{"id":105837,"date":"2017-10-12T06:30:58","date_gmt":"2017-10-11T22:30:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=105837"},"modified":"2017-10-09T20:10:43","modified_gmt":"2017-10-09T12:10:43","slug":"energ-environ-sci-%ef%bc%9a%e9%85%b8%e5%8c%96%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e7%ba%b8%e8%af%b1%e5%af%bc%e9%98%b3%e7%a6%bb%e5%ad%90%e5%8e%9f%e4%bd%8d%e8%81%9a%e5%90%88%e7%94%9f%e6%88%90%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=105837","title":{"rendered":"Energ. Environ. Sci.\uff1a\u9178\u5316\u78b3\u7eb3\u7c73\u7ba1\u7eb8\u8bf1\u5bfc\u9633\u79bb\u5b50\u539f\u4f4d\u805a\u5408\u751f\u6210\u7684\u56fa\u6001\u7535\u89e3\u8d28\u63d0\u5347\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u786b\u7535\u6c60\u7531\u4e8e\u5177\u6709\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u800c\u53d7\u5230\u7814\u7a76\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5411\u9502\u786b\u7535\u6c60\u4f53\u7cfb\u4e2d\u5f15\u5165\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u4e0d\u4ec5\u80fd\u6291\u5236\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\u53ca\u5176\u5bfc\u81f4\u7684\u5e93\u4ed1\u6548\u7387\u4e0b\u964d\u53ca\u5bb9\u91cf\u8870\u51cf\u7b49\u95ee\u9898\uff0c\u8fd8\u80fd\u89e3\u51b3\u5faa\u73af\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684\u9502\u679d\u6676\u5bfc\u81f4\u7684\u5b89\u5168\u9690\u60a3\u3002\u8981\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5c31\u9700\u8981\u5728\u6df1\u5165\u7406\u89e3\u56fa\u6001\u7535\u89e3\u8d28\u7684\u5f62\u6210\u673a\u7406\u53ca\u5bfc\u7535\u673a\u5236\u7684\u57fa\u7840\u4e0a\uff0c\u7814\u53d1\u540c\u65f6\u5177\u6709\u9ad8\u7684\u79bb\u5b50\u9009\u62e9\u6027\u53ca\u9ad8\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662<\/strong>\u7684\u674e\u5de8\u6559\u6388\u3001Akihiro Kushima\u52a9\u7406\u6559\u6388<\/strong>\u548c\u5357\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66<\/strong>\u7684\u5f20\u6821\u521a\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u53ca\u5f90\u6842\u94f6\u535a\u58eb\uff08\u7b2c\u4e00\u4f5c\u8005\uff09<\/strong>\u7b49\u91c7\u7528\u9502\u786b\u7535\u6c60\u5e38\u7528\u7684\u919a\u57fa\u7535\u89e3\u8d28\uff08DOL\/DME\uff09\u6eb6\u6db2\uff0c\u7528\u785d\u9178\u9178\u5316\u7684\u78b3\u7eb3\u7c73\u7ba1\u7eb8\uff08\u4ee5\u4e0b\u5206\u522b\u7528CNTP\u548cACNTP\u8868\u793a\u9178\u5316\u5904\u7406\u524d\u3001