{"id":107687,"date":"2017-10-20T08:54:56","date_gmt":"2017-10-20T00:54:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=107687"},"modified":"2017-10-20T08:54:56","modified_gmt":"2017-10-20T00:54:56","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7-%e6%8f%90%e5%8d%87%e6%b0%b4%e7%b3%bb%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8%e7%9a%84%e8%be%93%e5%87%ba%e7%94%b5%e5%8e%8b%e7%9a%84%e7%ad%96%e7%95%a5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=107687","title":{"rendered":"\u5b66\u672f\u5e72\u8d27 | \u63d0\u5347\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8f93\u51fa\u7535\u538b\u7684\u7b56\u7565"},"content":{"rendered":"<p style=\"text-align: center\"><strong>\uff08\u57fa\u4e8e\u4e2d\u5c71\u5927\u5b66\u5362\u9521\u6d2a\u526f\u6559\u6388\u8bfe\u9898\u7ec4<\/strong><strong><em>Chem.-Eur. J.<\/em><\/strong><strong>\u6587\u7ae0\uff09<\/strong><\/p>\n<p style=\"text-align: center\"><span style=\"color: #008080\"><strong>\u3010\u63d0\u5347\u8f93\u51fa\u7535\u538b\u7684\u610f\u4e49\u3011<\/strong><\/span><\/p>\n<p>\u5316\u77f3\u71c3\u6599\u7684\u5feb\u901f\u6d88\u8017\u5bfc\u81f4\u5168\u7403\u9762\u4e34\u4e25\u5cfb\u7684\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\uff0c\u8fdb\u800c\u50ac\u751f\u4e86\u65b0\u80fd\u6e90\u7684\u5f00\u53d1\u5229\u7528\u3002\u8fd1\u5e74\u6765\uff0c\u5404\u79cd\u5404\u6837\u7684\u65b0\u80fd\u6e90\u6280\u672f\uff0c\u4f8b\u5982\u98ce\u80fd\u3001\u592a\u9633\u80fd\u3001\u6f6e\u6c50\u80fd\u7b49\uff0c\u5747\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f46\u662f\u8fd9\u4e9b\u65b0\u80fd\u6e90\u5728\u65f6\u95f4\u3001\u5b63\u8282\u3001\u5730\u57df\u4e0a\u7684\u5206\u5e03\u5b58\u5728\u4e0d\u8fde\u7eed\u548c\u4e0d\u5747\u5300\u6027\u3002\u6b32\u7a33\u5b9a\u5229\u7528\u5b83\u4eec\u5219\u9700\u8981\u5c06\u4e4b\u8f6c\u5316\u4e3a\u53ef\u5b58\u50a8\u7684\u80fd\u6e90\u5f62\u5f0f\uff0c\u5982\u7535\u80fd\uff0c\u4ee5\u4fbf\u8fd0\u8f93\u4ee5\u53ca\u5728\u9700\u8981\u65f6\u91ca\u653e\u4f7f\u7528\u3002\u56e0\u6b64\uff0c\u65b0\u578b\u7535\u80fd\u50a8\u5b58\u88c5\u7f6e\uff0c\u5982\u9502\u79bb\u5b50\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u7684\u53d1\u5c55\u5728\u8fd1\u5e74\u6765\u5f97\u5230\u4e86\u6781\u5927\u7684\u63a8\u52a8\u3002<\/p>\n<p>\u8d85\u7ea7\u7535\u5bb9\u5668\u4ee5\u5176\u9ad8\u529f\u7387\u5bc6\u5ea6\u3001\u5feb\u901f\u5145\u653e\u7535\u80fd\u529b\u4ee5\u53ca\u8d85\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u7279\u70b9\u4f7f\u5f97\u5176\u4e0e\u53ef\u5145\u7535\u7535\u6c60\u533a\u522b\u5f00\u6765\u5e76\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u79d1\u7814\u5173\u6ce8\u3002\u73b0\u9636\u6bb5\u8d85\u7ea7\u7535\u5bb9\u5668\u53d1\u5c55\u7684\u4e3b\u8981\u74f6\u9888\u5728\u4e8e\u5176\u8f83\u4f4e\u7684\u80fd\u91cf\u5bc6\u5ea6\u96be\u4ee5\u6ee1\u8db3\u5404\u79cd\u7535\u5b50\u5668\u4ef6\u5bf9\u957f\u7eed\u822a\u80fd\u529b\u7684\u9700\u6c42\u3002\u636e\u516c\u5f0f<em>E<\/em>=0.5<em>CV<\/em><sup>2<\/sup>\uff0c\u63d0\u9ad8\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u80fd\u91cf\u5bc6\u5ea6\uff08<em>E<\/em>\uff09\u53ef\u4ee5\u4ece\u63d0\u5347\u5668\u4ef6\u7535\u5bb9\uff08<em>C<\/em>\uff09\u548c\/\u6216\u63d0\u5347\u5668\u4ef6\u8f93\u51fa\u7535\u538b\uff08<em>V<\/em>\uff09\u4e24\u4e2a\u65b9\u9762\u5b9e\u73b0\u3002\u5148\u524d\u7684\u7814\u7a76\u57fa\u672c\u5c06\u91cd\u70b9\u653e\u5728\u5229\u7528\u7535\u6781\u7ed3\u6784\u8bbe\u8ba1\u3001\u6750\u6599\u590d\u5408\u3001\u6539\u6027\u4fee\u9970\u7b49\u624b\u6bb5\u63d0\u5347\u7535\u6781\u7684\u6bd4\u5bb9\u91cf\u4e0a\uff0c\u8bb8\u591a\u7efc\u8ff0\u4e5f\u5bf9\u6b64\u8fdb\u884c\u4e86\u603b\u7ed3\u3002\u7136\u800c\u5bf9\u4e8e\u8c03\u8282\u8d85\u7ea7\u7535\u5bb9\u5668\u8f93\u51fa\u7535\u538b\u7684\u7814\u7a76\u548c\u8ba4\u8bc6\u5c1a\u4e3a\u7f3a\u4e4f\u3002<\/p>\n<p>\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8f93\u51fa\u7535\u538b\u540c\u6240\u4f7f\u7528\u7684\u7535\u89e3\u8d28\u606f\u606f\u76f8\u5173\u3002\u6839\u636e\u4f7f\u7528\u7535\u89e3\u6db2\u7684\u6210\u5206\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u89e3\u8d28\u4e3b\u8981\u53ef\u5206\u4e3a\u6709\u673a\u7cfb\u4e0e\u6c34\u7cfb\uff08\u8fd1\u4e9b\u5e74\u6765\u53d1\u5c55\u5f00\u6765\u7684\u8fd8\u6709\u79bb\u5b50\u6db2\u4f53\uff09\u3002\u6709\u673a\u7535\u89e3\u8d28\u4e00\u822c\u53ef\u627f\u53d72.5 &#8211; 4 