{"id":107563,"date":"2017-10-21T06:30:20","date_gmt":"2017-10-20T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=107563"},"modified":"2017-10-21T20:48:50","modified_gmt":"2017-10-21T12:48:50","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e5%be%85%e5%ae%9a%e3%80%91%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6%e5%8a%a0%e5%b7%9e%e5%a4%a7%e5%ad%a6%e6%b2%b3%e6%bb%a8%e5%88%86%e6%a0%a1afm%e5%86%85%e5%b0%81%e9%9d%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=107563","title":{"rendered":"\u5929\u6d25\u5927\u5b66&\u52a0\u5dde\u5927\u5b66\u6cb3\u6ee8\u5206\u6821AFM\u5185\u5c01\u9762\u6587\u7ae0\uff1a \u81ea\u6a21\u677f\u5236\u5907CoO-MoO2 \u7eb3\u7c73\u7b3c\u7528\u4e8e\u6790\u6c27\u53cd\u5e94"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u89e3\u6c34\u5236\u6c22\u548c\u4e8c\u6c27\u5316\u78b3\u7535\u5316\u5b66\u8fd8\u539f\u5236\u5907\u71c3\u6599\u548c\u5316\u5b66\u54c1\u88ab\u5e7f\u6cdb\u5730\u8ba4\u4e3a\u662f\u53ef\u4ee5\u5c06\u53ef\u518d\u751f\u80fd\u6e90(\u5982\u592a\u9633\u80fd\u548c\u98ce\u80fd\u7b49)\u8f6c\u5316\u4e3a\u66f4\u9ad8\u5bc6\u5ea6\u80fd\u91cf\u50a8\u5b58\u6a21\u5f0f-\u5316\u5b66\u80fd\u3002\u6790\u6c27\u53cd\u5e94\u53ef\u4ee5\u4e3a\u9634\u6781\u63d0\u4f9b\u8d28\u5b50\u548c\u7535\u5b50\uff0c\u5728\u7535\u89e3\u6c34\u548c\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e2d\u626e\u6f14\u91cd\u8981\u7684\u89d2\u8272\u3002\u6790\u6c27\u53cd\u5e94\u901f\u7387\u7f13\u6162\u6162\uff0c\u6781\u5927\u5730\u5236\u7ea6\u4e86\u8fd9\u4e9b\u80fd\u91cf\u8f6c\u6362\u548c\u50a8\u5b58\u6548\u7387\u3002\u5f00\u53d1\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u5242\u5bf9\u4e8e\u5236\u5907\u9ad8\u6548\u80fd\u91cf\u8f6c\u6362\u548c\u50a8\u5b58\u671f\u95f4\u6765\u8bf4\u81f3\u5173\u91cd\u8981\u3002IrO2<\/sub>\u548cRuO2<\/sub>\u56e0\u5176\u5177\u6709\u6781\u9ad8\u7684\u6790\u6c27\u6d3b\u6027\u800c\u88ab\u516c\u8ba4\u4e3a\u662f\u8f83\u597d\u7684\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u4ef7\u683c\u6602\u8d35\uff0c\u5143\u7d20\u542b\u91cf\u4f4e\u7b49\u81f4\u547d\u7f3a\u70b9\u6781\u5927\u5730\u9650\u5236\u4e86IrO2<\/sub>\u548cRuO2<\/sub>\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u5728\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u4e2d\uff0c\u6c27\u5316\u94b4\u6790\u6c27\u6d3b\u6027\u8f83\u9ad8\uff0c\u4ef7\u683c\u4f4e\u5ec9\u88ab\u8ba4\u4e3a\u5177\u6709\u524d\u666f\u7684\u8d35\u91d1\u5c5e\u6790\u6c27\u50ac\u5316\u5242\u53d6\u4ee3\u8005\u3002\u7136\u800c\uff0c\u6d3b\u6027\u6700\u9ad8\u7684\u6c27\u5316\u94b4\u57fa\u6790\u6c27\u50ac\u5316\u5242\u4ecd\u7136\u5177\u6709\u8f83\u5927\u7684\u6790\u6c27\u8fc7\u7535\u4f4d\u3002\u5236\u5907\u9ad8\u6548\u6c27\u5316\u94b4\u57fa\u6790\u6c27\u50ac\u5316\u5242\u4ecd\u7136\u5b58\u5728\u5f88\u591a\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5929\u6d25\u5927\u5b66\u5415\u5949\u78ca\u535a\u58eb\uff08\u7b2c\u4e00\u4f5c\u8005\uff0c\u8054\u5408\u57f9\u517b\u535a\u58eb\uff09,\u738b\u5e86\u6cd5\u6559\u6388\u548c\u52a0\u5dde\u5927\u5b66\u6cb3\u6ee8\u5206\u6821Yadong Yin \u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u62a5\u9053\u4e86\u4ee5ZIF-67\u4e3a\u6a21\u677f\u5236\u5907\u591a\u5b54CoO-MoO2<\/sub>\u7eb3\u7c73\u7b3c\u7528\u4e8e\u6790\u6c27\u53cd\u5e94\u3002\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA\/cm2<\/sup>\u65f6\uff0cCoO-MoO2<\/sub> \u7684\u6790\u6c27\u8fc7\u7535\u4f4d\u4ec5\u4e3a312 mV\uff0c\u6bd4CoO\u964d\u4f4e\u4e8634 mV\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u81ea\u6a21\u677f\u65b9\u6cd5\u53ef\u4ee5\u6269\u5c55\u5230CoO-WO2<\/sub>\u4f53\u7cfb\uff0c\u4e3a\u6784\u5efa\u590d\u5408\u6c27\u5316\u7269\u7eb3\u7c73\u7b3c\u7528\u4e8e\u80fd\u91cf\u8f6c\u5316\u548c\u50a8\u5b58\u88c5\u7f6e\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u673a\u4f1a\u3002<\/p>\n

