{"id":108222,"date":"2017-10-25T06:30:11","date_gmt":"2017-10-24T22:30:11","guid":{"rendered":"\/\/m.iemloyee.com\/?p=108222"},"modified":"2017-10-23T21:29:04","modified_gmt":"2017-10-23T13:29:04","slug":"macromolecules-%ef%bc%9a%e6%b0%b4%e5%8f%82%e4%b8%8e%e7%9a%84%e6%96%b0%e5%9e%8b%e4%b8%89%e9%94%ae%e8%81%9a%e5%90%88%e5%8f%8d%e5%ba%94%e5%88%b6%e5%a4%87%e5%8f%af%e5%90%8e%e5%8a%9f%e8%83%bd%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=108222","title":{"rendered":"Macromolecules \uff1a\u6c34\u53c2\u4e0e\u7684\u65b0\u578b\u4e09\u952e\u805a\u5408\u53cd\u5e94\u5236\u5907\u53ef\u540e\u529f\u80fd\u5316\u7684\u805a\u9170\u80fa"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u6c34\uff0c\u4f5c\u4e3a\u81ea\u7136\u754c\u4e2d\u5ec9\u4ef7\u6613\u5f97\u7684\u8d44\u6e90\uff0c\u5728\u5316\u5b66\u53cd\u5e94\u4e2d\u4e00\u822c\u4f5c\u4e3a\u526f\u4ea7\u7269\u800c\u88ab\u4eba\u6240\u77e5\u3002\u800c\u6c34\u53c2\u4e0e\u7684\u6709\u673a\u548c\u805a\u5408\u53cd\u5e94\u62a5\u9053\u8f83\u5c11\u3002\u9274\u4e8e\u50ac\u5316\u4f53\u7cfb\u7684\u8106\u5f31\u6027\u548c\u805a\u5408\u7269\u7684\u6eb6\u89e3\u6027\uff0c\u76ee\u524d\u5c06\u6c34\u4f5c\u4e3a\u4e00\u79cd\u5355\u4f53\u7528\u6765\u5408\u6210\u9ad8\u5206\u5b50\u4f9d\u7136\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\u3002\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u9762\u5bf9\u8fd9\u4e00\u6311\u6218\uff0c\u5f00\u53d1\u4e86\u4e00\u6761\u5229\u7528\u6c34\u548c\u5f02\u8148\u53ca\u6eb4\u4ee3\u7094\u7684\u805a\u5408\u53cd\u5e94\u8def\u7ebf\u3002\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u83b7\u5f97\u4e86\u5177\u6709\u9ad8\u5206\u5b50\u91cf\uff08\u9ad8\u8fbe41 700\uff09\u548c\u9ad8\u7acb\u6784\u89c4\u6574\u6027\uff08Z-\u5f02\u6784\u4f53\u6bd4\u4f8b\u9ad8\u4e8e80\uff05\uff09\u7684\u4ea7\u7269\uff0c\u4ea7\u7387\u9ad8\u8fbe98.1\uff05\u3002\u6240\u5f97\u805a\u5408\u7269\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\u3001\u70ed\u7a33\u5b9a\u6027\u548c\u8f83\u9ad8\u7684\u6298\u5c04\u7387\u3002\u901a\u8fc7\u8bbe\u8ba1\u5355\u4f53\u5411\u805a\u5408\u7269\u4e2d\u5f15\u5165\u56db\u82ef\u57fa\u4e59\u70ef\u540e\uff0c\u805a\u5408\u7269\u663e\u793a\u51fa\u72ec\u7279\u7684\u805a\u96c6\u589e\u5f3a\u8367\u5149\uff08AEE\uff09\u73b0\u8c61\u3002\u6b64\u9879\u5de5\u4f5c\u4e0d\u4ec5\u9996\u6b21\u5b9e\u73b0\u4e86\u6c34\u4f5c\u4e3a\u5355\u4f53\u4e4b\u4e00\u7684\u805a\u5408\uff0c\u540c\u65f6\u4e3a\u805a\u9170\u80fa\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u9053\u8def\u3002\u53e6\u5916\uff0c\u6240\u5f97\u805a\u5408\u7269\u53ef\u4ee5\u901a\u8fc7\u591a\u6761\u7b80\u5355\u7684\u8def\u5f84\u8fdb\u4e00\u6b65\u540e\u4fee\u9970\uff0c\u4e3a\u5176\u529f\u80fd\u5316\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5e7f\u9614\u7684\u5e73\u53f0\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u6c34\u662f\u4e00\u79cd\u975e\u5e38\u4e30\u5bcc\u3001\u4fbf\u5b9c\u3001\u53ef\u6301\u7eed\u7684\u8d44\u6e90\uff0c\u4f46\u662f\u7531\u4e8e\u79cd\u79cd\u9650\u5236\uff0c\u5f88\u96be\u4f5c\u4e3a\u5171\u805a\u5355\u4f53\u53c2\u4e0e\u805a\u5408\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u5728\u5f88\u591a\u7f29\u805a\u53cd\u5e94\u4e2d\uff0c\u6c34\u662f\u526f\u4ea7\u7269\u53cd\u5e94\u4f53\u7cfb\u4e2d\u6c34\u7684\u79ef\u7d2f\u4e0d\u5229\u4e8e\u53cd\u5e94\u5e73\u8861\u7684\u6b63\u5411\u79fb\u52a8\uff0c\u56e0\u6b64\u9700\u8981\u5c3d\u5feb\u628a\u6c34\u4ece\u53cd\u5e94\u4f53\u7cfb\u4e2d\u9664\u53bb\u3002\u6c34\u6709\u65f6\u4e5f\u662f\u7ec8\u6b62\u53cd\u5e94\u7684\u731d\u706d\u5242\uff0c\u5f88\u591a\u805a\u5408\u53cd\u5e94\u9700\u8981\u5728\u4e25\u683c\u7684\u65e0\u6c34\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002\u56e0\u6b64\uff0c\u4f7f\u7528\u6c34\u4f5c\u4e3a\u5171\u805a\u5355\u4f53\u5236\u5907\u805a\u5408\u7269\u662f\u4e00\u4e2a\u975e\u5e38\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u79e6\u5b89\u519b\u6559\u6388<\/strong>\u548c<strong>\u5510\u672c\u5fe0\u9662\u58eb<\/strong>\uff08<strong>\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\uff09\u7b49\u4eba\u5728<strong>Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5229\u7528\u6c34\u4f5c\u4e3a\u5171\u805a\u5355\u4f53\uff0c\u6784\u5efa\u805a\u5408\u7269\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>Facile