{"id":105680,"date":"2017-10-10T06:30:40","date_gmt":"2017-10-09T22:30:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=105680"},"modified":"2017-10-09T10:12:06","modified_gmt":"2017-10-09T02:12:06","slug":"%e9%a6%99%e6%b8%af%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6chem-mater-%ef%bc%9a%e5%9b%ba%e6%80%81%e7%94%b5%e8%a7%a3%e8%b4%a8%e7%90%86%e8%ae%ba%e7%a0%94%e7%a9%b6%e5%8f%96%e5%be%97%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=105680","title":{"rendered":"\u9999\u6e2f\u79d1\u6280\u5927\u5b66Chem. Mater.\uff1a\u56fa\u6001\u7535\u89e3\u8d28\u7406\u8bba\u7814\u7a76\u53d6\u5f97\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u56fa\u6001\u7535\u6c60\u6280\u672f\u662f\u7a81\u7834\u9502\u79bb\u5b50\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u74f6\u9888\u7684\u5173\u952e\u6280\u672f\u4e4b\u4e00\uff0c\u4e5f\u662f\u76ee\u524d\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002[1]\u76f8\u6bd4\u4e8e\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u7531\u4e8e\u4e0d\u542b\u6db2\u6001\u6709\u673a\u6eb6\u5242\uff0c\u56fa\u6001\u7535\u6c60\u4e0d\u5b58\u5728\u6f0f\u6db2\u3001\u80c0\u6c14\u71c3\u70e7\u7b49\u95ee\u9898\uff0c\u56e0\u6b64\u66f4\u52a0\u5b89\u5168\u3002\u53e6\u5916\uff0c\u76ee\u524d\u666e\u904d\u8ba4\u4e3a\u7531\u56fa\u6001\u7535\u89e3\u8d28\u904d\u5177\u6709\u8f83\u597d\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u5728\u4f7f\u7528\u9502\u91d1\u5c5e\u8d1f\u6781\u65f6\u53ef\u4ee5\u907f\u514d\u679d\u6676\uff08dendrite\uff09\u751f\u957f\u95ee\u9898\u3002\u56fa\u6001\u7535\u6c60\u9762\u4e34\u7684\u4e3b\u8981\u95ee\u9898\u5728\u4e8e\u500d\u7387\u6027\u80fd\uff0c\u5373\u5145\u653e\u7535\u901f\u5ea6\u8f83\u6162\u3002\u4e3a\u4e86\u89e3\u51b3\u8be5\u95ee\u9898\uff0c\u9700\u8981\u5bfb\u627e\u5177\u6709\u6781\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u56fa\u6001\u7535\u89e3\u8d28\u3002\u8fd1\u671f\uff0c\u591a\u79cd\u91d1\u5c5e\u787c\u6c22\u5316\u7269\uff08Li<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u3001LiCB<sub>11<\/sub>H<sub>12<\/sub>\u7b49\uff09[2][3]\u88ab\u53d1\u73b0\u5177\u6709\u6781\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u88ab\u8ba4\u4e3a\u6709\u671b\u6210\u4e3a\u4f18\u8d28\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u4f46\u5176\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u3001\u4e0e\u6b63\u8d1f\u6781\u4e4b\u95f4\u7684\u9002\u914d\u6027\u4ee5\u53ca\u6291\u5236\u679d\u6676\u751f\u957f\u7684\u80fd\u529b\u4ecd\u7136\u5b58\u5728\u8f83\u5927\u7591\u95ee\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u9999\u6e2f\u79d1\u6280\u5927\u5b66Francesco\u00a0Ciucci\u8bfe\u9898\u7ec4<\/strong>\u5229\u7528\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\u7cfb\u7edf\u7814\u7a76\u4e86Li\u3001Na\u3001Ca\u3001Mg\u7b49\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u7684\u70ed\u529b\u5b66\u6027\u8d28\u53ca\u5176\u5728\u7535\u5316\u5b66\u6c27\u5316\u6761\u4ef6\u4e0b\u4e0e\u7535\u6781\u7684\u9002\u914d\u6027\uff0c\u5e76\u5728<strong>Chem. Mater.