\u540e\u7684\u78b3\u7eb3\u7c73\u7ba1\u7eb8\uff09\u8bf1\u5bfc1,3-\u4e8c\u6c27\u620a\u73af\uff08DOL\uff09\u8fdb\u884c\u9633\u79bb\u5b50\u539f\u4f4d\u805a\u5408\uff0c\u5728ACNTP\u8868\u9762\u539f\u4f4d\u751f\u6210\u4e86\u67d4\u6027\u3001\u53ef\u81ea\u6108\u7684\u56fa\u6001\u7535\u89e3\u8d28\u8584\u819c\u3002\u8fd9\u79cd\u56fa\u6001\u7535\u89e3\u8d28\u8584\u819c\u5177\u6709\u9ad8\u5ea6\u7684\u79bb\u5b50\u9009\u62e9\u6027\uff0c\u80fd\u5c06\u53ef\u6eb6\u6027\u591a\u786b\u5316\u7269\u5bc6\u5c01\u5728\u6b63\u6781\u5ba4\uff0c\u4f46\u5141\u8bb8\u9502\u79bb\u5b50\u7684\u53cc\u5411\u901a\u8fc7\uff0c\u4ece\u800c\u6709\u6548\u6291\u5236\u4e86\u7a7f\u68ad\u6548\u5e94\uff0c\u5e76\u63d0\u9ad8\u4e86\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u3002\u4ee5\u91d1\u5c5e\u9502\u4f5c\u4e3a\u8d1f\u6781\uff0c\u4ee5\u8d1f\u8f7d\u786b\u7684\u6d3b\u6027\u70ad\uff08AC\/S\uff09\u4f5c\u4e3a\u6b63\u6781\uff0c\u91c7\u7528\u5e38\u7528\u7684\u919a\u57fa\u7535\u89e3\u8d28\u6eb6\u6db2\uff08DOL\/DME\uff09\uff0c\u5e76\u4ee5PP\/ACNTP\/PP\uff08PP\u4e3a\u805a\u4e19\u70ef\uff09\u4e09\u660e\u6cbb\u7ed3\u6784\u4f5c\u4e3a\u9694\u819c\u6784\u6210\u7684\u6263\u5f0f\u7535\u6c60\uff0c\u5728\u7535\u5316\u5b66\u6d4b\u8bd5\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1a\u5f53\u5145\u653e\u7535\u500d\u7387\u4e3a1C\uff081675 mA\/g\uff09\u65f6\uff0c\u5176\u521d\u59cb\u6bd4\u5bb9\u91cf\u4e3a683 mAh\/g\uff0c\u5728\u5faa\u73af\u5145\u653e\u7535400\u5708\u540e\u4ecd\u4fdd\u6301\u6709454 mAh\/g\u7684\u653e\u7535\u6bd4\u5bb9\u91cf\u3002\u8be5\u9502\u786b\u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\u9ad8\u8fbe99%\uff0c\u5e73\u5747\u6bcf\u5708\u5faa\u73af\u4f34\u968f\u7684\u5bb9\u91cf\u8870\u51cf\u4ec5\u4e3a0.1%\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cAd hoc\u00a0solid electrolyte on acidized carbon nanotube paper improves cycle life of lithium\u2013sulfur batteries<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Energ. Environ. Sci.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. ACNTP\u8bf1\u5bfcDOL\u7684\u9633\u79bb\u5b50\u539f\u4f4d\u805a\u5408<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u7eb5\u6a2a\u4ea4\u9519\u7684\u94a2\u7b4b\u7f51\u3002\u5411\u94a2\u7b4b\u7f51\u4e0a\u503e\u5012\u6db2\u6001\u6df7\u51dd\u571f\u5e76\u4f7f\u4e4b\u56fa\u5316\uff0c\u5373\u53ef\u5f97\u5230\u575a\u56fa\u7684\u94a2\u7b4b-\u6df7\u51dd\u571f\u7ed3\u6784\u3002<\/p>\n

