{"id":104904,"date":"2017-10-07T14:00:07","date_gmt":"2017-10-07T06:00:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=104904"},"modified":"2017-10-03T20:28:19","modified_gmt":"2017-10-03T12:28:19","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e5%8c%96%e5%ad%a6%e6%89%80%ef%bc%9a%e6%9c%89%e6%9c%ba%e7%83%ad%e7%94%b5%e7%a0%94%e7%a9%b6%e6%96%b9%e9%9d%a2%e5%8f%96%e5%be%97%e7%b3%bb%e5%88%97%e8%bf%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=104904","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u6240\uff1a\u6709\u673a\u70ed\u7535\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u7cfb\u5217\u8fdb\u5c55"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u5728\u6709\u673a\u70ed\u7535\u6750\u6599\u4f53\u7cfb\u7684\u7814\u7a76\u4e2d\uff0cn\u578b\u6750\u6599\u7684\u5f00\u53d1\u957f\u671f\u9762\u4e34\u4f53\u7cfb\u5c11\u3001\u6027\u80fd\u4f4e\u548c\u63ba\u6742\u56f0\u96be\u7b49\u96be\u9898\u3002\u5728\u79d1\u6280\u90e8\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3001\u4e2d\u79d1\u9662\u6218\u7565\u6027\u5148\u5bfc\u79d1\u6280\u4e13\u9879\u548c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u9879\u76ee\u7684\u652f\u6301\u4e0b\uff0c\u6709\u673a\u56fa\u4f53\u5b9e\u9a8c\u5ba4\u7684\u79d1\u7814\u4eba\u5458\u7ed3\u5408\u524d\u671f\u9ad8\u8fc1\u79fb\u7387\u6709\u673a\u534a\u5bfc\u4f53\u7684\u7814\u7a76\u3001\u70ed\u7535\u6027\u8d28\u7684\u573a\u8c03\u63a7\u548c\u94cb\u91d1\u5c5e\u754c\u9762\u5316\u5b66\u63ba\u6742\uff0c\u6210\u529f\u53d1\u73b0\u5e76\u8bc1\u5b9e\u4e86TDPPQ\u662f\u4e00\u7c7b\u9ad8\u6027\u80fdn\u578b\u6709\u673a\u534a\u5bfc\u4f53\u70ed\u7535\u6750\u6599\uff08Angew. Chem. Int. Ed.\u20022016, 55, 10672\uff09\u3002\u6700\u8fd1\uff0c\u4ed6\u4eec\u8fdb\u4e00\u6b65\u7ed3\u5408\u70ed\u7535\u6027\u8d28\u7684\u573a\u8c03\u63a7\u548c\u5316\u5b66\u63ba\u6742\u8c03\u63a7\uff0c\u6210\u529f\u53d1\u73b0\u4e86\u65b0\u578b\u7684\u66f4\u9ad8\u6027\u80fdn\u578b\u6709\u673a\u534a\u5bfc\u4f53\u70ed\u7535\u6750\u6599\uff08A-DCV-DPPTT\uff09\u3002\u8be5\u7c7b\u6750\u6599\u7684\u8584\u819c\u5728\u5316\u5b66\u63ba\u6742\u540e\u7684\u6700\u9ad8\u70ed\u7535\u4f18\u503c\u7a81\u78340.2\uff0c\u662fn\u578b\u6709\u673a\u5c0f\u5206\u5b50\u70ed\u7535\u6750\u6599\u7684\u6700\u4f18\u6027\u80fd\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u4ed6\u4eec\u548c\u5317\u4eac\u5e08\u8303\u5927\u5b66\u7684\u79d1\u7814\u4eba\u5458\u5bc6\u5207\u5408\u4f5c\uff0c\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\u7cfb\u7edf\u9610\u8ff0\u4e86\u8be5\u7c7b\u6750\u6599\u70ed\u7535\u6027\u80fd\u7684\u5171\u8f6d\u9aa8\u67b6\u6548\u5e94\u4e0e\u63ba\u6742\u673a\u5236\uff0c\u4e3a\u65b0\u578b\u6709\u673a\u534a\u5bfc\u4f53\u70ed\u7535\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\u548c\u91cd\u8981\u7684\u53c2\u8003\u4f9d\u636e\u3002\u76f8\u5173\u7ed3\u679c\u8fd1\u671f\u4ee5\u9898\u4e3a\u201cConjugated-Backbone