<\/strong>\u4e0a\u5728\u7ebf\u53d1\u8868\u4e86\u9898\u4e3a\u201d<strong> Metal-borohydrides as electrolytes for solid-state Li, Na, Mg and Ca batteries: a first-principles study<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002[4]\u8be5\u7814\u7a76\u8868\u660e\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u5728\u9ad8\u6c27\u5316\u7535\u4f4d\u4e0b\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\uff0c\u4f46\u5176\u5206\u89e3\u4ea7\u7269\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u56e0\u6b64\u53ef\u4ee5\u9650\u5236\u7535\u89e3\u8d28\u819c\u7684\u8fdb\u4e00\u6b65\u5206\u89e3\uff0c\u57fa\u4e8e\u6b64\u7ed3\u679c\u4f5c\u8005\u63d0\u51fa\u4e86\u754c\u4e00\u79cd\u754c\u9762\u7a33\u5b9a\u5316\u673a\u5236\u5e76\u9884\u6d4bLi\u3001Na\u787c\u6c22\u5316\u7269\u7684\u5b8f\u89c2\u7535\u5316\u5b66\u7a97\u53e3\u53ef\u8fbe5V\u3002\u4f5c\u8005\u8fd8\u7814\u7a76\u4e86\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u673a\u68b0\u6027\u80fd\u5e76\u53d1\u73b0\u5176\u5177\u6709\u8f83\u4f4e\u7684\u526a\u5207\u6a21\u91cf\uff0c\u56e0\u6b64\u5176\u4e0e\u7eaf\u91d1\u5c5e\u7535\u6781\u7684\u673a\u68b0\u9002\u914d\u6027\u8f83\u5dee\uff0c\u8f83\u96be\u6291\u5236\u679d\u6676\u751f\u957f\u3002\u901a\u8fc7\u5173\u8054\u9634\u79bb\u5b50\u8f6c\u52a8\u80fd\u5792\u4e0e\u5b9e\u9a8c\u89c2\u6d4b\u5230\u7684\u79bb\u5b50\u8d85\u5bfc\u76f8\u53d8\u6e29\u5ea6\uff08superionic\u00a0phase transition temperature\uff09\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u63ba\u6742\u5f02\u534a\u5f84\u9634\u79bb\u5b50\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u65b9\u6cd5\u5e76\u5f97\u5230\u4e86\u5b9e\u9a8c\u9a8c\u8bc1\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \uff08a\uff09\u51e0\u79cd\u5e38\u89c1\u787c\u6c22\u5316\u7269\u9634\u79bb\u5b50\u7ed3\u6784\uff1b\uff08b\uff09Li<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u7684\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105687\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72471-8.png\" alt=\"\" width=\"600\" height=\"333\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72471-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72471-8-300x167.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u901a\u8fc7\u8ba1\u7b97\u5927\u91cf\u53ef\u80fd\u5b58\u5728\u7684\u76f8\uff0c\u4f5c\u8005\u6784\u9020\u4e86Li\u3001Na\u3001Ca\u3001Mg\u787c\u6c22\u5316\u7269\u7684\u70ed\u529b\u5b66\u76f8\u56fe\u3002\u6b64\u524d\u5b9e\u9a8c\u4e2d\u53d1\u73b0\u7684\u51e0\u79cd\u7269\u8d28\u88ab\u53d1\u73b0\u662f\u7a33\u5b9a\u76f8\uff08LiBH<sub>4<\/sub>\u7b49\uff09\u6216\u4e9a\u7a33\u76f8\uff08Li<sub>2<\/sub>B<sub>10<\/sub>H<sub>10<\/sub>\u7b49\uff09\u3002\u5728Li\u3001Na\u3001Ca\u3001Mg\u4e2d\uff0c\u53ea\u6709Na\u7684\u787c\u6c22\u5316\u7269\u4e0eNa\u91d1\u5c5e\u4e4b\u95f4\u7a33\u5b9a\uff0cLi\u3001Na\u3001Ca\u7684\u787c\u6c22\u5316\u7269\u5747\u4f1a\u4e0e\u5176\u5bf9\u5e94\u7684\u91d1\u5c5e\u8d1f\u6781\u53cd\u5e94\u3002<\/p>\n<p><strong>\u56fe2\u00a0\uff08a\uff09Li-\uff08b\uff09Na-\uff08c\uff09Ca-\uff08d\uff09Mg-B-H\u4f53\u7cfb\u7684\u70ed\u529b\u5b66\u76f8\u56fe (\u03b1) LiB<sub>10<\/sub>H<sub>9<\/sub>, (\u03b2) Li<sub>2<\/sub>B<sub>10<\/sub>H<sub>10<\/sub>, (\u03b3) LiB<sub>3<\/sub>H<sub>8<\/sub>, (\u03b4) Na<sub>2<\/sub>B<sub>10<\/sub>H<sub>10<\/sub>, (\u03b5) Na<sub>2<\/sub>B<sub>6<\/sub>H<sub>6<\/sub>, and (\u03b6) NaB<sub>3<\/sub>H<sub>8<\/sub>.