(b) ACNTP\u5728\u919a\u57fa\u7535\u89e3\u8d28\uff08DOL\/DME\uff09\u6eb6\u6db2\u4e2d\u8bf1\u5bfcDOL\u53d1\u751f\u9633\u79bb\u5b50\u539f\u4f4d\u805a\u5408\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

(c) \u672a\u63a5\u89e6\u7535\u89e3\u8d28\u6eb6\u6db2\u7684ACNTP\uff1b(d) \u4e0e\u7535\u89e3\u8d28\u6eb6\u6db2\u63a5\u89e6\u540e\u5f62\u6210\u7684ACNTP\/\u56fa\u6001\u7535\u89e3\u8d28\u590d\u5408\u7ed3\u6784\uff1b(e) \u7ecf\u8fc7\u5faa\u73af\u5145\u653e\u7535\u540e\u7684ACNTP\/\u56fa\u6001\u7535\u89e3\u8d28\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2. \u56fa\u6001\u7535\u89e3\u8d28\u7684\u673a\u68b0\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

\u7528SEM\u4e2d\u7684\u7eb3\u7c73\u64cd\u7eb5\u63a2\u9488\u5bf9ACNTP\u4e0a\u539f\u4f4d\u751f\u6210\u7684\u56fa\u6001\u7535\u89e3\u8d28\u8fdb\u884c(a) \u5212\u75d5\u5b9e\u9a8c\uff1b(b) \u62c9\u4f38\u5b9e\u9a8c\u3002<\/p>\n

\u56fe3. \u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u9502\u786b\u7535\u6c60\u4f53\u7cfb\u4e2d\u542b\u6709ACNTP\u65f6AC\/S\u6b63\u6781\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff0c\u626b\u63cf\u901f\u5ea6\u4e3a0.2 mV\/s\u3002<\/p>\n

(b, c) \u5145\u653e\u7535\u500d\u7387\u4e3a0.5C\u65f6\uff0cAC\/S\u6b63\u6781\u3001\u542b\u6709CNTP\u53caACNTP\u65f6\u7684AC\/S\u6b63\u6781\u7684 (b) \u7b2c10\u5708\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b(c) \u957f\u5faa\u73af\u7a33\u5b9a\u6027\u80fd\u3002<\/p>\n

(d) \u5145\u653e\u7535\u500d\u7387\u4e3a1C\u65f6\uff0c\u542b\u6709ACNTP\u65f6AC\/S\u6b63\u6781\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u80fd\u53ca\u5e93\u4ed1\u6548\u7387\u3002<\/p>\n

\u56fe4. <\/strong>ACNTP<\/strong>\u7684\u5f62\u8c8c\u3001\u7ed3\u6784\u8868\u5f81\u53ca\u5176\u8868\u9762\u5438\u9644Li2<\/sub>Sn <\/sub>(n=1,2,4)\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) ACNTP\u7684SEM\u622a\u9762\u56fe\u3002<\/p>\n

(b) \u5145\u653e\u7535\u5faa\u73af50\u5708\u540eACNTP\u7684SEM\u56fe\u50cf\uff0c\u5145\u653e\u7535\u500d\u7387\u4e3a0.5C\u3002<\/p>\n

(c-f) \u56feb\u5bf9\u5e94\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

(g) ACNTP\u8868\u9762\u5ac1\u63a5-COOH\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

(h-j) ACNTP\u8868\u9762\u7684-COOH\u4e0e Li2<\/sub>Sn <\/sub>(n=1, 2, 4)\u76f8\u4e92\u4f5c\u7528\u7684\u793a\u610f\u56fe\uff0c\u63d2\u56fe\u4e3a\u5176\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002<\/p>\n

(k) ACNTP\u8868\u9762\u5ac1\u63a5-OH\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

(l-n) ACNTP\u8868\u9762\u7684-OH\u4e0e Li2<\/sub>Sn <\/sub>(n=1, 2, 4)\u76f8\u4e92\u4f5c\u7528\u7684\u793a\u610f\u56fe\uff0c\u63d2\u56fe\u4e3a\u5176\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002<\/p>\n

\u56fe5. \u5145\u653e\u7535\u524d\u540e\u7684ACNTP\u5f62\u8c8c\u8868\u5f81\u53ca\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u7ed3\u679c<\/strong><\/p>\n