V\u7684\u7535\u538b\u800c\u4e0d\u5206\u89e3\uff0c\u56e0\u800c\u4f7f\u7528\u6709\u673a\u7535\u89e3\u6db2\u662f\u4e00\u79cd\u975e\u5e38\u6709\u6548\u7684\u63d0\u5347\u8d85\u7ea7\u7535\u5bb9\u5668\u80fd\u91cf\u5bc6\u5ea6\u7684\u65b9\u6cd5\u3002\u7136\u800c\u6709\u673a\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u5de5\u4f5c\u7535\u538b\u7684\u63d0\u5347\u5f80\u5f80\u4f34\u968f\u7740\u5bb9\u91cf\u548c\u529f\u7387\u7684\u635f\u5931\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u6709\u673a\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7ec4\u88c5\u590d\u6742\uff08\u5982\u9700\u8981\u5728\u65e0\u6c34\u65e0\u6c27\u73af\u5883\u4e0b\u7ec4\u88c5\uff09\u3001\u4ef7\u683c\u6602\u8d35\u3001\u800c\u4e14\u7535\u89e3\u8d28\u81ea\u8eab\u5177\u6709\u73af\u5883\u6c61\u67d3\u6027\u548c\u6613\u71c3\u6613\u7206\u6027\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5927\u5bb9\u91cf\u3001\u9ad8\u529f\u7387\u3001\u5ec9\u4ef7\u3001\u5b89\u5168\u3001\u7eff\u8272\u73af\u4fdd\u7684\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u53d1\u5c55\u4fbf\u66f4\u5177\u5438\u5f15\u529b\u3002\u53d1\u5c55\u9ad8\u529f\u7387\u3001\u9ad8\u80fd\u91cf\u3001\u957f\u5faa\u73af\u7a33\u5b9a\u7684\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u6210\u4e3a\u4e86\u73b0\u9636\u6bb5\u7684\u53d1\u5c55\u8d8b\u52bf\u3002\u4f46\u6c34\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u7535\u4f4d\u4ec5\u4e3a1.23 V\uff0c\u6545\u800c\u7406\u8bba\u4e0a\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8f93\u51fa\u7535\u538b\u5728\u4fdd\u8bc1\u7535\u89e3\u8d28\u4e0d\u5206\u89e3\u7684\u524d\u63d0\u4e0b\u96be\u4ee5\u8d85\u8fc7\u6b64\u7535\u4f4d\u3002\u56e0\u6b64\uff0c\u63d0\u5347\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u5de5\u4f5c\u7535\u538b\u6210\u4e3a\u4e86\u5b9e\u73b0\u7814\u53d1\u9ad8\u6027\u80fd\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5173\u952e\u3002<\/p>\n<p>\u672c\u6587\u4ee5\u8fd1\u65e5\u4e2d\u5c71\u5927\u5b66\u5362\u9521\u6d2a\u526f\u6559\u6388\u548c\u4e8e\u660e\u6d69\u535a\u58eb\u5171\u540c\u53d1\u8868\u7684\u9898\u4e3a \u201cNew Insights into the Operating Voltage of Aqueous Supercapacitors\u201d\u7684\u6587\u7ae0[1]\u4f5c\u4e3a\u57fa\u7840\uff0c\u5bf9\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u5de5\u4f5c\u7535\u538b\u7684\u5f71\u54cd\u56e0\u7d20\u8fdb\u884c\u4ecb\u7ecd\u3002\u540c\u65f6\u5c06\u91cd\u70b9\u8ba8\u8bba\u5982\u4f55\u63d0\u5347\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u4f4d\u7a97\u53e3\u3002<\/p>\n<p style=\"text-align: center\"><span style=\"color: #008080\"><strong>\u3010\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8f93\u51fa\u7535\u538b\u3011<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107688 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-69.jpg\" alt=\"\" width=\"592\" height=\"450\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-69.jpg 1268w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-69-300x228.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-69-768x583.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-69-1024x778.jpg 1024w\" sizes=\"(max-width: 592px) 100vw, 592px\" \/><\/p>\n<p>\u4e0a\u56fe\u5c55\u793a\u4e86\u7535\u5bb9\u5668\u7535\u6781\u5b9e\u9645\u7535\u4f4d\u53d8\u5316\uff08Practical Potential Range of SCs\uff09\u3001\u7535\u5bb9\u5668\u7535\u6781\u7406\u8bba\u53ef\u7528\u7535\u4f4d\u533a\u95f4\uff08Available Potential Range of SCs\uff09\u4e0e\u7535\u6781\u8868\u73b0\u7535\u5bb9\u6027\u8d28\u7684\u7535\u4f4d\u8303\u56f4\uff08Capacitive Potential Range\uff09\u4ee5\u53ca\u7535\u89e3\u8d28\u7a33\u5b9a\u7535\u4f4d\u8303\u56f4\uff08Stable Potential Range of Electrolyte\uff09\u7684\u5173\u7cfb\u3002[1]<\/p>\n<ul>\n<li><span style=\"color: #ff00ff\">\u6700\u5de6\u4fa7\u7c89\u7ea2\u8272\u7ad6\u7ebf<\/span>\uff1a\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7535\u4f4d\uff0c\u5373\u53ef\u4fdd\u8bc1\u7535\u89e3\u8d28\u4e0d\u5206\u89e3\u65f6\u7684\u6700\u4f4e\u7535\u4f4d\u3002<\/li>\n<li><span style=\"color: #ff0000\">\u5de6\u4fa7\u7ea2\u8272\u865a\u7ebf<\/span>\uff1a\u8d1f\u6781\u6240\u80fd\u7a33\u5b9a\u8868\u73b0\u51fa\u7535\u5bb9\u6027\u80fd\u7684\u6700\u4f4e\u7535\u4f4d\u3002\u4f4e\u4e8e\u6b64\u7535\u4f4d\u53ef\u5bf9\u8d1f\u6781\u9020\u6210\u4e0d\u53ef\u9006\u7684\u7834\u574f\u6216\u5bfc\u81f4HER\u53cd\u5e94\u5728\u8d1f\u6781\u8868\u9762\u53d1\u751f\u3002<\/li>\n<li><span style=\"color: #ff0000\">\u7ea2\u8272\u65b9\u6846<\/span>\uff1a\u8d1f\u6781\u6240\u80fd\u8868\u73b0\u51fa\u7535\u5bb9\u884c\u4e3a\u7684\u7535\u4f4d\u8303\u56f4\u3002<\/li>\n<li><span style=\"color: #3366ff\">\u84dd\u8272\u65b9\u6846<\/span>\uff1a\u8d1f\u6781\u6240\u80fd\u8868\u73b0\u51fa\u7535\u5bb9\u884c\u4e3a\u7684\u7535\u4f4d\u8303\u56f4\u3002<\/li>\n<li><span style=\"color: #008080\">\u53f3\u4fa7\u8349\u7eff\u8272\u7ad6\u7ebf<\/span>\uff1a\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u53d1\u751f\u65f6\u7684\u7535\u4f4d\uff0c\u5373\u53ef\u4fdd\u8bc1\u7535\u89e3\u8d28\u4e0d\u5206\u89e3\u65f6\u7684\u6700\u9ad8\u7535\u4f4d\u3002<\/li>\n<\/ul>\n<p>\u7535\u5bb9\u5668\u5145\u7535\u65f6\uff0c\u5668\u4ef6\u7535\u6781\u7684\u7535\u4f4d\u4eceP<sub>0V<\/sub>\uff08\u5668\u4ef6\u8f93\u51fa\u7535\u538b\u4e3a0 V\u65f6\u7535\u6781\u7684\u7535\u4f4d\uff09\u6240\u5728\u7684\u4f4d\u7f6e\u5f00\u59cb\uff0c\u8d1f\u6781\u7535\u4f4d\u5411\u4f4e\u7535\u4f4d\u79fb\u52a8\uff0c\u6b63\u6781\u7535\u4f4d\u5411\u9ad8\u7535\u4f4d\u79fb\u52a8\u3002\u5728\u56fe\u793a\u60c5\u51b5\u4e2d\uff0c\u6b63\u6781\u7535\u4f4d\u9996\u5148\u8fbe\u5230\u58a8\u7eff\u8272\u7ad6\u7ebf\u4f4d\u7f6e\uff0c\u6b64\u65f6\u82e5\u5668\u4ef6\u7535\u4f4d\u518d\u5347\u9ad8\uff08\u5373\u5bf9\u5668\u4ef6\u7ee7\u7eed\u5145\u7535\uff09\uff0c\u5219\u4f1a\u9020\u6210\u6c27\u6c14\u5728\u6b63\u6781\u8868\u9762\u4ea7\u751f\uff08OER\u53cd\u5e94\uff09\uff0c\u6545\u6b64\u65f6\u5668\u4ef6\u5e94\u505c\u6b62\u5145\u7535\u3002\u9700\u8981\u6307\u51fa\u7684\u662f\u8fd9\u65f6\u8d1f\u6781\u7684\u7535\u4f4d\u5c1a\u672a\u8fbe\u5230HER\u7684\u7535\u4f4d\u3002\u6b64\u65f6\u5668\u4ef6\u80fd\u591f\u8f93\u51fa\u7684\u6700\u5927\u7535\u538b\u4e3a\u6b63\u6781\u7535\u538b\u548c\u8d1f\u6781\u7535\u538b\u7684\u5dee\u503c\u3002\u7531\u56fe\u53ef\u89c1\uff0c\u8be5\u53ef\u8f93\u51fa\u6700\u5927\u7535\u538b\u8f83\u7406\u8bba\u53ef\u8fbe\u5230\u7684\u7535\u538b\u5c0f\u3002<\/p>\n<p>\u7531\u56fe\u53ef\u89c1\uff0c\u51b3\u5b9a\u4e00\u4e2a\u8d85\u7ea7\u7535\u5bb9\u5668\u5668\u4ef6\u53ef\u8f93\u51fa\u7684\u6700\u5927\u7535\u538b\u7684\u56e0\u7d20\u6709:<\/p>\n<p>1\uff09\u7535\u89e3\u8d28\u81ea\u8eab\u7a33\u5b9a\u7684\u7535\u4f4d\u8303\u56f4\uff1b<\/p>\n<p>2\uff09\u4e24\u7535\u6781\u7535\u5bb9\u884c\u4e3a\u7684\u7535\u4f4d\u8303\u56f4\uff1b<\/p>\n<p>3\uff09P<sub>0V<\/sub>\u7684\u4f4d\u7f6e\uff1b<\/p>\n<p>4\uff09\u4e24\u7535\u6781\u7535\u4f4d\u53d8\u5316\u7684\u901f\u7387\u3002<\/p>\n<p style=\"text-align: center\"><span style=\"color: #008080\"><strong>\u3010\u62d3\u5bbd\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u6700\u5927\u8f93\u51fa\u7535\u538b\u7684\u65b9\u6cd5\u3011<\/strong><\/span><\/p>\n<p>\u603b\u4f53\u800c\u8a00\uff0c\u76f8\u5173\u65b9\u6cd5\u53ef\u5206\u4e3a\u4e24\u7c7b\uff1a<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u4e00\u3001\u589e\u5927<\/strong><strong>HER<\/strong><strong>\u548c<\/strong><strong>OER<\/strong><strong>\u7684\u8d85\u7535\u52bf<\/strong><\/span><\/p>\n<p><span style=\"color: #ff0000\"><strong>\u4e8c\u3001\u6700\u5927\u9650\u5ea6\u5730\u62d3\u5bbd\u5b9e\u9645\u6700\u5927\u53ef\u8f93\u51fa\u7535\u538b\uff0c\u4f7f\u4e4b\u4e0e\u7406\u8bba\u53ef\u8fbe\u5230\u7684\u6700\u5927\u7535\u538b\u63a5\u8fd1<\/strong><\/span><\/p>\n<p>\u76ee\u524d\u4e3b\u8981\u53ef\u901a\u8fc7\u6539\u53d8\u7535\u89e3\u8d28\u548c\u7535\u6781\u7684\u6027\u8d28\u6765\u5b9e\u73b0\u4e0a\u8ff0\u4e00\u70b9\u6216\u4e24\u70b9\u3002<\/p>\n<p style=\"text-align: center\"><span style=\"color: #0000ff\"><strong>\u3010\u4ece\u7535\u89e3\u8d28\u5165\u624b\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #ff9900\"><strong>1 | <\/strong><strong>\u6539\u53d8\u7535\u89e3\u6db2<\/strong><strong>pH<\/strong><strong>\u503c<\/strong><\/span><\/p>\n<p>\u636e\u80fd\u65af\u7279\u65b9\u7a0b\uff08Nernst Equation\uff09\u53ef\u77e5HER\u548cOER\u53cd\u5e94\u7684\u7535\u4f4d\u5206\u522b\u548c\u6c22\u79bb\u5b50\u6d53\u5ea6\u548c\u6c22\u6c27\u6839\u6d53\u5ea6\u6709\u5173\u3002\u56e0\u800c\u6539\u53d8\u7535\u89e3\u8d28\u7684pH\u503c\u53ef\u4ee5\u6709\u6548\u6539\u53d8\u8d85\u7535\u52bf\u7684\u5927\u5c0f\u3002\u6b63\u5e38\u60c5\u51b5\u4e0b\uff0c\u7535\u89e3\u8d28pH\u503c\u6108\u5c0f\uff0c\u5219HER\u53cd\u5e94\u6108\u5bb9\u6613\u53d1\u751f\uff0c\u5176\u8d85\u7535\u52bf\u6108\u5c0f\uff08\u56fe1\uff09\u3002\u53cd\u4e4b\uff0c\u5f53\u7535\u89e3\u8d28pH\u503c\u5347\u9ad8\uff0c\u5219OER\u53cd\u5e94\u8d8a\u5bb9\u6613\u53d1\u751f\uff0c\u5176\u8d85\u7535\u52bf\u8d8a\u5c0f\u3002\u901a\u8fc7\u9002\u5f53\u8c03\u63a7pH\u503c\uff0c\u4f7f\u5f97OER\u7535\u4f4d\u548cHER\u7535\u4f4d\u7684\u5dee\u503c\u6700\u5927\u5316\u662f\u5173\u952e\u3002<\/p>\n<p>\u7136\u800c\uff0c\u65e0\u8bba\u662fHER\u8fd8\u662fOER\uff0c\u5176\u81ea\u8eab\u7535\u4f4d\u5927\u5c0f\u5e76\u4e0d\u80fd\u5b8c\u7f8e\u5730\u7528\u80fd\u65af\u7279\u65b9\u7a0b\u6765\u89e3\u91ca\uff08\u56e0\u4e3a\u8be5\u65b9\u7a0b\u4ec5\u8003\u8651\u4e86\u70ed\u529b\u5b66\u56e0\u7d20\uff09\u3002\u4e00\u4e9b\u52a8\u529b\u5b66