Polymerization of Water and Triple-Bond Based Monomers toward Functional Polyamides<\/strong>\u201d\u3002\u6587\u4e2d\u4ecb\u7ecd\u7684\u4ee5\u6c34\u4e3a\u5171\u805a\u5355\u4f53\u8fdb\u884c\u805a\u5408\uff0c\u4e0d\u4ec5\u7a81\u7834\u4f20\u7edf\u9650\u5236\uff0c\u800c\u4e14\u63d0\u4f9b\u4e86\u4e00\u6761\u76f4\u63a5\u3001\u65b0\u9896\u7684\u65b0\u53cd\u5e94\u8def\u7ebf\u6765\u5236\u5907\u805a\u9170\u80fa\u3002\u6b64\u5916\uff0c\u6240\u5f97\u805a\u9170\u80fa\u53ef\u4ee5\u5bb9\u6613\u5730\u540e\u5b98\u80fd\u5316\u3002\u805a\u5408\u540e\u4fee\u9970\uff08PPM\uff09\u53ef\u4ee5\u6709\u6548\u5730\u6d88\u8017\u9884\u805a\u7269\u4e0a\u7684\u53cd\u5e94\u6027\u57fa\u56e2\uff0c\u4ee5\u5bcc\u96c6\u5177\u6709\u76f8\u540c\u9aa8\u67b6\u7684\u805a\u5408\u7269\u7684\u529f\u80fd\u3002\u901a\u8fc7\u7b80\u5355\u7684Sonogashira\u53cd\u5e94\u548c\u53d6\u4ee3\u53cd\u5e94\uff0c\u53ef\u4ee5\u65b9\u4fbf\u5730\u5bf9\u805a\u9170\u80fa\u8fdb\u884c\u540e\u4fee\u9970\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u901a\u8fc7\u53d6\u4ee3\u53cd\u5e94\u8fdb\u884c\u7684\u805a\u5408\u540e\u4fee\u9970\u751a\u81f3\u4e0d\u9700\u8981\u7eaf\u5316\u805a\u5408\u7269\uff0c\u53ef\u4ee5\u91c7\u7528\u201c\u4e00\u9505\u6cd5\u201d\u8fdb\u884c\u3002\u56e0\u6b64\uff0c\u8be5\u6cd5\u63d0\u4f9b\u4e86\u805a\u5408\u7269\u540e\u529f\u80fd\u5316\u7684\u4fbf\u5229\u5e73\u53f0\uff0c\u4e3a\u5176\u5e94\u7528\u63d0\u4f9b\u4e86\u5e7f\u9614\u7684\u524d\u666f\u3002<strong>\u6d59\u6c5f\u5927\u5b66\u5f20\u6d01\u4e3a\u7b2c\u4e00\u4f5c\u8005<\/strong>\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u6c34\u3001\u5f02\u8148\u548c\u6eb4\u4ee3\u7094\u7c7b\u5355\u4f53\u7684\u805a\u5408\u65b9\u6848<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108223 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-49.png\" alt=\"\" width=\"700\" height=\"302\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-49.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-49-300x129.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe2 PI\uff08\u805a\u9170\u80fa\uff09\u7684NMR\u56fe\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108225 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-27.png\" alt=\"\" width=\"700\" height=\"721\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-27.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-27-291x300.png 291w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>A \u7a7a\u6c14\u4e0b\u5236\u5907\u3002 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0B \u6c2e\u6c14\u4e0b\u5236\u5907\u3002<\/p>\n<p><strong>\u56fe3 PI\u7684\u7ea2\u5916\u5149\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108226 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-13.png\" alt=\"\" width=\"700\" height=\"481\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-13.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-13-300x206.