n (a) Cu-MoO2<\/sub>\u3001Cu-Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C-S1\u3001Mo2<\/sub>C-S2\u300120 wt% Pt\/C\u57280.5 M H2<\/sub>SO4<\/sub>\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u3002\u6ce8\uff1aMo2<\/sub>C-S1\u548cMo2<\/sub>C-S2\u5747\u4e3a\u7a7a\u767d\u8bd5\u6837\uff0c\u5176\u4e2dMo2<\/sub>C-S1\u7531\u4e0d\u542b\u94dc\u7684MoO2<\/sub>\u524d\u9a71\u4f53\u5236\u5f97\uff0cMo2<\/sub>C-S2\u7531Cu-MoO2<\/sub>\u524d\u9a71\u4f53\uff08\u78b3\u5316\u524d\u94dc\u88ab\u53bb\u9664\uff09\u5236\u5f97\u3002<\/p>\n (b) Cu-MoO2<\/sub>\u3001Cu-Mo2<\/sub>C\/ CLCN\u3001Mo2<\/sub>C\/ CLCN\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u5728+0.05 V\u7535\u4f4d\u5904\u7684\u53cc\u7535\u5c42\u5145\u7535\u7535\u6d41\u3002<\/p>\n (c) \u7531\u56fe(a)\u5f97\u5230\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\u3002<\/p>\n (d) Mo2<\/sub>C\/ CLCN\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u7684Nyquist\u56fe\u3002<\/p>\n (e) \u4e0d\u540c\u7535\u4f4d\u4e0b\u7684\u7535\u6d41\u5bc6\u5ea6-\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n (f) Mo2<\/sub>C\/ CLCN\u5728\u8ba1\u65f6\u7535\u6d41\u6cd5\u6d4b\u8bd5\u524d\u540e\u7684\u6781\u5316\u66f2\u7ebf\uff0c\u63d2\u56fe\u4e3aMo2<\/sub>C\/ CLCN\u7ecf\u8ba1\u65f6\u7535\u6d41\u6cd5\u6d4b\u8bd5\u540e\u7684SEM\u56fe\u50cf\u3002<\/p>\n \u56fe7. \u63a2\u7a76\u4e0d\u540c\u523b\u8680\u6761\u4ef6\u5bf9Mo2<\/sub>C\/ CLCN\u7684\u5f71\u54cd<\/strong><\/p>\n (a) \u4e0d\u540c\u523b\u8680\u6761\u4ef6\u4e0b\u6240\u5f97\u6837\u54c1\u7684XRD\u56fe\u8c31\u3002<\/p>\n (b) Cu 2p \u548c (c) Mo 3d\u7684\u9ad8\u5206\u8fa8XPS\u56fe\u8c31\u3002<\/p>\n (d) \u4e0d\u540c\u523b\u8680\u6761\u4ef6\u4e0b\u6240\u5f97\u6837\u54c1\u4e2dCu\u3001Mo\u5143\u7d20\u7684\u542b\u91cf\u3002<\/p>\n (e) \u4e0d\u540c\u523b\u8680\u6761\u4ef6\u4e0b\u6240\u5f97\u6837\u54c1\u57280.5 M H2<\/sub>SO4<\/sub>\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n (f) \u4e0d\u540c\u523b\u8680\u6761\u4ef6\u4e0b\u6240\u5f97\u6837\u54c1\u7684\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\u3002<\/p>\n \u6ce8\uff1a\u523b\u8680\u6761\u4ef6\u4e3a\u8d85\u58f0\u6761\u4ef6\u4e0b\u75280.01 M FeCl3<\/sub>\u6eb6\u6db2\u523b\u8680\u6837\u54c110\u300140\u300180 min\u548c\u75283 M FeCl3<\/sub>\u6eb6\u6db2\u523b\u8680\u6837\u54c180 min\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u8fd9\u9879\u5de5\u4f5c\u91c7\u7528\u81ea\u6a21\u677f\u4fdd\u62a4\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u7684\u7b56\u7565\uff0c\u7528Cu-MoO2<\/sub>\u5fae\u7c73\u68d2\u524d\u9a71\u4f53\u5408\u6210\u4e86Mo2<\/sub>C\/ CLCN\u590d\u5408\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u8be5\u4f53\u7cfb\u5728\u9178\u6027\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u7684\u7535\u50ac\u5316\u6790\u6c22\u6d3b\u6027\u8fdc\u9ad8\u4e8e\u4ee5\u5f80\u7edd\u5927\u591a\u6570\u4e0d\u542b\u975e\u91d1\u5c5e\u63ba\u6742\u5143\u7d20\u7684Mo2<\/sub>C\u50ac\u5316\u5242\uff0c\u5e76\u5728\u9178\u6027\u3001\u4e2d\u6027\u3001\u78b1\u6027\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u5747\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u8be5\u4f53\u7cfb\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6790\u6c22\u6027\u80fd\u4e0d\u4ec5\u5f97\u76ca\u4e8e\u76f8\u4e92\u4ea4\u8054\u7684\u4e8c\u7ef4\u77f3\u58a8\u70ef\u7247\u6784\u6210\u7684\u591a\u7ea7\u7ed3\u6784\u591a\u5b54\u77f3\u58a8\u70ef\u5fae\u7c73\u68d2\u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u8fd8\u5f97\u76ca\u4e8eCu-MoO2<\/sub>\u524d\u9a71\u4f53\u4e2d\u8986\u76d6\u5728Mo2<\/sub>C\u8868\u9762\u7684\u94dc\u7ec4\u5206\u5bf9Mo2<\/sub>C\u8868\u9762\u7684\u94bc\u6d3b\u6027\u4f4d\u70b9\u8d77\u5230\u4e86\u4fdd\u62a4\u4f5c\u7528\uff0c\u6709\u6548\u9632\u6b62\u540e\u7eed\u53cd\u5e94\u4e2d\u539f\u4f4d\u751f\u6210\u7684\u78b3\u6750\u6599\u6c89\u79ef\u5230\u94bc\u6d3b\u6027\u4f4d\u70b9\u4e0a\uff0c\u5e76\u7528\u523b\u8680\u9664\u53bb\u94dc\u7684\u65b9\u6cd5\u91cd\u65b0\u66b4\u9732\u51fa\u8868\u9762\u7684\u7ec8\u7aef\u94bc\u539f\u5b50\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5236\u5907\u6bd4\u8868\u9762\u79ef\u5927\u3001\u5bcc\u542b\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u7684\u9ad8\u6548\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u5177\u6709\u666e\u904d\u610f\u4e49\u7684\u6709\u76ca\u542f\u53d1\u548c\u53ef\u9760\u9014\u5f84\uff01<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Molybdenum Carbide on Hierarchical Porous Carbon Synthesized from Cu-MoO2<\/sub> as Efficient Electrocatalysts for Electrochemical Hydrogen Generation<\/a>(Nano Energy, 2017, DOI:\u00a0http:\/\/dx.doi.org\/10.1016\/j.nanoen.2017.10.030)<\/p>\n \u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a<\/strong><\/p>\n (1) \u9648\u5c11\u4f1f<\/strong>\u8001\u5e08\u73b0\u4e3a\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u5723\u514b\u9c81\u5179\u5206\u6821\u5316\u5b66\u4e0e\u751f\u7269\u5316\u5b66\u7cfb\u6559\u6388\uff0c2010\u5e74\u5e74\u5e95\u5165\u9009\u56fd\u5bb6\u201c\u5343\u4eba\u8ba1\u5212\u201d\u00a0\uff0c\u73b0\u4e3a\u534e\u5357\u7406\u5de5\u5927\u5b66\u73af\u5883\u4e0e\u80fd\u6e90\u5b66\u9662\u65b0\u80fd\u6e90\u7814\u7a76\u6240\u7684\u5343\u4eba\u7279\u8058\u6559\u6388\u3002\u7814\u7a76\u65b9\u5411\u4e3b\u8981\u96c6\u4e2d\u5728\u7eb3\u7c73\u529f\u80fd\u6750\u6599\u53ca\u5176\u7535\u5b50\u4f20\u8f93\u5316\u5b66\u65b9\u9762\uff0c\u73b0\u6709\u8bfe\u9898\u5305\u62ec\uff081\uff09\u4e24\u9762\u795e\u201cJanus\u201d\u7eb3\u7c73\u9897\u7c92\uff1b\uff082\uff09\u7eb3\u7c73\u9897\u7c92\u53ca\u5176\u56fa\u4f53\u96c6\u6210\u7684\u5355\u7535\u5b50\u4f20\u8f93\uff1b\uff083\uff09\u754c\u9762\u952e\u5408\u4f5c\u7528\u5bf9\u7eb3\u7c73\u9897\u7c92\u7535\u8377\u4f20\u8f93\u52a8\u529b\u5b66\u7684\u5f71\u54cd\uff1b\uff084\uff09\u7535\u50ac\u5316\u548c\u71c3\u6599\u7535\u6c60\u7535\u5316\u5b66\u3002\u81f3\u4eca\u5df2\u53d1\u8868\u4e86\u00a0260\u00a0\u4f59\u7bc7\u5b66\u672f\u8bba\u6587\uff0c\u5e76\u51fa\u7248\u4e94\u672c\u4e13\u8457\u4ee5\u53ca\u00a0\u516b\u00a0\u4e2a\u4e13\u8457\u7ae0\u8282\u3002\u4e8e\u00a02001\u00a0\u5e74\u83b7\u5f97\u7f8e\u56fd\u56fd\u5bb6\u79d1\u5b66\u57fa\u91d1\u4f1a\u7684\u00a0CAREER