\u56e0\u7d20\uff0c\u8bf8\u5982\u6c22\u79bb\u5b50\u5728\u7535\u6781\u8868\u9762\u7684\u7535\u5438\u9644\u8fc7\u7a0b\u4ee5\u53ca\u7535\u6781\u8868\u9762\u4e0e\u79bb\u5b50\u6269\u6563\u76f8\u5173\u7684\u8d5d\u7535\u5bb9\u884c\u4e3a\u7b49\u4f1a\u5bf9\u7535\u89e3\u8d28\u8d85\u7535\u52bf\u3001\u7535\u6781\u7535\u5bb9\u884c\u4e3a\u7535\u4f4d\u8303\u56f4\u4ea7\u751f\u660e\u663e\u7684\u5f71\u54cd\u3002\u9700\u8981\u6307\u51fa\u7684\u662f\uff0c\u76ee\u524d\u76f8\u5173\u4e8e\u5bf9\u5404\u79cd\u7535\u6781-\u7535\u89e3\u8d28\u7ec4\u5408\u4f53\u7cfb\u7684pH\u548c\u8d85\u7535\u52bf\u5173\u7cfb\u7684\u7814\u7a76\u8fd8\u5f88\u7f3a\u4e4f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107689 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-63.jpg\" alt=\"\" width=\"597\" height=\"267\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-63.jpg 1270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-63-300x134.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-63-768x343.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-63-1024x458.jpg 1024w\" sizes=\"(max-width: 597px) 100vw, 597px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong>. \u6d3b\u6027\u70ad\u7535\u6781\u5728\uff08a\uff09Li<sub>2<\/sub>SO<sub>4<\/sub>\uff08pH=6.5\uff09\u4e0e\uff08b\uff09BeSO<sub>4<\/sub>\uff08pH=2.1\uff09\u7535\u89e3\u6db2\u4e2d\u4e0d\u540c\u7535\u4f4d\u8303\u56f4\u4e0b\u6d4b\u5f97\u7684\u5faa\u73af\u4f0f\u5b89\uff08CV\uff09\u66f2\u7ebf\u3002\u56fe\u4e2d\u7ea2\u8272\u865a\u7ebf\u6807\u793a\u4e86HER\u53cd\u5e94\u7684\u7535\u4f4d\u3002\u5f53\u7535\u6781\u7535\u4f4d\u4f4e\u4e8e\u7ea2\u8272\u865a\u7ebf\u540e\uff0cCV\u66f2\u7ebf\u51fa\u73b0\u660e\u663e\u7684\u6c22\u79bb\u5b50\u8131\u9644\u5cf0\uff0c\u4f7f\u5f97\u7535\u6781\u504f\u79bb\u7535\u5bb9\u884c\u4e3a\u3002\u53e6\u5916\uff0c\u5f53pH\u51cf\u5c0f\u65f6HER\u7535\u4f4d\u76f8\u5e94\u671d\u6b63\u7535\u4f4d\u65b9\u5411\u79fb\u52a8\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[2]\u3002<\/p>\n<p><span style=\"color: #ff9900\"><strong>2 | <\/strong><strong>\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u6dfb\u52a0\u5242<\/strong><\/span><\/p>\n<p>\u5411\u7535\u89e3\u8d28\u4e2d\u52a0\u5165\u4e00\u5bf9\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7269\u8d28\u662f\u53e6\u4e00\u79cd\u6269\u5c55\u7535\u4f4d\u7a97\u53e3\u7684\u65b9\u6cd5\u3002\u4f7f\u7528\u8fd9\u79cd\u65b9\u6cd5\u7684\u524d\u63d0\u6761\u4ef6\u662f\uff1a<\/p>\n<p>1\uff09\u52a0\u5165\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7269\u8d28\u5fc5\u987b\u4e3a\u6c34\u6eb6\u6027\u4e14\u5177\u6709\u9ad8\u6eb6\u89e3\u5ea6\uff0c\u4e14\u4e0d\u4e0e\u7535\u89e3\u8d28\u53d1\u751f\u53cd\u5e94\uff1b<\/p>\n<p>2\uff09\u52a0\u5165\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7269\u8d28\u5fc5\u987b\u5728\u81f3\u5c11\u4e00\u4e2a\u7535\u6781\u4e0a\u53d1\u751f\u53cd\u5e94\uff08\u56fe2a\uff09\uff1b<\/p>\n<p>3\uff09\u52a0\u5165\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7269\u8d28\u9700\u5177\u6709\u8f83\u5feb\u7684\u53cd\u5e94\u901f\u7387\uff0c\u4e0d\u80fd\u8fc7\u5927\u5730\u5236\u7ea6\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5feb\u901f\u5145\u653e\u7535\u7684\u80fd\u529b\uff1b<\/p>\n<p>4\uff09\u52a0\u5165\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7269\u8d28\u7684\u53cd\u5e94\u7535\u4f4d\u9700\u63a5\u8fd1\u6c34\u6eb6\u6db2\u7684HER\u548c\/\u6216OER\u7535\u4f4d\uff0c\u5e76\u80fd\u501f\u52a9\u81ea\u8eab\u7684\u5feb\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u6291\u6b62HER\u548c\/\u6216OER\u7684\u53d1\u751f\u3002<\/p>\n<p>\u56fe2b\u5c55\u793a\u4e86\u5e38\u89c1\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u5bf9\u7684\u53cd\u5e94\u7535\u4f4d\u3002\u5982\u9760\u8fd1OER\u7535\u4f4d\u7684Fe<sup>3+<\/sup>\/Fe<sup>2+<\/sup>\u6c27\u5316\u8fd8\u539f\u5bf9\u5df2\u5728\u6db2\u6d41\u7535\u6c60\uff08Flow Battery\uff09\u4e2d\u6709\u6240\u5e94\u7528\u3002[3]<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107690 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-51.jpg\" alt=\"\" width=\"596\" height=\"564\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-51.jpg 1268w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-51-300x284.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-51-768x726.