{"id":107731,"date":"2017-10-23T06:30:27","date_gmt":"2017-10-22T22:30:27","guid":{"rendered":"\/\/m.iemloyee.com\/?p=107731"},"modified":"2017-10-21T08:44:14","modified_gmt":"2017-10-21T00:44:14","slug":"%e6%b8%85%e5%8d%8e%e5%bc%a0%e5%bc%banat-commun-p%e5%8c%ba%e9%87%91%e5%b1%9e%e8%b0%83%e6%8e%a7%e4%b8%8b%e5%af%8c%e8%a1%a8%e9%9d%a2%e7%bc%ba%e9%99%b7%e7%9a%84%e9%92%99%e9%92%9b%e7%9f%bf%e6%b0%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=107731","title":{"rendered":"\u6e05\u534e\u5f20\u5f3aNat. Commun: 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mA cm<sup>-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u8fc7\u7535\u4f4d\u4ec5\u4e3a350 mV\uff0c\u540c\u7b49\u6761\u4ef6\u4e0b\u76f8\u6bd4\u4e8e\u8d35\u91d1\u5c5eIrO<sub>2<\/sub>\u50ac\u5316\u5242\u8fc7\u7535\u4f4d\u51cf\u5c11\u4e8620 mV\uff0c\u5176\u53cd\u5e94\u52a8\u529b\u5b66\u4e5f\u6709\u660e\u663e\u63d0\u5347\u3002\u540c\u65f6\uff0cSnNiFe\u50ac\u5316\u5242\u7684\u6c27\u6790\u51fa\u7a33\u5b9a\u6027\u4e5f\u4f18\u4e8eIrO<sub>2<\/sub>\uff0c\u5728\u521d\u59cb\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm<sup>-2<\/sup>\u7684\u6052\u7535\u4f4d\u6761\u4ef6\u4e0b\u5de5\u4f5c20000 s\u540e\uff0cSnNiFe\u53ef\u4ee5\u4fdd\u630160%\u7684\u521d\u59cb\u7535\u6d41\u5bc6\u5ea6\uff0c\u800c\u76f8\u540c\u6761\u4ef6\u4e0bIrO<sub>2<\/sub>\u53ea\u80fd\u4fdd\u630140%\u3002\u4f5c\u8005\u8fdb\u4e00\u6b65\u5730\u6784\u5efa\u4e86\u201c\u6c27\u6c60\u201d\u6a21\u578b\u6765\u63cf\u8ff0\u5bcc\u7f3a\u9677\u8868\u9762\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\uff0c\u5176\u4e2d\u53cd\u5e94\u7269\u878d\u5165\u8868\u9762\u6c27\u6c60\u5e76\u52a0\u901f\u7535\u5316\u5b66\u53cd\u5e94\u6700\u7ec8\u5bfc\u81f4\u4ea7\u7269\u4ece\u6c27\u6c60\u4e2d\u6790\u51fa\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Regulating\u00a0p-block metals in perovskite nanodots for efficient electrocatalytic water oxidation<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Nature Communications<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\uff1a<\/strong><strong>p<\/strong><strong>\u533a\u91d1\u5c5e\u8c03\u63a7\u4e0b\u9499\u949b\u77ff\u8868\u9762\u7f3a\u9677\u6784\u7b51\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-107732\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u7247-1-2.jpg\" alt=\"\" width=\"700\" height=\"201\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u7247-1-2.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u7247-1-2-300x86.