\"\"<\/p>\n

(a) ACNTP\uff1b(b, c) \u7ecf\u5faa\u73af\u5145\u653e\u7535\u540eACNTP\u7684TEM\u56fe\u50cf\u3002<\/p>\n

(d) \u7528\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u5f97\u5230\u7684LiTFSI\/Li2<\/sub>S4<\/sub>\u6df7\u5408\u7269\u6a21\u578b\u3002<\/p>\n

(e) \u5747\u65b9\u4f4d\u79fb\uff08MSD\uff09\u968f\u65f6\u95f4\u7684\u53d8\u5316\u56fe\u3002<\/p>\n

(f) Li+<\/sup>\u5728TFSI–<\/sup>\u4e4b\u95f4\u4ee5\u8df3\u8dc3\u7684\u65b9\u5f0f\u8fdb\u884c\u6269\u6563\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u901a\u8fc7\u7b80\u5355\u7684\u9178\u5904\u7406\u5728\u78b3\u7eb3\u7c73\u7ba1\u7eb8\u8868\u9762\u5f15\u5165\u4e86-COOH\u548c-OH\u57fa\u56e2\uff0c\u5e76\u5728\u9178\u6027\u57fa\u56e2\u7684\u8bf1\u5bfc\u4e0b\u4f7f\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u7684DOL\u53d1\u751f\u9633\u79bb\u5b50\u805a\u5408\u53cd\u5e94\uff0c\u539f\u4f4d\u751f\u6210\u4e86\u67d4\u6027\u3001\u53ef\u81ea\u6108\u7684\u56fa\u6001\u7535\u89e3\u8d28\u8584\u819c\u3002\u8fd9\u79cd\u56fa\u6001\u7535\u89e3\u8d28\u8584\u819c\u80fd\u5c06\u53ef\u6eb6\u6027\u591a\u786b\u5316\u7269\u9650\u5236\u5728\u6b63\u6781\u5ba4\u5185\uff0c\u6709\u6548\u6291\u5236\u4e86\u7a7f\u68ad\u6548\u5e94\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u9502\u786b\u7535\u6c60\u4f53\u7cfb\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u5e93\u4ed1\u6548\u7387\u3002\u8be5\u56fa\u6001\u7535\u89e3\u8d28\u4e0d\u4ec5\u53ef\u4ee5\u7528\u4e8e\u9694\u79bb\u9502\u786b\u7535\u6c60\u4e2d\u7684\u591a\u786b\u79bb\u5b50\u4e8e\u6b63\u6781\u533a\uff0c\u8fd8\u80fd\u5bf9\u8d1f\u6781\u7684\u91d1\u5c5e\u9502\u8d77\u5230\u4fdd\u62a4\u4f5c\u7528\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u6c60\u7684\u5b89\u5168\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ad hoc\u00a0solid electrolyte on acidized carbon nanotube paper improves cycle life of lithium\u2013sulfur batteries<\/a> (Energ. Environ. Sci., 2017, DOI:10.1039\/c7ee01898c)<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a<\/strong><\/p>\n