\u3010\u8bbe\u8ba1\u601d\u8def\u3011<\/strong><\/p>\n

\u8bbe\u8ba1\u7684\u51fa\u53d1\u70b9\u6e90\u4e8e\u4ee5\u4e0b\u4e09\u4e2a\u65b9\u9762\uff1a<\/p>\n

(1) CoO\u5177\u6709\u8f83\u9ad8\u7684\u6790\u6c27\u6d3b\u6027\uff0c\u662fCoO-MoO2\u7eb3\u7c73\u7b3c\u4e2d\u4e3b\u8981\u7684\u6d3b\u6027\u7ec4\u5206\uff1b<\/p>\n

(2) \u5177\u6709\u4e2d\u7a7a\u7ed3\u6784\u7684\u7eb3\u7c73\u7b3c\u5177\u6709\u6bd4\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u6269\u6563\u5230\u6d3b\u6027\u4f4d\uff1b<\/p>\n

(3) MoO2<\/sub>\u662f\u4e00\u79cd\u5177\u6709\u91d1\u5c5e\u6027\u8d28\u7684\u6c27\u5316\u7269\uff0c\u5176\u672c\u8eab\u5177\u6709\u4e00\u5b9a\u7684\u6790\u6c27\u53cd\u5e94\u6d3b\u6027\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0cMoO2<\/sub>\u5bfc\u7535\u6027\u8f83\u597d\u3002\u5f15\u5165MoO2<\/sub>\uff0c\u4e0d\u4ec5\u6709\u6548\u5730\u7ef4\u6301\u4e86\u7eb3\u7c73\u7b3c\u7ed3\u6784\uff0c\u589e\u5927\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\uff0c\u6709\u5229\u4e8e\u8d28\u91cf\u4f20\u9012\uff1b\u8fd8\u53ef\u4ee5\u964d\u4f4e\u6790\u6c27\u53cd\u5e94\u7535\u8377\u8f6c\u79fb\u963b\u529b\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u4f20\u9012\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. CoO\u2013MoO2<\/sub>\u7eb3\u7c73\u7b3c\u5408\u6210\u793a\u610f\u56fe.<\/p>\n

\"\"<\/p>\n

\u56fe 2. a,d) ZIF-67, b,e) CoMoO4<\/sub>\u2013Co(OH)2<\/sub> \u548cc,f) CoWO4<\/sub>\u2013Co(OH)2<\/sub>\u7684\u626b\u63cf\u7535\u955c\u548c\u900f\u5c04\u7535\u955c\u56fe\u50cf. \u6807\u5c3a: 1 \u03bcm (a\u2013c) \u548c 100 nm (d\u2013f).<\/p>\n

\"\"<\/p>\n

\u56fe 3. a\u2013c) CoMo\u2013H\u7684\u626b\u63cf\u7535\u955c\uff0c\u900f\u5c04\u7535\u955c\u548c\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\u56fe\u7247; d\u2013g) Co, Mo, \u548c O\u7684\u5143\u7d20\u5206\u5e03. \u6807\u5c3a: 1 \u03bcm (a), 100 nm (b), 2 nm (c), \u548c 200 nm (d).<\/p>\n