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105689\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72472-5.png\" alt=\"\" width=\"471\" height=\"415\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72472-5.png 471w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72472-5-300x264.png 300w\" sizes=\"(max-width: 471px) 100vw, 471px\" \/><\/p>\n<p>\u9664\u4e86Ca\u4ee5\u5916\u8fd9\u4e9b\u4e0e\u7eaf\u91d1\u5c5e\u7535\u6781\u7684\u53cd\u5e94\u9a71\u52a8\u529b\u5e76\u4e0d\u5f3a\uff0c\u56e0\u6b64\u53ea\u6709Ca\u7684\u787c\u6c22\u5316\u7269\u6bd4\u8f83\u5bb9\u6613\u5728\u8fd8\u539f\u7535\u4f4d\u4e0b\u5206\u89e3\u3002\u89c1\u56fe3\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3002\u540c\u65f6\uff0cLiBH<sub>4<\/sub>\u7b49\u7269\u8d28\u5728\u6c27\u5316\u6761\u4ef6\u4e0b\u5bb9\u6613\u5206\u89e3\u6210\u4e3aLi<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\uff0c\u800cLi<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u76f8\u5bf9\u7a33\u5b9a\uff0c\u4e0d\u4f1a\u7ee7\u7eed\u88ab\u6c27\u5316\uff0c\u56e0\u6b64\u53ef\u4ee5\u4fdd\u62a4LiBH<sub>4<\/sub>\u7b49\u56fa\u6001\u7535\u89e3\u8d28\uff08\u89c1\u56fe4\uff09<\/p>\n<p><strong>\u56fe3\u00a0\u5404\u79cd\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u7684\u7535\u5316\u5b66\u7a97\u53e3<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105690\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72473-5.png\" alt=\"\" width=\"413\" height=\"316\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72473-5.png 413w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72473-5-300x230.png 300w\" sizes=\"(max-width: 413px) 100vw, 413px\" \/><\/p>\n<p><strong>\u56fe4 (a)LiBH<sub>4<\/sub>\u4e0e(b)Li<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u5728\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u5206\u89e3\u4ea7\u7269\uff1b(c)\u754c\u9762\u7a33\u5b9a\u5316\u673a\u5236\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105692\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72474-6.png\" alt=\"\" width=\"600\" height=\"515\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72474-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72474-6-300x258.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe5 \u5404\u79cd\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u7684\u529b\u5b66\u6027\u8d28\uff08\u526a\u5207\u6a21\u91cf\u3001\u4f53\u6a21\u91cf\u3001Pugh\u6bd4\u4f8b\uff09<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105694\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72475-4.png\" alt=\"\" width=\"352\" height=\"251\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72475-4.png 352w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72475-4-300x214.png 300w\" sizes=\"(max-width: 352px) 100vw, 