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>A \u53cc\u5f02\u8148\u5355\u4f53\uff081a\uff09\u3002 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 B \u53cc\u6eb4\u4ee3\u7094\u7c7b\u5355\u4f53\uff082a\uff09\u3002 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0C PI\u3002<\/p>\n<p><strong>\u56fe4\u6a21\u578b\u5316\u5408\u72695\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108227 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/4-12.png\" alt=\"\" width=\"734\" height=\"159\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/4-12.png 734w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/4-12-300x65.png 300w\" sizes=\"(max-width: 734px) 100vw, 734px\" \/><\/p>\n<p><strong>\u56fe5 PI\u7684\u7ea2\u5916\u5149\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108228 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-10.png\" alt=\"\" width=\"700\" height=\"1173\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-10.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-10-179x300.png 179w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-10-611x1024.png 611w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe6 <sup>13<\/sup>C NMR\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108229 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-9.png\" alt=\"\" width=\"700\" height=\"1213\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-9.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-9-173x300.png 173w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-9-591x1024.png 591w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe7 \u805a\u5408\u7269\u56fa\u4f53\u8584\u819c\u7684\u5149\u6298\u5c04\u5149\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108230 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/7-7.png\" alt=\"\" width=\"700\" height=\"397\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/7-7.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/7-7-300x170.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe8 \u5149\u81f4\u53d1\u5149\u5149\u8c31\uff08PL\u8c31\uff09<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108231 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-6.png\" alt=\"\" width=\"700\" height=\"330\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-6.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-6-300x141.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>A PI\u5728THF\u548cTHF \/\u6c34\u6df7\u5408\u7269\u4e2d\u7684PL\u8c31\u3002<\/p>\n<p>B \u5728THF \/\u6c34\u6df7\u5408\u7269\u4e2d\u76f8\u5bf9PL\u5f3a\u5ea6\u4e0e\u6c34\u542b\u91cf\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n<p><strong>\u56fe9 \u901a\u8fc7\u4e0d\u540c\u53cd\u5e94\u8fdb\u884cPI\u540e\u4fee\u9970\u8def\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-108232 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/9-4.png\" alt=\"\" width=\"700\" height=\"413\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/9-4.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/9-4-300x177.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u672c\u9879\u5de5\u4f5c\uff0c\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u9996\u6b21\u5b9e\u73b0\u4e86\u5c06\u6c34\u4f5c\u4e3a\u5355\u4f53\u4e4b\u4e00\u7684\u805a\u5408\u53cd\u5e94\uff0c\u540c\u65f6\uff0c\u6b64\u7c7b\u65b0\u578b\u805a\u5408\u53cd\u5e94\u63d0\u4f9b\u4e86\u4e00\u6761\u5408\u6210\u805a\u9170\u80fa\u7684\u65b0\u65b9\u6cd5\u3002\u6b64\u5916\uff0c\u6240\u5f97\u7684\u805a\u9170\u80fa\u53ef\u901a\u8fc7\u591a\u79cd\u7b80\u5355\u7684\u65b9\u6cd5\u8fdb\u884c\u540e\u4fee\u9970\uff0c\u4e3a\u5176\u529f\u80fd\u5316\u63d0\u4f9b\u4e86\u5e7f\u9614\u7684\u5e73\u53f0\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/acs.macromol.7b01592\" target=\"_blank\" rel=\"noopener\">Facile Polymerization of Water and Triple-Bond Based Monomers toward Functional Polyamides<\/a><br \/>\n \uff08Macromolecules \uff0c2017\uff0c DOI:10.1021\/acs.macromol.7b01592\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u5b66\u672f\u7ec4\u6c34\u624b\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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