\u00a0(1) \u674e\u5de8\u6559\u6388<\/strong>\u73b0\u4e3a\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u6838\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u53ca\u6750\u6599\u7cfb\u7684\u53cc\u8058\u6559\u6388\uff0c\u5176\u9886\u5bfc\u7684\u7814\u7a76\u56e2\u961f\u81f4\u529b\u4e8e\u6750\u6599\u529b\u5b66\u7279\u6027\u7684\u8ba1\u7b97\u548c\u5b9e\u9a8c\u7814\u7a76\uff0c\u53ca\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u7814\u7a76\u3002\u674e\u5de8\u6559\u6388\u4e8e2005\u5e74\u83b7\u5f97\u7f8e\u56fd\u9752\u5e74\u79d1\u6280\u5de5\u4f5c\u8005\u6700\u9ad8\u5956\u201c\u7f8e\u56fd\u9752\u5e74\u79d1\u5b66\u5bb6\u4e0e\u5de5\u7a0b\u5e08\u603b\u7edf\u5956\u201d\uff08Presidential Early Career Award for Scientists and Engineers)\uff0c2006\u5e74\u83b7\u5f97\u7f8e\u56fd\u6750\u6599\u5b66\u4f1a\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u5bb6\u5927\u5956\uff08MRS Outstanding Young Investigator Award)\uff0c2007\u5e74\u83b7\u5f97\u5e74\u5ea6\u300a\u6280\u672f\u8bc4\u8bba\u300b\u6742\u5fd7\u201c\u4e16\u754c\u9752\u5e74\u521b\u65b0\uff08TR35\uff09\u5956\u201d\uff0c\u5e76\u5728 2014\u5e74\u548c2017\u5e74\u5206\u522b\u88ab\u9009\u4e3a\u7f8e\u56fd\u7269\u7406\u5b66\u4f1a\u4f1a\u58eb\uff08APS\uff09\u548c\u7f8e\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\uff08MRS\uff09\u4f1a\u58eb\u30022016\u5e74\uff0c\u674e\u5de8\u4e0e\u4ed6\u4eba\u5171\u540c\u6210\u7acbMIT\u80fd\u6e90\u521b\u65b0\u8ba1\u5212\u4f4e\u78b3\u80fd\u6e90\u4e2d\u5fc3\u4e4b\u4e00\uff0c\u5373\u80fd\u6e90\u548c\u6781\u7aef\u73af\u5883\u7814\u7a76\u4e2d\u5fc3\u3002<\/p>\n

\u00a0(2) \u5f20\u6821\u521a\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\u4f9d\u6258\u4e8e\u5357\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\u3001\u6c5f\u82cf\u7701\u50a8\u80fd\u6750\u6599\u4e0e\u6280\u672f\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u3002\u76ee\u524d\u8bfe\u9898\u7ec4\u4e3b\u6301\u201c973\u201d\u8ba1\u5212\u8bfe\u9898\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u7701\u79d1\u6280\u6210\u679c\u8f6c\u5316\u9879\u76ee\u7b49\u591a\u9879\u7814\u7a76\u8bfe\u9898\u3002\u5b9e\u9a8c\u5ba4\u5728\u529f\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u5236\u5907\u3001\u7535\u5316\u5b66\u50a8\u8377\u673a\u7406\u7814\u7a76\u3001\u65b0\u578b\u50a8\u80fd\u5668\u4ef6\u7684\u6784\u5efa\u548c\u4f18\u5316\u7b49\u9886\u57df\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u521b\u65b0\u578b\u6210\u679c\uff0c\u5728Adv. Mater.\uff0cAdv. Funct. Mater.\uff0cAdv. Energy Mater.\uff0cNano Lett.\uff0cEnergy Environ.\u00a0Sci.\uff0cChem. Sci.\uff0cNano Energy\u7b49\u56fd\u9645\u6743\u5a01\u6742\u5fd7\u53d1\u8868\u4e0a\u767e\u7bc7\u5b66\u672f\u8bba\u6587\u3002\u7814\u7a76\u56e2\u961f\u591a\u6b21\u83b7\u5f97\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u5956\u3001\u6c5f\u82cf\u7701\u79d1\u5b66\u6280\u672f\u5956\u7b49\u591a\u9879\u8363\u8a89\u3002<\/p>\n

\u5f20\u6821\u521a\u6559\u6388\u3001\u674e\u5de8\u6559\u6388\u56e2\u961f\u5728\u9502\u786b\u7535\u6c60\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b\uff1a<\/strong><\/p>\n

