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297\u00b165\uff09\u3002ICP-MS\u7814\u7a76\u8868\u660e\uff0c\u7ecf\u538620h\u7684\u5149\u50ac\u5316HER\u540e\uff0c\u53ea\u67090.2%\u7684Ir\u8fdb\u5165\u6eb6\u6db2\u3002\u53cd\u5e94\u524d\u540e\u7684TEM\u56fe\u3001PXRD\u548cEDX\u8868\u660e\uff0c\u7ecf20h HER\u540e\uff0c\u7ed3\u6784\u548c\u7ec4\u6210\u57fa\u672c\u6ca1\u6709\u53d1\u751f\u53d8\u5316\u3002\u8fd9\u8868\u660eNi4<\/sub>P2<\/sub>\u5728HER\u524d\u540e\u662f\u7a33\u5b9a\u7684\uff0cESI-MS\u4e5f\u8bc1\u5b9e\u4e86\u8fd9\u4e2a\u7ed3\u8bba\u3002\u5355\u7eaf\u7684Ni4<\/sub>P2<\/sub>\u5149\u50ac\u5316\u6548\u679c\u4e0d\u4f73\uff0c\u8fd9\u8868\u660e\u5206\u7ea7\u6574\u5408\u5149\u654f\u5316\u7684MOF\u548cPOM\u80fd\u591f\u5b9e\u73b0\u9ad8\u6548\u5149\u50ac\u5316HER\u3002<\/p>\n Ni4<\/sub>P2<\/sub>@MOF-2\u8fdb\u884c\u50ac\u5316HER\uff0c\u4ee4\u4eba\u610f\u5916\u7684\u662f\uff0c\u7ecf\u538620h\u7684\u53ef\u89c1\u5149\u7167\u5c04HER\u53ea\u6709\u5c11\u91cf\u7684H2\u4ea7\u751f\uff08\u5b9e\u9a8c\u6761\u4ef6\u4e0e1a\u5b8c\u5168\u76f8\u540c\uff09\uff0c\u8fd9\u8868\u660eNi4<\/sub>P2<\/sub>@MOF-2\u51e0\u4e4e\u65e0\u5149\u50ac\u5316HER\u6027\u80fd\u3002<\/p>\n Ni<\/b><\/strong>4<\/b><\/sub><\/strong>P<\/b><\/strong>2<\/b><\/sub><\/strong>@MOF \u53ef\u89c1\u5149\u50ac\u5316<\/b><\/strong>HER\u8fc7\u7a0b\u673a\u7406\u7814\u7a76<\/b><\/strong><\/p>\n \u4e3a\u4e86\u7814\u7a76HER\u673a\u7406\uff0c\u4f7f\u7528\u53d1\u5149\u6dec\u706d\u548c\u5bff\u547d\u6d4b\u8bd5\u624b\u6bb5\u6765\u7814\u7a76\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u5149\u654f\u5242\u6fc0\u53d1\u6001\u6dec\u706d\u6709\u4e24\u6761\u8def\u5f84\uff0c\u8fd8\u539f\uff08\u901a\u8fc7\u7532\u9187\u4f5c\u4e3a\u7535\u5b50\u7ed9\u4f53\uff09\u6216\u6c27\u5316\uff08\u901a\u8fc7Ni4P2\u4f5c\u4e3a\u7535\u5b50\u53d7\u4f53\uff09\u3002<\/p>\n <\/p>\n \u56fe3\uff08a\uff09\u4e09\u7535\u5b50\u6ce8\u5165\u5230Ni4<\/sub>P2<\/sub>\u793a\u610f\u56fe\uff08b\uff09\u5728625nm\u53d1\u5c04\u6ce2\u957f\uff0cNi4P2@MOF-1a\u548c MOF-1\u6807\u51c6\u5316\u53d1\u5149\u8870\u51cf\u66f2\u7ebf\u53ca\u62df\u5408\u66f2\u7ebf\uff08c\uff09\u52a0\u5165\u4e0d\u540c\u91cfNi4P2\u65f6\uff0cMe2L1 (0.05 mM)\u7684\u53d1\u5c04\u5149\u8c31\uff08d\uff09\u4e0d\u540c\u7532\u9187\u542b\u91cf\u7684\u53d1\u5c04\u5149\u8c31<\/p>\n \u7531\u56fe3c\u30013d\uff0cMe2L1\u7684\u53d1\u5149\u53ef\u4ee5\u88abNi4<\/sub>P2<\/sub>\u6dec\u706d\uff0c\u800c\u5916\u52a0\u7532\u9187\u5bf9\u5176\u6ca1\u6709\u5f71\u54cd\u3002\u8fd9\u8bf4\u660e\u5149\u50ac\u5316HER\u7b2c\u4e00\u6b65\u662f\u901a\u8fc7\u7535\u5b50\u4ece\u5149\u654f\u5242\u6fc0\u53d1\u6001\u8f6c\u79fb\u5230Ni4<\/sub>P2<\/sub>\u4e0a\u6765\u8fdb\u884c\uff0cMOF-1, MOF-2\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u6d4b\u91cf\u7ed3\u679c\u8fdb\u4e00\u6b65\u652f\u6301\u8fd9\u4e2a\u6c27\u5316\u6dec\u706d\u673a\u7406\u3002\u8367\u5149\u5bff\u547d\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0cNi4<\/sub>P2<\/sub>@MOF\u7684\u6dec\u706d\u662f\u7531\u4e8e\u7535\u5b50\u4ece\u6fc0\u53d1\u6001\u5149\u654f\u5242\u8f6c\u79fb\u5230POM\uff08POM\u548cMOF\u76f8\u4e92\u9760\u7684\u5f88\u8fd1\uff09\u4e0a\u5bfc\u81f4\u7684\u3002<\/p>\n <\/p>\n \u56fe4\uff08a\uff09\u57282M\u6c2f\u5316\u94a0\u6c34\u6eb6\u6db2\u4e2d0.2mM Ni4<\/sub>P2<\/sub>\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff08b\uff09\u57280.2 mm Me2L1\u548c Me2L2\u4e2d\u76840.2mM\u7684Ni4P2\u5fae\u5206\u8109\u51b2\u4f0f\u5b89\u66f2\u7ebf\uff08c\uff09\u57282M\u6c2f\u5316\u94a0\u6c34\u6eb6\u6db2\uff08pH\u4e3a1.2\uff09\u4e2d\u76840.2mM\u7684Ni4P2\u5fae\u5206\u8109\u51b2\u4f0f\u5b89\u66f2\u7ebf\uff08d\uff09\u5728\u6c34\u6eb6\u6db2\uff08pH\u4e3a1.2\uff09\u4e2dMe2<\/sub>L1<\/sub>\u548cMe2L2\u7684\u53d1\u5c04\u5149\u8c31\uff08\u6fc0\u53d1\u6ce2\u957f\u5206\u522b\u4e3a360nm\u548c400 nm\uff09<\/p>\n \u603b\u7ed3\u4e0e\u5c55\u671b<\/b><\/strong><\/p>\n \u79d1\u7814\u4eba\u5458\u6210\u529f\u7684\u5c06\u542b\u954dNi4P2 POM\u5f15\u5165\u5230\u4e0d\u540c\u7684MOFs\u7684\u7a7a\u8154\u5f53\u4e2d\u3002\u53ef\u89c1\u5149\u50ac\u5316HER\u5b9e\u9a8c\u8868\u660e\uff0cNi4P2\u4e0eNi4P2@MOF\u4e2d\u591a\u79cd\u5149\u654f\u5242\u9760\u8fd1\uff0c\u8fd9\u5bf9\u4e8e\u591a\u7535\u5b50\u8f6c\u79fb\u548c\u6709\u6548\u7684HER\u975e\u5e38\u91cd\u8981\uff0c\u5149\u7269\u7406\u548c\u7535\u5316\u5b66\u7814\u7a76\u8868\u660e\uff