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/3-51-1024x968.jpg 1024w\" sizes=\"(max-width: 596px) 100vw, 596px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong>. \uff08a\uff09\u7535\u89e3\u6db2\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u5bf9\u7684\u7535\u5316\u5b66\u50a8\u80fd\u673a\u7406\u793a\u610f\u56fe\u3002\uff08b\uff09\u591a\u79cd\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u5bf9\u5728\u9178\u6027\uff08\u7ea2\u70b9\uff09\u3001\u4e2d\u6027\uff08\u7eff\u70b9\uff09\u3001\u78b1\u6027\uff08\u84dd\u70b9\uff09\u7535\u89e3\u6db2\u4e2d\u7684\u8fd8\u539f\u7535\u4f4d\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[4]\u3002<\/p>\n<p><span style=\"color: #ff9900\"><strong>3 | Water-in-Salt<\/strong><strong>\u578b\u7535\u89e3\u6db2<\/strong><\/span><\/p>\n<p>\u5f53\u7535\u89e3\u8d28\u6d53\u5ea6\u8f83\u7a00\u65f6\uff0c\u79bb\u5b50\uff08\u7279\u522b\u662f\u9633\u79bb\u5b50\uff09\u5468\u56f4\u4f1a\u5f62\u6210\u6c34\u5408\u5c42\u3002\u8be5\u6c34\u5408\u5c42\u4e2d\u5305\u542b\u5927\u91cf\u6c34\u5206\u5b50\uff08\u56fe3a\u6240\u793a\uff09\u3002\u5f53\u79bb\u5b50\u540c\u7535\u6781\u76f8\u4e92\u4f5c\u7528\u65f6\uff0c\u5904\u4e8e\u6c34\u5408\u5c42\u4e2d\u7684\u6c34\u5206\u5b50\u5c06\u201c\u9996\u5f53\u5176\u51b2\u201d\u5730\u53c2\u4e0eOER\u6216HER\u53cd\u5e94\u3002\u7136\u800c\u8fd1\u5e74\u6765\u7814\u7a76\u8005\u53d1\u73b0\u5f53\u67d0\u4e9b\u7535\u89e3\u8d28\uff08\u5982\u56fe3b\u6240\u793a\u7684\u4e09\u6c1f\u7532\u78fa\u9170\u9502\uff0cLiTFSI\uff09\u7684\u6d53\u5ea6\u8fbe\u5230\u8fd1\u9971\u548c\u7684\u65f6\u5019\uff0c\u5176\u4e2d\u7684\u9634\u79bb\u5b50\u53ef\u4ee5\u88ab\u201c\u6324\u5165\u201d\u6c34\u5408\u5c42\uff0c\u4f7f\u5f97\u6c34\u5408\u5c42\u4e2d\u7684\u6c34\u5206\u5b50\u6570\u91cf\u51cf\u5c11\uff0c\u6d53\u5ea6\u964d\u4f4e\uff0c\u4ece\u800c\u589e\u5927OER\u6216HER\u53cd\u5e94\u7684\u8d85\u7535\u52bf\u3002\u8fd9\u79cd\u8fd1\u9971\u548c\u7684\u7535\u89e3\u8d28\u88ab\u79f0\u4e3a\u201cWater-in-Salt\u201d\uff0c\u8868\u793a\u6b64\u65f6Salt\u4f5c\u4e3a\u6eb6\u5242\uff0cWater\u4f5c\u4e3a\u6eb6\u8d28\u3002\u4f46\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u6b64\u65f6\u6c34\u5206\u5b50\u7684\u6570\u91cf\u4ecd\u8fdc\u8fdc\u8d85\u8fc7\u79bb\u5b50\u7684\u6570\u91cf\uff0c\u53ea\u662f\u6c34\u5206\u5b50\u5728\u79bb\u5b50\u8868\u9762\u6c34\u5408\u5c42\u4e2d\u7684\u6d53\u5ea6\u6216\u6570\u91cf\u51cf\u5c0f\u3002<\/p>\n<p>Water-in-Salt\u7535\u89e3\u8d28\u4f7f\u5f97\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u8f93\u51fa\u540c\u6709\u673a\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u8fd1\u7684\u7535\u538b\u6210\u4e3a\u53ef\u80fd\u3002\u6700\u65e9\u5c55\u793a\u8fd9\u4e2a\u6982\u5ff5\u7684\u6587\u7ae0\u53d1\u8868\u4e8e2015\u5e74\u7684Science\u671f\u520a\u3002[5] \u524d\u4e0d\u4e45\u8be5\u8bfe\u9898\u7ec4\u5c06Water-in-Salt\u7535\u89e3\u8d28\u548c\u9ad8\u5206\u5b50\u8584\u819c\u8054\u7528\uff0c\u5df2\u7ecf\u6210\u529f\u628a\u6c34\u7cfb\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u7684\u6700\u5927\u8f93\u51fa\u7535\u538b\u63d0\u9ad8\u5230\u4e864.0 V\u3002[6]<\/p>\n<p>\u7b14\u8005\u66fe\u5c31Water-in-Salt\u7535\u89e3\u8d28\u6a21\u578b\u63d0\u51fa\u7684\u201c\u5fc3\u8def\u5386\u7a0b\u201d\u91c7\u8bbf\u8fc7\u6587\u7ae0\u901a\u8baf\u4f5c\u8005\u4e4b\u4e00\u7684\u8bb8\u5eb7\u7814\u7a76\u5458\uff0c\u611f\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u4ee5\u79fb\u6b65\u7b14\u8005\u7684\u4e2a\u4eba\u7f51\u7ad9\u3002[7]<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107691 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/4-48.jpg\" alt=\"\" width=\"516\" height=\"386\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/4-48.jpg 516w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/4-48-300x224.jpg 300w\" sizes=\"(max-width: 516px) 100vw, 516px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong>. \uff08a\uff09Li<sup>+<\/sup>\u5728\u666e\u901a\u6c34\u6eb6\u6db2\u4e0e\uff08b\uff09Water-in-Salt\u578b\u6c34\u6eb6\u6db2\u4e2d\u7684\u6eb6\u5242\u5316\u6a21\u578b\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[5]\u3002<\/p>\n<p style=\"text-align: center\"><span style=\"color: #0000ff\"><strong>\u3010\u4ece\u7535\u6781\u5165\u624b\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #ff9900\"><strong>1 | <\/strong><strong>\u63d0\u9ad8<\/strong><strong>HER<\/strong><strong>\u8d85\u7535\u4f4d<\/strong><\/span><\/p>\n<p>HER\u53d1\u751f\u5728\u7535\u6781\u548c\u7535\u89e3\u8d28\u754c\u9762\uff0c\u6545\u5176\u8d85\u7535\u52bf\u5927\u5c0f\u4e0d\u4ec5\u53d6\u51b3\u4e8e\u4e4b\u524d\u4ecb\u7ecd\u8fc7\u7684pH\u503c\uff0c\u540c\u7535\u6781\u8868\u9762\u7684\u6027\u8d28\u4e5f\u606f\u606f\u76f8\u5173\u3002HER\u53d1\u751f\u9700\u8981\u7ecf\u8fc7\u6c22\u79bb\u5b50\u7684\u5438\u9644\u548c\u8131\u9644\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u7406\u8bba\u4e0a\u8bb2\uff0c\u82e5\u7535\u6781\u8868\u9762\u5bf9\u6c22\u79bb\u5b50\u7684\u5438\u9644\u4f5c\u7528\u51cf\u5f31\uff0c\u6216\u8005\u6c22\u79bb\u5b50\u8131\u9644\u56f0\u96be\uff0c\u7686\u53ef\u63d0\u9ad8HER\u8d85\u7535\u52bf\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u51cf\u5f31\u5438\u9644\u4f5c\u7528\u548c\u589e\u5927\u8131\u9644\u96be\u5ea6\u662f\u4e24\u4e2a\u5357\u8f95\u5317\u8f99\u7684\u8fc7\u7a0b\uff0c\u5b9e\u9645\u53ea\u80fd\u62e9\u4e00\u800c\u884c\u3002\u76ee\u524d\u8ba1\u7b97\u6a21\u62df\u65b9\u6cd5\u7684\u5e94\u7528\u53ef\u8ba1\u7b97\u79bb\u5b50\u5438\u9644\u548c\u8131\u9644\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\uff0c\u4e3a\u7535\u6781\u7684\u8bbe\u8ba1\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u53c2\u8003\u3002<\/p>\n<p>\u4e0e\u6b64\u540c\u65f6\uff0c\u901a\u8fc7\u8bbe\u8ba1\u7535\u6781\uff0c\u5f15\u5165\u53cd\u5e94\u52a8\u529b\u5b66\u5feb\u901f\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4ee5\u6291\u5236\u6c34\u5206\u89e3\u53cd\u5e94\u4e5f\u662f\u4e00\u79cd\u6709\u6548\u62d3\u5bbd\u8d85\u7ea7\u7535\u5bb9\u5668\u5de5\u4f5c\u7535\u538b\u7684\u65b9\u6cd5\u3002\u56fe4\u5c55\u793a\u7684\u662f\u4e00\u79cd\u94a0\u79bb\u5b50\u5d4c\u5165\u4fee\u9970\u540e\u3001\u53ef\u8fbe\u52301.3 V vs. Ag\/AgCl\u7535\u4f4d\u7684\u4e8c\u6c27\u5316\u9530\u7535\u6781\u7684CV\u66f2\u7ebf\u3002\u5176\u4e0e\u78b3\u5305\u8986\u7684\u56db\u6c27\u5316\u4e09\u94c1\uff08Fe<sub>3<\/sub>O<sub>4<\/sub>@C\uff09\u8d1f\u6781\u7ec4\u6210\u7684\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u7684\u6700\u5927\u8f93\u51fa\u7535\u538b\u5df2\u9ad8\u8fbe2.5 V\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107692 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-32.jpg\" alt=\"\" width=\"600\" height=\"216\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-32.jpg 1270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-32-300x108.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-32-768x276.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/5-32-1024x368.jpg 1024w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong>.\uff08a\uff09Li<sup>+<\/sup>\u5728Na<sub>0.5<\/sub>MnO<sub>2<\/sub>\u4e2d\u7684\u5d4c\u5165\/\u8131\u51fa\u53cd\u5e94\u5bf9\u6c34\u5206\u89e3\u7684\u6291\u5236\u4f5c\u7528\u4f7f\u5176\u7535\u5bb9\u7535\u4f4d\u9ad8\u8fbe1.3 V\u3002\uff08b\uff09\u7ec4\u88c5\u7684Na<sub>0.5<\/sub>MnO<sub>2<\/sub>\/\/Fe<sub>3<\/sub>O<sub>4<\/sub>@C\u975e\u5bf9\u79f0\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u6700\u9ad8\u8f93\u51fa\u7535\u538b\u8fbe\u52302.6 V\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[8]\u3002<\/p>\n<p><span style=\"color: #ff9900\"><strong>2 | <\/strong><strong>\u8c03\u63a7\u6b63\u8d1f\u6781\u6d3b\u6027\u6750\u6599\u8d28\u91cf<\/strong><\/span><\/p>\n<p>\u6b64\u65b9\u6cd5\u7684\u57fa\u672c\u539f\u7406\u662f\u786e\u4fdd\u6b63\u6781\u6240\u80fd\u5b58\u50a8\u7684\u7535\u91cf\u4e0e\u8d1f\u6781\u6240\u80fd\u5b58\u50a8\u7684\u7535\u91cf\u76f8\u7b49\uff08\u56fe5\uff09\u3002\u8bd5\u60f3\u5982\u679c\u4e24\u7535\u6781\u53ef\u5b58\u50a8\u7535\u91cf\u603b\u91cf\u4e0d\u4e00\u81f4\uff0c\u5982\u8d1f\u6781\u50a8\u7535\u91cf\u5c0f\u4e8e\u6b63\u6781\uff0c\u5219\u5f53\u8d1f\u6781\u5b58\u6ee1\u7535\u8377\u540e\uff0c\u6b64\u65f6\u6b63\u6781\u5c1a\u672a\u201c\u88c5\u6ee1\u201d\uff0c\u6545\u6b63\u6781\u7535\u538b\u5c1a\u6709\u4e00\u90e8\u5206\u53ef\u4ee5\u5229\u7528\u7684\u8303\u56f4\u672a\u80fd\u5229\u7528\u3002\u6545\u800c\u53ea\u6709\u5f53\u4e24\u4e2a\u7535\u6781\u540c\u65f6\u8fbe\u5230\u201c\u88c5\u6ee1\u201d\u7684\u72b6\u6001\uff0c\u4e24\u7535\u6781\u53ef\u7528\u7535\u4f4d\u8303\u56f4\u624d\u80fd\u88ab\u5b8c\u5168\u5229\u7528\uff0c\u5668\u4ef6\u8f93\u51fa\u7535\u538b\u624d\u80fd\u8fbe\u5230\u6700\u5927\u3002\u91c7\u7528\u8fd9\u79cd\u65b9\u6cd5\u6539\u53d8\u5668\u4ef6\u6700\u5927\u8f93\u51fa\u7535\u538b\u9700\u8981\u6ce8\u610f\u4ee5\u4e0b\u8981\u70b9\uff1a<\/p>\n<p>1\uff09\u7535\u6781\u7684\u7535\u4f4d\u7a97\u53e3\u7684\u62d3\u5c55\u8981\u907f\u514d\u8d85\u8fc7HER\u6216OER\u7684\u7535\u4f4d\uff1b<\/p>\n<p>2\uff09\u6b64\u6cd5\u7684\u6210\u529f\u8fd0\u7528\u4f9d\u8d56\u4e8e\u4e24\u4e2a\u7535\u6781\u7535\u5bb9\u7684\u6b63\u786e\u6d4b\u91cf\u3002\u4e00\u822c\u800c\u8a00\uff0c\u4f4e\u626b\u901f\u6216\u5c0f\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6d4b\u5f97\u7684\u7535\u5bb9\u503c\uff08\u9700\u8981\u4fdd\u8bc1\u5e93\u4f26\u6548\u7387\u63a5\u8fd1100%\uff09\u66f4\u63a5\u8fd1\u771f\u5b9e\u503c\u3002<\/p>\n<p>3\uff09\u8d5d\u7535\u5bb9\u7535\u6781\u5728\u4e0d\u540c\u7535\u4f4d\u7a97\u53e3\u4e0b\u6d4b\u5f97\u7684\u7535\u5bb9\u53ef\u80fd\u4f1a\u56e0\u4e3a\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u53d1\u751f\u800c\u53d8\u5316\u5f88\u5927\uff0c\u8fd9\u70b9\u5728\u8ba1\u7b97\u65f6\u9700\u8981\u683c\u5916\u6ce8\u610f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107694 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-14.jpg\" alt=\"\" width=\"597\" height=\"315\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-14.jpg 1944w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-14-300x158.