\"\"<\/p>\n

\u56fe 4. CoO, MoO2<\/sub>, CoMo\u2013H, CoW\u2013H, CoMo\u2013A\u548c CoW\u2013A\u7684 a)\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf, b) 10 mA cm\u2212<\/sup>2<\/sup>\u7684\u8fc7\u7535\u4f4d, c) \u03b7 = 320 mV\u7684\u7535\u6d41\u5bc6\u5ea6, \u548c d) \u5854\u83f2\u5c14\u659c\u7387\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 5. AFM\u7684\u5c01\u9762\u56fe\u50cf (ADFM-27(34)_IFC).<\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u4ee5ZIF-67\u5b9e\u5fc3\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u4e3a\u6a21\u677f\uff0c\u52a0\u5165Na2<\/sub>MoO4<\/sub>\u56de\u6d41\uff0c\u53ef\u4ee5\u5f97\u5230\u4e2d\u7a7a\u7684CoMoO4<\/sub>-Co(OH)2<\/sub>\u7eb3\u7c73\u7b3c\u3002\u7ecf\u8fc7\u8fd8\u539f\u6027\u6c14\u6c1b\u7119\u70e7\u5f97\u5230\u7684CoO-MoO2<\/sub>\u7eb3\u7c73\u7b3c\u5c55\u73b0\u51fa\u8f83\u597d\u7684\u6790\u6c27\u53cd\u5e94\u6d3b\u6027\u3002Mo\u7684\u5f15\u5165\u4e00\u65b9\u9762\u53ef\u4ee5\u6709\u6548\u5730\u7ef4\u6301\u7eb3\u7c73\u7b3c\u7ed3\u6784\uff0c\u4e0eCoO\u7eb3\u7c73\u9897\u7c92\u76f8\u6bd4\uff0c\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\uff0c\u6709\u5229\u4e8e\u53cd\u5e94\u7269\u6269\u6563\u5230\u6d3b\u6027\u4e2d\u5fc3\uff1b\u53e6\u4e00\u65b9\u9762\u53ef\u4ee5\u589e\u5f3a\u50ac\u5316\u5242\u7684\u5bfc\u7535\u6027\uff0c\u6781\u5927\u5730\u964d\u4f4e\u4e86\u6790\u6c27\u53cd\u5e94\u7535\u8377\u8f6c\u79fb\u963b\u529b\u3002\u8fd9\u79cd\u5408\u6210\u65b9\u6cd5\u4e0d\u4ec5\u9002\u5408CoO-MoO2<\/sub>\u7eb3\u7c73\u7b3c\u8fd8\u53ef\u4ee5\u6269\u5c55\u5230CoO-WO2<\/sub>\u7eb3\u7c73\u7b3c\u4f53\u7cfb\uff0c\u4e3a\u590d\u5408\u6c27\u5316\u7269\u7eb3\u7c73\u7b3c\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSelf-Templated Fabrication of CoO\u2013MoO2<\/sub> Nanocages for Enhanced Oxygen Evolution\uff08Adv. Funct. Mater. 2017, 1702324. DOI: 10.1002\/adfm.201702324<\/a>\uff09<\/p>\n

\u8bfe\u9898\u7ec4\u7b80\u4ecb<\/strong><\/p>\n

\u738b\u5e86\u6cd5\u6559\u6388\u81f4\u529b\u4e8e\u6e05\u6d01\u71c3\u6599\u5408\u6210\uff0c\u80fd\u6e90\u7535\u5316\u5b66\u548c\u6e05\u6d01\u785d\u5316\u5de5\u827a\u7814\u7a76\uff0c\u70b9\u6211\u67e5\u770b\u738b\u8001\u5e08\u4e2a\u4eba\u4e3b\u9875<\/a>\u3002
\n Yadong Yin\u8bfe\u9898\u7ec4\u81f4\u529b\u4e8e\u6750\u6599\u53ca\u754c\u9762\u5316\u5b66\u7684\u7814\u7a76\uff0c\u4ee5\u53d1\u5c55\u65b0\u6750\u6599\u548c\u5229\u7528\u65b0\u80fd\u6e90\u4e3a\u4e3b\u9898\uff0c\u4ee5\u5316\u5b66\u5408\u6210\u3001\u7ec4\u88c5\u548c\u529f\u80fd\u5316\u4e3a\u4e3b\u8981\u624b\u6bb5\uff0c\u540c\u65f6\u8de8\u8d8a\u6750\u6599\u3001\u7269\u7406\u3001\u751f\u7269\u53ca\u5de5\u7a0b\u7b49\u591a\u4e2a\u5b66\u79d1\u3002\u4ee5\u7eb3\u7c73\u6280\u672f\u4e3a\u7279\u8272\uff0c\u81f4\u529b\u4e8e\u7814\u7a76\u6750\u6599\u7684\u65b0\u7ec4\u6210\u3001\u65b0\u7ed3\u6784\u3001\u65b0\u7279\u6027\u548c\u65b0\u5e94\u7528\u3002\u70b9\u6211\u67e5\u770b\u8bfe\u9898\u7ec4\u4e3b\u9875<\/a>\u3002<\/p>\n

\u672c\u6587\u7cfb\u4f5c\u8005nanocages\u6295\u7a3f\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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