\u8be5\u56e2\u961f\u7814\u7a76\u4eba\u5458\u957f\u671f\u81f4\u529b\u4e8e\u9502\u786b\u7535\u6c60\u7684\u76f8\u5173\u7814\u7a76\uff0c\u63d0\u51fa\u4e86\u4e00\u7cfb\u5217\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u529f\u7387\u5bc6\u5ea6\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u5173\u952e\u6027\u80fd\u6307\u6807\u7684\u65b0\u4e3e\u63aa\u3002\u57fa\u4e8e\u591a\u5e74\u7684\u78b3\u6750\u6599\u7814\u7a76\u7ecf\u9a8c\uff0c\u8be5\u56e2\u961f\u4ece\u78b3\u57fa\u8d28\u6750\u6599\u51fa\u53d1\uff0c\u901a\u8fc7\u78b3\u6750\u6599\u4e0e\u786b\u6b63\u6781\u7684\u590d\u5408\u53ca\u78b3\u6750\u6599\u7684\u6539\u6027\u63d0\u9ad8\u786b\u6b63\u6781\u7684\u7535\u5b50\u5bfc\u7535\u6027\uff0c\u5e76\u901a\u8fc7\u591a\u5b54\u78b3\u6750\u6599\u5bf9\u591a\u786b\u5316\u7269\u7684\u7269\u7406\u5438\u9644\u6291\u5236\u591a\u786b\u5316\u7269\u7684\u6eb6\u89e3\uff0c\u6539\u5584\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd(Chem. Eur. J., 2013, 19, 12306-12312<\/a>; J. Mater. Chem. A, 2014, 2, 19788-19796<\/a>; ACS Appl. Mater. Interfaces, 2014, 6, 194-199<\/a>; Nano Lett., 2015, 15, 1796-1802<\/a>; Chem. Eng. J., 2017, 322, 454-462<\/a>)\u3002\u8be5\u56e2\u961f\u9996\u6b21\u5229\u7528MOFs\u884d\u751f\u78b3\u4f5c\u4e3a\u786b\u6b63\u6781\u57fa\u8d28\u6750\u6599(J. Mater. Chem. A, 2013, 1, 4490-4496<\/a>)\uff0c\u63d0\u9ad8\u4e86\u9502\u786b\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u8be5\u56e2\u961f\u5728Materials Today\u671f\u520a\u53d1\u8868\u4e86\u76f8\u5173\u7efc\u8ff0\u201cExploring metal organic frameworks for energy storage in batteries and supercapacitors<\/a>\u201d\u3002\u8be5\u7efc\u8ff0\u91cd\u70b9\u4ecb\u7ecd\u4e86MOFs\u5728\u9502\u786b\u7535\u6c60\u4e2d\u7684\u5e94\u7528\uff0c\u603b\u7ed3\u4e86MOFs\u7684\u7ed3\u6784\u3001\u6bd4\u8868\u9762\u79ef\u3001\u529f\u80fd\u6709\u673a\u94fe\u3001\u91d1\u5c5e\u4e2d\u5fc3\u539f\u5b50\u4e0e\u9502\u786b\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5e76\u8fdb\u4e00\u6b65\u5c55\u671b\u4e86\u901a\u8fc7\u8c03\u63a7MOFs\u7684\u7ed3\u6784\u4e0e\u6027\u8d28\u7b49\u6765\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u529f\u7387\u5bc6\u5ea6\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u6027\u80fd\u3002<\/p>\n