352px\" \/><\/p>\n<p>\u6b64\u524dMonroe\u7b49\u4eba[5]\u66fe\u4eca\u63d0\u51fa\u201c\u4e8c\u500d\u526a\u5207\u6a21\u91cf\u7406\u8bba\u201d\u7528\u4ee5\u9884\u6d4b\u7535\u89e3\u8d28\u662f\u5426\u80fd\u6291\u5236\u679d\u6676\u751f\u957f\uff1a\u5f53\u7535\u89e3\u8d28\u526a\u5207\u6a21\u91cf\u5927\u4e8e2\u500d\u91d1\u5c5e\u9502\u7684\u526a\u5207\u6a21\u91cf\uff0c\u8be5\u754c\u9762\u53ef\u4ee5\u8ba4\u4e3a\u7a33\u5b9a\u3002\u5bf9\u4e8eLi\u3001Na\u787c\u6c22\u5316\u7269\uff0c\u526a\u5207\u6a21\u91cf\u90fd\u6bd4\u8f83\u5c0f\uff0c\u56e0\u6b64\uff0c\u4e0d\u50cf\u4e4b\u524d\u6240\u5e7f\u6cdb\u8ba4\u4e3a\u7684\uff0c\u8fd9\u79cd\u56fa\u6001\u7535\u89e3\u8d28\u5f88\u53ef\u80fd\u4e0d\u80fd\u6291\u5236\u679d\u6676\u751f\u957f\u3002\u56e0\u6b64\u9700\u8981\u957f\u65f6\u95f4\u5927\u7535\u6d41\u5145\u653e\u7535\u6d4b\u8bd5\u3002<\/p>\n<p><strong>\u56fe6 \u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\u5f97\u5230\u7684\u9634\u79bb\u5b50\u8f6c\u52a8\u80fd\u5792\u4e0e\u76f8\u53d8\u6e29\u5ea6\u5173\u7cfb\uff1b\u5404\u79cd\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u7684\u9633\u79bb\u5b50\u7f3a\u9677\u5f62\u6210\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105695\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72476-2.png\" alt=\"\" width=\"533\" height=\"239\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72476-2.png 533w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72476-2-300x135.png 300w\" sizes=\"(max-width: 533px) 100vw, 533px\" 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\u7b2c\u4e00\u6027\u52a8\u529b\u5b66\u6a21\u62dfNa\u3001Mg\u3001Ca\u787c\u6c22\u5316\u7269\u7684\u9633\u79bb\u5b50\u6269\u6563<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-105697\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72477-1.png\" alt=\"\" width=\"517\" height=\"385\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72477-1.png 517w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/\u56fe\u72477-1-300x223.png 300w\" sizes=\"(max-width: 517px) 100vw, 517px\" \/><\/p>\n<p>\u52a8\u529b\u5b66\u6a21\u62df\u8868\u660eMg\u4e0eCa\u787c\u6c22\u5316\u7269\u6269\u6563\u8f83\u6162\uff0c\u4e0d\u9002\u5408\u5728\u5ba4\u6e29\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u5f53\u4f5c\u7535\u89e3\u8d28\u4f7f\u7528\u3002\uff08\u56fe7\uff09<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/xueshu.baidu.com\/s?wd=paperuri%3A%2867d71eb22d499e5e06df9db319e84793%29&amp;filter=sc_long_sign&amp;tn=SE_xueshusource_2kduw22v&amp;sc_vurl=http%3A%2F%2Fpubs.acs.org%2Fdoi%2F10.1021%2Facs.chemmater.7b03284&amp;ie=utf-8&amp;sc_us=10501636666686624873\" target=\"_blank\" rel=\"noopener\">Metal-borohydrides as electrolytes for solid-state Li, Na, Mg and Ca batteries: a first-principles study<\/a>\uff08Chem. Mater.,2017,DOI:10.1021\/acs.chemmater.7b03284\uff09<\/p>\n<p><strong>\u3010\u76f8\u5173\u4ee3\u7801\u3011<\/strong><\/p>\n<p>\u8be5\u7406\u8bba\u5de5\u4f5c\u76f8\u5173\u4ee3\u7801\u4e8e\u8fd1\u671f\u516c\u5e03\u5728Github\u4e0a\uff1ahttps:\/\/github.com\/luzihen\/AIMD_Toolkit<\/p>\n<p><strong>\u3010\u76f8\u5173\u5de5\u4f5c\u3011<\/strong><\/p>\n<p>\u79bb\u5b50\u8d85\u5bfc\u4f53\u76f8\u5173\u7406\u8bba\u7814\u7a76\uff1a<\/p>\n<p>[7] Sci. Rep.: doi:10.1038\/srep40769<\/p>\n<p>[8] Phys. Chem. Chem. Phys.: doi:10.1039\/C5CP05722A<\/p>\n<p>[9] J. Mater. Chem. A: doi:10.1039\/C6TA07443J<\/p>\n<p>\u56fa\u6001\u7535\u89e3\u8d28\u76f8\u5173\u5b9e\u9a8c\u7814\u7a76\uff1a\u00a0<\/p>\n<p>[10] J. Power Sources: doi:j.jpowsour.2017.08.020<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u91d1\u5c5e\u787c\u6c22\u5316\u7269\u662f\u7406\u60f3\u7684\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u4e00\u3002\u5f97\u76ca\u4e8e\u754c\u9762\u7a33\u5b9a\u5316\u673a\u5236\uff0c\u4ed6\u4eec\u5177\u6709\u8f83\u597d\u7684\u6297\u7535\u5316\u5b66\u6c27\u5316\u6027\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u7535\u6781\u7684\u679d\u6676\u751f\u957f\u9700\u8981\u957f\u65f6\u95f4\u5faa\u73af\u7684\u5b9e\u9a8c\u7814\u7a76\u3002<\/p>\n<p><strong>\u3010\u53c2\u8003\u6587\u732e\u3011<\/strong><\/p>\n<p>[1] Janek, J\u00fcrgen, and Wolfgang G. Zeier. &#8220;A solid future for battery development.&#8221;\u00a0<em><i>Nature Energy<\/i><\/em>\u00a01 (2016): 16141.<\/p>\n<p>[2]\u00a0Mohtadi, Rana, and Shin-ichi Orimo. &#8220;The renaissance of hydrides as energy materials.&#8221;\u00a0<em><i>Nature Reviews Materials<\/i><\/em>\u00a02 (2016): 16091.<\/p>\n<p>[3] Tang, Wan Si, et al. &#8220;Liquid\u2010Like Ionic Conduction in Solid Lithium and Sodium Monocarba\u2010closo\u2010Decaborates Near or at Room Temperature.&#8221;\u00a0<em><i>Advanced Energy Materials<\/i><\/em>\u00a06.8 (2016).<\/p>\n<p>[4]\u00a0Lu, Ziheng, and Francesco Ciucci. \u201cMetal-borohydrides as electrolytes for solid-state Li, Na, Mg and Ca batteries: a first-principles study\u201d <a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/acs.chemmater.7b03284\" target=\"_blank\" rel=\"noopener\">Chemistry of Materials<\/a> (2017)<\/p>\n<p>&nbsp;<\/p>\n<p>[5] Monroe, Charles, and John Newman. &#8220;The impact of elastic deformation on deposition kinetics at lithium\/polymer interfaces.&#8221;\u00a0<em><i>Journal of The Electrochemical Society<\/i><\/em>\u00a0152.2 (2005): A396-A404.<\/p>\n<p>[6] Yan, Yigang, et al. &#8220;A Lithium Amide\u2010Borohydride Solid\u2010State Electrolyte with Lithium\u2010Ion Conductivities Comparable to Liquid Electrolytes.&#8221;\u00a0<em><i>Advanced Energy Materials<\/i><\/em>\u00a0(2017).<\/p>\n<p>[7] Chen, Chi, Ziheng Lu, and Francesco Ciucci. &#8220;Data mining of molecular dynamics data reveals Li diffusion characteristics in garnet Li7La3Zr2O12.&#8221;\u00a0<em><i>Scientific reports<\/i><\/em>\u00a07 (2017): 40769.<\/p>\n<p>[8] Lu, Ziheng, et al. &#8220;Defect chemistry and lithium transport in Li 3 OCl anti-perovskite superionic conductors.&#8221;\u00a0<em><i>Physical Chemistry Chemical Physics<\/i><\/em>\u00a017.48 (2015): 32547-32555.<\/p>\n<p>[9] Lu, Ziheng, and Francesco Ciucci. &#8220;Structural origin of the superionic Na conduction in Na 2 B 10 H 10 closo-borates and enhanced conductivity by Na deficiency for high performance solid electrolytes.&#8221;\u00a0<em><i>Journal of Materials Chemistry A<\/i><\/em>\u00a04.45 (2016): 17740-17748.<\/p>\n<p>[10] Saccoccio, Mattia, et al. &#8220;Low temperature pulsed laser deposition of garnet Li 6.4 La 3 Zr 1.4 Ta 0.6 O 12 films as all solid-state lithium battery electrolytes.&#8221;\u00a0<em><i>Journal of Power Sources<\/i><\/em>\u00a0365 (2017): 43-52.<\/p>\n<p>\u672c\u6587\u7531\u7531Francesco\u00a0Ciucci\u8bfe\u9898\u7ec4\u4f9b\u7a3f\uff0c\u6750\u6599\u4ebaAllen\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" 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