0cNi4P2\u6fc0\u53d1\u6001\u5149\u654f\u5242\u7684\u6c27\u5316\u6dec\u706d\u662fHER\u7684\u5f00\u59cb\u6b65\u9aa4\uff0c\u540c\u65f6\u4e5f\u89e3\u91ca\u4e86\u4e24\u79cd\u4e0d\u540c\u7684POM@MOF\u9ad8\u6548\u7684\u50ac\u5316\u6d3b\u6027\u4e0d\u540c\u4e4b\u5904\u3002POM@MOF\u7684\u7ec4\u88c5\u4e0d\u4ec5\u4e3a\u8bbe\u8ba1\u9ad8\u6548HER\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u53ef\u8c03\u6027\u7684\u5e73\u53f0\uff0c\u8fd8\u4fc3\u8fdb\u4eba\u4eec\u5bf9\u4e8eHER\u8fc7\u7a0b\u7684\u8be6\u7ec6\u673a\u7406\u7684\u7406\u89e3\uff0c\u4fc3\u8fdb\u4e86MOF\u590d\u5408\u6750\u6599\u5149\u50ac\u5316\u9886\u57df\u7684\u53d1\u5c55\u53ca\u5176\u673a\u7406\u7684\u7814\u7a76\u3002<\/p>\n<\/p>\n
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<\/p>\n
\u56fe5\u00a0Ni4<\/sub>P2<\/sub>@MOF-1\u5149\u50ac\u5316HER\u673a\u7406\uff0c\u6d4b\u8bd5\u4e86Ni4<\/sub>P2<\/sub>\u548c\u5149\u654f\u5242\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u6765\u8fdb\u4e00\u6b65\u7814\u7a76\u5149\u50ac\u5316HER\u673a\u7406\u3002\u6839\u636e\u8fd9\u4e9b\u5b9e\u9a8c\uff0c\u53ef\u5f97Ni4<\/sub>P2<\/sub>@MOF-1\u5149\u50ac\u5316HER\u673a\u7406\uff08\u5982\u56fe5\u6240\u793a\uff09\uff0c\u7531\u56fe4c\u53ef\u5f97\uff0cMe2L1\u548cMe2L2\u663e\u793a\u6c27\u5316\u5cf0\u5206\u522b\u57281.38\u548c1.34 eV\u3002\u7531\u56fe4d\u53ef\u5f97\uff0cMe2L1\u548cMe2L2\u7684\u8367\u5149\u53d1\u5c04\u5cf0\u5206\u522b\u5728598nm\u548c663nm\u3002\u8fd9\u5bf9\u5e94\u7684\u5149\u654f\u5242\u6fc0\u53d1\u6001\u548c\u57fa\u6001\u7684\u80fd\u9699\u5206\u522b\u4e3a2.08 \u548c1.96 eV\u3002[Ir(ppy)2-(bpy\u2019)]+*\u548c [Ir(ppy)2<\/sub>(bpy)]2+<\/sup>\u7684\u80fd\u91cf\u5dee\u4e3a1.38-2.08=-0.70 eV\uff0c\u8fd9\u4e2a\u80fd\u91cf\u5dee\u8db3\u591f\u901a\u8fc7Ni4P2\u9a71\u52a8HER\uff0c\u800c[Ru(bpy)2(bpy\u2019)]2+* \u548c[Ru-(bpy)2(bpy\u2019)]3+\u80fd\u91cf\u5dee\u4e3a1.34-1.96=-0.62 eV\uff0c\u8fd9\u4e2a\u80fd\u91cf\u5dee\u5374\u4e0d\u80fd\u591f\u901a\u8fc7Ni4P2\u9a71\u52a8HER\u3002\u8fd9\u89e3\u91ca\u4e3a\u4ec0\u4e48\u5f53\u7532\u9187\u4f5c\u4e3a\u7535\u5b50\u4f9b\u4f53\u727a\u7272\u5242\u65f6\uff0c2a-2f\u65e0\u6cd5\u53d1\u751f\u5149\u50ac\u5316HER\u3002<\/p>\n