\u8be5\u56e2\u961f\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u9502\u786b\u7535\u6c60\u6b63\u6781\u4e2d\u7684\u7c98\u7ed3\u5242(Nano Energy, 2017, 31, 568-574<\/a>)\uff0c\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\uff0c\u5c06PAA\u7c98\u7ed3\u5242\u5ac1\u63a5\u5230RGO\u8868\u9762\uff0c\u5236\u5907\u5f97\u5230\u5bfc\u7535\u7684GO-PAA\u7c98\u7ed3\u5242\uff1aRGO\u4e3b\u8981\u63d0\u9ad8\u4e86\u529f\u80fd\u7c98\u7ed3\u5242\u7684\u7535\u5b50\u7535\u5bfc\uff1bPAA\u80fd\u591f\u4e0e\u6eb6\u89e3\u7684\u591a\u786b\u5316\u9502\u5f62\u6210\u5316\u5b66\u952e\uff0c\u5316\u5b66\u5438\u9644\u5411\u8d1f\u6781\u6269\u6563\u7684\u591a\u786b\u5316\u9502\uff0c\u4ece\u800c\u6539\u5584\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u4e3a\u4e86\u8fdb\u4e00\u6b65\u6291\u5236\u7a7f\u68ad\u6548\u5e94\uff0c\u8be5\u56e2\u961f\u4ece\u9502\u786b\u7535\u6c60\u7684\u6574\u4f53\u7ed3\u6784\u51fa\u53d1\uff0c\u5bf9\u9502\u786b\u7535\u6c60\u9694\u819c\u7684\u5236\u5907\u53ca\u6539\u6027\u4f5c\u51fa\u4e86\u7cfb\u7edf\u7684\u7814\u7a76\u3002\u8be5\u56e2\u961f\u901a\u8fc7\u9178\u5904\u7406\u78b3\u7eb3\u7c73\u7ba1\u7eb8\u7684\u65b9\u6cd5\u6210\u529f\u5236\u5907\u51fa\u53ef\u7528\u4e8e\u9502\u786b\u7535\u6c60\u7684\u79bb\u5b50\u9009\u62e9\u6027\u819c(Energ Environ. Sci., 2017, DOI:10.1039\/C7EE01898C<\/a>)\uff0c\u901a\u8fc7\u8be5\u65b9\u6cd5\u81ea\u53d1\u539f\u4f4d\u5f62\u6210\u7684\u56fa\u6001\u7535\u89e3\u8d28\u819c\u5177\u6709\u826f\u597d\u7684\u673a\u68b0\u67d4\u97e7\u6027\u3001\u81ea\u5bc6\u5c01\u548c\u81ea\u6108\u5408\u7b49\u7279\u6027\uff0c\u540c\u65f6\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u9694\u819c\u5728\u9502\u786b\u7535\u6c60\u4f53\u7cfb\u7684\u4f5c\u7528\u673a\u5236\u3002\u6b64\u5916\uff0c\u8be5\u56e2\u961f\u901a\u8fc7\u5728\u78b3\u7eb3\u7c73\u7ba1\u7eb8\u4e0a\u4fee\u9970\u5bf9\u591a\u786b\u79bb\u5b50\u5177\u6709\u8f83\u5f3a\u5316\u5b66\u5438\u9644\u4f5c\u7528\u7684\u4e8c\u6c27\u5316\u949b\uff0c\u5e76\u5c06\u5176\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u9694\u819c\uff0c\u663e\u8457\u63d0\u5347\u4e86\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027(Nano Res., 2015, 8, 3066-3074<\/a>)\u3002<\/p>\n

\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u7684\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8be5\u56e2\u961f\u5c06\u529f\u80fd\u6750\u6599\u76f4\u63a5\u6d82\u8986\u4e8e\u9694\u819c(Chem. Sci., 2017, 8, 6619-6625<\/a>)\u3002\u7b2c\u4e00\u6027\u539f\u7406\u53ca\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u8be5\u4f53\u7cfb\u4e2d\u7684\u4e8c\u6c27\u5316\u949b\u5bf9\u591a\u786b\u79bb\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u8d77\u5230\u50ac\u5316\u4f5c\u7528\u3002\u6bdb\u7ec6\u7ba1\u7535\u6c60\u6d4b\u8bd5\u8bc1\u660e\u8be5\u529f\u80fd\u9694\u819c\u5177\u6709\u6291\u5236\u9502\u679d\u6676\u7a7f\u523a\u7684\u80fd\u529b\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u524d\u7ebf\u738b\u948a\u9896\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

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