Award\u00a0\u548cResearch Corporation for Science Advancement\u00a0\u7684Cottrell Scholar Award\uff0c2002\u00a0\u5e74\u83b7\u5f97\u4e2d\u56fd\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4f1a\u7684\u6d77\u5916\u6770\u51fa\u9752\u5e74\u57fa\u91d1\uff0c2003\u5e74\u83b7\u5f97\u738b\u5bbd\u8bda\u57fa\u91d1\u4f1a\u7814\u7a76\u57fa\u91d1\uff0c\u5e76\u4e8e2005\u00a0\u5e74\u88ab\u6311\u9009\u4e3a\u7b2c\u00a043\u00a0\u5c4a\u56fd\u9645\u7eaf\u7cb9\u4e0e\u5e94\u7528\u5316\u5b66\u8054\u76df\u5927\u4f1a\u7684\u5e74\u8f7b\u89c2\u5bdf\u5458\uff0c\u540c\u5e74\u83b7\u5f97\u56fd\u9645\u7535\u5316\u5b66\u534f\u4f1a\u7684\u00a0Tajima Prize\u3002<\/p>\n (2) \u5468\u4f1f\u5bb6<\/strong>\u8001\u5e08\u73b0\u4e3a\u534e\u5357\u7406\u5de5\u5927\u5b66\u73af\u5883\u4e0e\u80fd\u6e90\u5b66\u9662\u526f\u6559\u6388\uff0c2014\u5e74\u5165\u9009\u4e3a\u201c\u73e0\u6c5f\u79d1\u6280\u65b0\u661f\u201d\uff0c2017\u5e74\u5165\u9009\u4e3a\u201c\u5e7f\u4e1c\u7279\u652f\u8ba1\u5212\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u201d\u548c \u201c\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u83b7\u5f97\u8005\u201d\uff0c\u5728Energy Environ. Sci.\u3001Angew.Chem. Int. Ed.\u3001Adv. Funct. Mater.\u3001Nano energy\u7b49\u671f\u520a\u53d1\u8868\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005SCI\u6536\u5f55\u8bba\u658738\u4f59\u7bc7\uff0c\u4ed6\u5f15\u8d85\u8fc71800\u4f59\u6b21\uff0cESI\u9ad8\u88ab\u5f15\u7528\u8bba\u658712\u7bc7\uff0c\u4e2d\u56fd\u767e\u7bc7\u6700\u5177\u5f71\u54cd\u529b\u56fd\u9645\u5b66\u672f\u8bba\u65871\u7bc7\uff1b\u6388\u6743\u53d1\u660e\u4e13\u52294\u9879\u3002\u62c5\u4efbAngew. Chem. Int. Ed.\u3001Adv. Mater.\u7b49\u6742\u5fd7\u7684\u7279\u9080\u5ba1\u7a3f\u4eba\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u7eb3\u7c73\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u5316\u6280\u672f\u4e2d\u7684\u7535\u50ac\u5316\u7814\u7a76\u53ca\u73af\u5883\u5e9f\u5f03\u7269\u7684\u65b0\u80fd\u6e90\u8d44\u6e90\u5316\u518d\u5229\u7528\u7814\u7a76\uff0c\u73b0\u6709\u8bfe\u9898\u65b9\u5411\u5305\u62ec(1)\u8fc7\u6e21\u91d1\u5c5e-\u78b3\u57fa\u548c\u94bc\u57fa\u7535\u50ac\u5316\u5242\u8bbe\u8ba1\u5408\u6210\u53ca\u5149\u7535\u50ac\u5316\u89e3\u6c34\u6027\u80fd\u7814\u7a76\uff1b(2)\u8d85\u7ea7\u7535\u5bb9\u5668\u4e09\u7ef4\u591a\u7ea7\u7535\u6781\u6784\u5efa\u53ca\u6027\u80fd\u8c03\u63a7\u7814\u7a76\uff1b(3)\u6c27\u8fd8\u539f\u53cd\u5e94\u7b49\u7535\u50ac\u5316\u7814\u7a76\u3002<\/p>\n \u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n \u81ea2012\u5e74\u4ee5\u6765\uff0c\u9648\u5c11\u4f1f\u8001\u5e08\u5728\u534e\u5357\u7406\u5de5\u5927\u5b66\u7ec4\u5efa\u4e86\u4e00\u4e2a\u7eb3\u7c73\u529f\u80fd\u6750\u6599\u4e0e\u7535\u5316\u5b66\u80fd\u6e90\u56e2\u961f\uff0c\u73b0\u6709\u6559\u5e08\u4e94\u540d\uff0c\u535a\u58eb\u751f\u7814\u7a76\u751f\u4e09\u5341\u591a\u540d\u3002\u76ee\u524d\u56e2\u961f\u7684\u4e3b\u8981\u79d1\u7814\u6d3b\u52a8\u4e13\u6ce8\u4e8e\u7eb3\u7c73\u529f\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u53ca\u5de5\u7a0b\u5316\uff0c\u4ee5\u53ca\u5728\u7535\u5316\u5b66\u80fd\u6e90\u8f6c\u5316\u4e0e\u50a8\u5b58\u4e0a\u7684\u5e94\u7528\uff0c\u7279\u522b\u662f\u9502\u786b\u7535\u6c60\u3001\u4f4e\u6e29\u71c3\u6599\u7535\u6c60\u3001\u6c34\u5206\u89e3\u6790\u6c22\u7b49\u3002<\/p>\n \u76f8\u5173\u6587\u732e\u63a8\u8350\uff1a<\/strong><\/p>\n Yi Peng, Bingzhang Lu, Limei Chen, Nan Wang, Jia En Lu, Yuan Ping, and Shaowei Chen, “Hydrogen evolution reaction catalyzed by ruthenium ion-complexed graphitic-like carbon nitride nanosheets<\/a>“,\u00a0J. Mater. Chem. A<\/em>,\u00a02017<\/strong>,\u00a05<\/em>, 18261.<\/p>\n Shuaibo Zeng, Ligui Li, Lihong Xie, Dengke Zhao, Nan Wang, and Shaowei Chen, “Conducting Polymers Crosslinked with Sulfur as Cathode Materials for High-Rate, Ultralong-Life Lithium-Sulfur Batteries<\/a>“,\u00a0ChemSusChem<\/em>,\u00a02017<\/strong>,\u00a010<\/em>, 3378.\u00a0<\/p>\n Shuaibo Zeng, Ligui Li, Lihong Xie, Dengke Zhao, Ni Zhou, Nan Wang, and Shaowei Chen, “Graphene-Supported Highly Crosslinked Organosulfur Nanoparticles as Cathode Materials for High-Rate, Long-Life Lithium-Sulfur Battery<\/a>“,\u00a0Carbon<\/em>,\u00a02017<\/strong>,\u00a0122<\/em>, 106.<\/p>\n Bingzhang Lu, Tyler J. Smart, Dongdong Qin, Jia En Lu, Nan Wang, Limei Chen, Yi Peng, Yuan Ping, and Shaowei Chen, “Nitrogen and Iron-Codoped Carbon Hollow Nanotubules as High-Performance Catalysts Towards Oxygen Reduction Reaction: A Combined Experimental and Theoretical Study<\/a>“,\u00a0Chem. Mater.<\/em>,\u00a02017<\/strong>,\u00a029<\/em>, 5617.\u00a0<\/p>\n Nan Wang, Ligui Li, Dengke Zhao, Xiongwu Kang, Zhenghua Tang, and Shaowei Chen, “Graphene Composites with Cobalt Sulfide: Efficient Trifunctional Electrocatalysts for Oxygen Reversible Catalysis and Hydrogen Production in the Same Electrolyte<\/a>“,\u00a0Small<\/em>,\u00a02017<\/strong>,\u00a013<\/em>, 1701025.\u00a0<\/p>\n Shuaibo Zeng, Ligui Li, Dengke Zhao, Ji Liu, Wenhan Niu, Nan Wang, and Shaowei Chen, “Polymer-Capped Sulfur Copolymers as Lithium-Sulfur Battery Cathode: Enhanced Performance by Combined Contributions of Physical and Chemical Confinements<\/a>“,\u00a0J. Phys. Chem. 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Soc.<\/em>,\u00a02015<\/strong>,\u00a0137<\/em>, 5555\u3002<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u738b\u948a\u9896\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n<\/p>\n
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