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-14-768x405.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/6-14-1024x539.jpg 1024w\" sizes=\"(max-width: 597px) 100vw, 597px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5<\/strong>. \u6b63\u8d1f\u7535\u6781\u53ef\u5b58\u50a8\u7535\u8377\u91cf\u7b49\u5f0f\u3002\u5176\u4e2d<em>Q<\/em>\u4ee3\u8868\u53ef\u5b58\u50a8\u7535\u8377\u91cf\uff0c<em>U<\/em>\u8868\u793a\u7535\u4f4d\u7a97\u53e3\uff0c<em>C<\/em>\u8868\u793a\u6bd4\u7535\u5bb9\uff0c<em>m<\/em>\u8868\u793a\u7535\u5bb9\u6d3b\u6027\u7269\u8d28\u8d28\u91cf\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[1]\u3002<\/p>\n<p><span style=\"color: #ff9900\"><strong>3 | P<sub>0V<\/sub><\/strong><strong>\u8c03\u63a7<\/strong><\/span><\/p>\n<p>\u901a\u8fc7\u5bf9\u5668\u4ef6\u9884\u6ce8\u5165\u7535\u8377\u53ef\u6539\u53d8P<sub>0V<\/sub>\u7684\u7edd\u5bf9\u7535\u4f4d\u4f4d\u7f6e\uff0c\u4ece\u800c\u6700\u5927\u9650\u5ea6\u5730\u5229\u7528\u6b63\u8d1f\u4e24\u6781\u7684\u7406\u8bba\u7535\u4f4d\u8303\u56f4\u3002\u5173\u4e8e\u6b64\u79cd\u65b9\u6cd5\uff0c\u7b14\u8005\u5728\u4e4b\u524d\u7684\u4e00\u7bc7\u6587\u732e\u5bfc\u8bfb\u4e2d\u5df2\u6709\u8be6\u7ec6\u7684\u4ecb\u7ecd[9]\uff0c\u8fd9\u91cc\u4e0d\u518d\u8d58\u8ff0\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107695 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe5-3.jpg\" alt=\"\" width=\"599\" height=\"427\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe5-3.jpg 706w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe5-3-300x214.jpg 300w\" sizes=\"(max-width: 599px) 100vw, 599px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6<\/strong>. \u7535\u8377\u9884\u6ce8\u5165\u6cd5\u8c03\u63a7P<sub>0V<\/sub>\u5e76\u62d3\u5bbd\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u8f93\u51fa\u7535\u538b\u7684\u65b9\u6cd5\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[10]\u3002<\/p>\n<p><span style=\"color: #ff9900\"><strong>4 | \u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4f7f\u7528<\/strong><\/span><\/p>\n<p>\u6700\u540e\u7684\u8fd9\u79cd\u65b9\u6cd5\u4e5f\u662f\u4f7f\u7528\u65f6\u95f4\u6700\u957f\u7684\u65b9\u6cd5\u3002\u5176\u57fa\u672c\u539f\u7406\u662f\u5229\u7528\u6b63\u8d1f\u4e24\u6781\u4e0d\u540c\u7684\u7a33\u5b9a\u7535\u4f4d\u8303\u56f4\uff08\u56fe7\uff09\u4ee5\u53ca\u5404\u81ea\u4e0d\u540c\u7684HER\uff08\u9488\u5bf9\u8d1f\u6781\uff09\u548cOER\uff08\u9488\u5bf9\u6b63\u6781\uff09\u8d85\u8d85\u7535\u52bf\u6765\u8fbe\u5230\u8f93\u51fa\u7535\u538b\u6700\u5927\u5316\u7684\u76ee\u7684\u3002\u6b64\u5916\uff0c\u5bf9\u4e8e\u8d5d\u7535\u5bb9\u6750\u6599\uff0c\u56e0\u4e3a\u7535\u5b50\u4f1a\u7ecf\u5386\u4ece\u7535\u6781\u8868\u9762\u5230\u7535\u89e3\u6db2\u4e2d\u6d3b\u6027\u79bb\u5b50\u7684\u7535\u8377\u4f20\u9012\u8fc7\u7a0b\uff0c\u6b63\u8d1f\u6781\u6750\u6599\u7684\u529f\u51fd\u6570\uff08Work Function\uff09\u7684\u5dee\u503c\u6700\u5927\u5316\u4e5f\u662f\u5e94\u5f53\u8003\u8651\u7684\u56e0\u7d20\u4e4b\u4e00\u3002\u611f\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u53c2\u80032013\u5e74\u53d1\u8868\u5728<em>Advanced Materials<\/em>\u4e0a\u7684\u4e00\u7bc7\u8bba\u6587[11]\uff0c\u5176\u4e2d\u5c31\u8ba8\u8bba\u4e86\u5982\u4f55\u5229\u7528\u529f\u51fd\u6570\u9009\u62e9\u6b63\u8d1f\u6781\u7535\u6781\u6750\u6599\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-107696 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-8.jpg\" alt=\"\" width=\"601\" height=\"156\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-8.jpg 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-8-300x78.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-8-768x199.