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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\u4ecb\u5b54\u77f3\u58a8\u70ef\u9aa8\u67b6\u8d1f\u8f7d\u7684\u9499\u949b\u77ff\u7eb3\u7c73\u9897\u7c92\u7684HAADF-STEM\u7167\u7247, \u6bd4\u4f8b\u5c3a\u4e3a20 nm\u3002<\/p>\n<p>(c) \u4ecb\u5b54\u77f3\u58a8\u70ef\u9aa8\u67b6\u8d1f\u8f7d\u7684\u9499\u949b\u77ff\u7eb3\u7c73\u9897\u7c92\u7684TEM\u7167\u7247\uff0c\u6bd4\u4f8b\u5c3a\u4e3a5 nm\uff0c\u63d2\u56fe\u4e3a\u9499\u949b\u77ff\u7eb3\u7c73\u9897\u7c92\u7684\u7c92\u5f84\u5206\u5e03\u56fe\u3002<\/p>\n<p>(d) \u9499\u949b\u77ff\u7eb3\u7c73\u9897\u7c92\u7684\u9ad8\u5206\u8fa8TEM\u7167\u7247\uff0c\u6bd4\u4f8b\u5c3a\u4e3a2 nm\u3002<\/p>\n<p>(e) \u9499\u949b\u77ff\u7eb3\u7c73\u9897\u7c92\u7684XRD\u56fe\u8c31\u3002<\/p>\n<p><strong>\u56fe\u4e09\uff1a\u9499\u949b\u77ff\u7535\u50ac\u5316\u5242\u7684<\/strong><strong>p<\/strong><strong>\u533a\u91d1\u5c5e\u6d3b\u5316\u4e0e\u6c27\u6790\u51fa\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-107734\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u7247-3-2.jpg\" alt=\"\" width=\"700\" height=\"524\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u7247-3-2.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u7247-3-2-300x225.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>(a) p\u533a\u91d1\u5c5e\u8c03\u63a7\u4e0b\u9499\u949b\u77ff\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6d3b\u5316\u66f2\u7ebf\uff0c\u521d\u59cb\u7535\u6d41\u5bc6\u5ea6\u4e3a5.0 mA cm<sup>-2<\/sup>, \u7535\u89e3\u6db2\u4e3a\u6c27\u6c14\u9971\u548c\u76840.10 M KOH\u6c34\u6eb6\u6db2\u3002<\/p>\n<p>(b,c) p\u533a\u91d1\u5c5e\u6d3b\u5316\u524d\u540e\u7684\u9499\u949b\u77ff\u50ac\u5316\u5242\u4e0e\u4e8c\u6c27\u5316\u94f1\u50ac\u5316\u5242\u7684\u6c27\u6790\u51fa\u6781\u5316\u66f2\u7ebf\u4e0eTafel\u66f2\u7ebf\u3002<\/p>\n<p>(d) 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href=\"http:\/\/www.nature.com\/articles\/s41467-017-01053-x\" target=\"_blank\" rel=\"noopener\">Regulating p-block metals in perovskite nanodots for efficient electrocatalytic water oxidation<\/a> (Nat. Commun., <strong>2017<\/strong>, 8, 934, DOI: 10.1038\/s41467-017-01053-x)<\/p>\n<p><strong>\u76f8\u5173\u5de5\u4f5c\u5bfc\u8bfb\uff1a<\/strong><\/p>\n<p>\u6e05\u534e\u5316\u5de5\u7cfb\u5b9e\u73b0\u201c\u6c34\u706b\u76f8\u5bb9\u201d\u9884\u6c27\u5316\u5236\u5907\u9499\u949b\u77ff\u50ac\u5316\u5242<\/p>\n<p><a href=\"http:\/\/news.tsinghua.edu.cn\/publish\/thunews\/9659\/2016\/20161031101610179288693\/20161031101610179288693_.html\" target=\"_blank\" rel=\"noopener\">http:\/\/news.tsinghua.edu.cn\/publish\/thunews\/9659\/2016\/20161031101610179288693\/20161031101610179288693_.html<\/a><\/p>\n<p>Angew. Chem. Int. Ed. \u6e56\u5357\u5927\u5b66\u738b\u53cc\u5370\u6559\u6388\uff1a\u5c42\u72b6\u53cc\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u5e72\u6cd5\u5265\u79bb\u542b\u6709\u591a\u79cd\u7a7a\u4f4d\u4f5c\u4e3a\u9ad8\u6548\u6c27\u6790\u51fa\u7535\u50ac\u5316\u5242<\/p>\n<p>\/\/m.iemloyee.com\/77488.html<\/p>\n<p>\u4e2d\u79d1\u5927\u8c22\u6bc5\u9662\u58ebAdv. 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