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/8-8-1024x265.jpg 1024w\" sizes=\"(max-width: 601px) 100vw, 601px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>7<\/strong>. \u4e0d\u540c\u7535\u6781\u7684\u53ef\u7528\u7535\u5bb9\u7535\u4f4d\u7a97\u53e3\u3002\u56fe\u7247\u6765\u81ea\u6587\u732e[1]\u3002<\/p>\n<p style=\"text-align: center\"><span style=\"color: #008080\"><strong>\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/span><\/p>\n<p>\u76f8\u6bd4\u63d0\u5347\u7535\u6781\u7684\u6bd4\u7535\u5bb9\u91cf\uff0c\u589e\u5927\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6700\u5927\u8f93\u51fa\u7535\u538b\u662f\u4e00\u79cd\u66f4\u52a0\u9ad8\u6548\u7684\u63d0\u5347\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u80fd\u91cf\u5bc6\u5ea6\u7684\u65b9\u6cd5\u3002\u672c\u6587\u9996\u5148\u8ba8\u8bba\u4e86\u5f71\u54cd\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u6700\u5927\u8f93\u51fa\u7535\u538b\u7684\u56e0\u7d20\uff0c\u63a5\u7740\u63d0\u51fa\u4e86\u63d0\u5347\u8be5\u7535\u538b\u7684\u65b9\u6cd5\uff0c\u5e76\u4ece\u7535\u89e3\u6db2\u5165\u624b\u548c\u4ece\u7535\u6781\u5165\u624b\u5e76\u7ed3\u5408\u5177\u4f53\u6587\u732e\u63a2\u8ba8\u4e86\u53ef\u884c\u7684\u63aa\u65bd\u3002\u7b14\u8005\u76f8\u4fe1\u968f\u7740\u7814\u7a76\u4eba\u5458\u5bf9\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u50a8\u80fd\u673a\u7406\u7684\u8ba4\u8bc6\u52a0\u6df1\uff0c\u66f4\u591a\u5b9e\u73b0\u7535\u538b\u63d0\u5347\u7684\u6709\u6548\u7b56\u7565\u5c06\u88ab\u63d0\u51fa\u5e76\u5b9e\u8bc1\uff0c\u8fdb\u800c\u63a8\u52a8\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u53d1\u5c55\uff0c\u4f7f\u5176\u4e0e\u76ee\u524d\u5546\u4e1a\u6709\u673a\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7ade\u4e89\u5e02\u573a\u3002<\/p>\n<p><strong>&#8212;<\/strong><\/p>\n<p><strong>\u672c\u6587\u7531\u6750\u6599\u4eba\u7279\u9080\u7f16\u8f91\u5218\u7530\u5b87\u4ee5\u53ca\u4e2d\u5c71\u5927\u5b66\u5316\u5b66\u5b66\u9662\u5362\u9521\u6d2a\u8bfe\u9898\u7ec4\u5171\u540c\u64b0\u7a3f\u3002<\/strong><\/p>\n<p style=\"text-align: center\"><strong><span style=\"color: #008080\">\u3010\u53c2\u8003\u6587\u732e\u3011<\/span><\/strong><\/p>\n<p><strong>[1]<\/strong> M. Yu <em>et al.<\/em> <em>Chem.-Eur. J.<\/em>, <strong>2017<\/strong>, DOI: 10.1002\/chem.201704420<\/p>\n<p><strong>[2] <\/strong>Q. Abbas, <em>et al.<\/em> <em>J. Electrochem. Soc.<\/em> <strong>2015<\/strong><strong>, <\/strong>162, A5148-A5157<\/p>\n<p><strong>[3]<\/strong> Gong K. <em>et al.<\/em> <em>ACS Energy Lett.<\/em>,<strong> 2016, <\/strong>1, 89-93<\/p>\n<p><strong>[4]<\/strong> S. Chun <em>et al.<\/em> <em>Nat. Commun. <\/em><strong>2015<\/strong>, <em>6<\/em>, 7818.<\/p>\n<p><strong>[5]<\/strong> L. Suo, <em>et al.<\/em> <em>Science <\/em><strong>2015<\/strong>, <em>350<\/em>, 938-943.<\/p>\n<p><strong>[6]<\/strong> Yang C. <em>et al.<\/em> <em>Joule<\/em>,<strong> 2017,<\/strong> 122-132<\/p>\n<p><strong>[7]<\/strong> Interview of Dr. Xu, <a href=\"http:\/\/liutianyuresearch.weebly.com\/xu-interview.html\">http:\/\/liutianyuresearch.weebly.com\/xu-interview.html<\/a><\/p>\n<p><strong>[8]<\/strong> N. Jabeen <em>et al.<\/em> <em>Adv. Mater. <\/em><strong>2017<\/strong>, <em>29<\/em>, 1700804.<\/p>\n<p><strong>[9]<\/strong> \u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\uff1a\u7535\u6781\u7535\u4f4d\u65b0\u8d77\u70b9\uff0c\u62d3\u5bbd\u5668\u4ef6\u7535\u4f4d\u7a97\uff1a<a href=\"\/\/m.iemloyee.com\/75247.html\">\/\/m.iemloyee.com\/75247.html<\/a><\/p>\n<p><strong>[10]<\/strong> M. Yu <em>et al.<\/em> <em>Angew. Chem. Int. Ed.<\/em> <strong>2017<\/strong>, 56, 5454-5459.<\/p>\n<p><strong>[11]<\/strong> Chang J. <em>et al.<\/em> <em>Adv. Funct. Mater.<\/em><strong> 2013<\/strong>, 23, 5074-5083<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\uff08\u57fa\u4e8e\u4e2d\u5c71\u5927\u5b66\u5362\u9521\u6d2a\u526f\u6559\u6388\u8bfe\u9898\u7ec4Chem.-Eur. J.\u6587\u7ae0\uff09 \u3010\u63d0\u5347\u8f93\u51fa\u7535\u538b\u7684\u610f\u4e49\u3011 \u5316\u77f3\u71c3\u6599\u7684\u5feb\u901f\u6d88\u8017\u5bfc\u81f4\u5168\u7403\u9762\u4e34\u4e25\u5cfb\u7684\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\uff0c\u8fdb\u800c\u50ac\u751f\u4e86\u65b0\u80fd\u6e90\u7684&#8230;<\/p>\n","protected":false},"author":2791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-107687","post","type-post","status-publish","format-standard","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/107687"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2791"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=107687"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/107687\/revisions"}],"predecessor-version":[{"id":107700,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/107687\/revisions\/107700"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=107687"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=107687"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=107687"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}