Effect of Organic Small Molecules for n-Type Thermoelectric Materials with ZT over 0.2\u201d\u53d1\u8868Journal\u00a0of\u00a0the\u00a0American\u00a0Chemical\u00a0Society\u4e0a\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 \u9ad8\u6027\u80fd\u6709\u673a\u534a\u5bfc\u4f53\u70ed\u7535\u6750\u6599\u7684\u9aa8\u67b6\u6548\u5e94\u7814\u7a76\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-104907\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1.png\" alt=\"\" width=\"600\" height=\"371\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/1-300x186.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-104908\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2.png\" alt=\"\" width=\"600\" height=\"299\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/10\/2-300x150.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\u65cb\u6d82A-DCV-DPPTT\uff08a-d\uff09\u548cQ-DCM-DPPTT\uff08e-h\uff09\u819c\u7684AFM\u56fe\u50cf\uff0c\uff08a\uff0ce\uff09\u6df7\u5408\u4e860\uff05N-DMBI\uff0c\uff08b\uff0cf\uff09\u6df7\u5408\u4e861\u00a0wt\uff05N-DMBI\uff0c\uff08c\uff0cg\uff09\u6df7\u5408\u4e865\u00a0wt\uff05N-DMBI\u548c\uff08d\uff0ch\uff09\u6df7\u5408\u4e8610\u00a0wt\uff05N-DMBI\u3002<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u6709\u673a\u534a\u5bfc\u4f53\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u4e0e\u5206\u5b50\u5806\u79ef\u7279\u6027\u8d4b\u4e88\u5176\u4e30\u5bcc\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u7535\u8377\u4f20\u8f93\u548c\u80fd\u91cf\u8f6c\u6362\u5668\u4ef6\u4e2d\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u8fd1\u5e74\u6765\uff0c\u6709\u673a\u534a\u5bfc\u4f53\u7684\u70ed\u7535\u6027\u8d28\u7814\u7a76\u5f00\u59cb\u8d77\u6b65\uff0c\u9010\u6e10\u53d1\u5c55\u6210\u4e3a\u91cd\u8981\u7684\u524d\u6cbf\u7814\u7a76\u65b9\u5411\u3002\u5c3d\u7ba1\u76f8\u5173\u7814\u7a76\u6709\u671b\u4e3a\u6709\u673a\u534a\u5bfc\u4f53\u7684\u529f\u80fd\u6027\u8d28\u4e0e\u5e94\u7528\u7814\u7a76\u5e26\u6765\u65b0\u7684\u589e\u957f\u70b9\uff0c\u4f46\u4eba\u4eec\u5728\u6709\u673a\u70ed\u7535\u6750\u6599\u548c\u5668\u4ef6\u7684\u8bf8\u591a\u65b9\u9762\u90fd\u7f3a\u4e4f\u57fa\u672c\u8ba4\u77e5\uff0c\u9650\u5236\u4e86\u9886\u57df\u7684\u5feb\u901f\u53d1\u5c55\uff08Natl. Sci. Rev.\u20022016, 3, 269.\u00a0Nat. Commun. 2015, 6, 8356\uff09\u3002<\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u6709\u673a\u56fa\u4f53\u9662\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7684\u7814\u7a76\u4eba\u5458\u4e00\u76f4\u81f4\u529b\u4e8e\u6709\u673a\u70ed\u7535\u6750\u6599\u4e0e\u5668\u4ef6\u7684\u7814\u7a76\u3002\u5728\u524d\u671f\u5de5\u4f5c\u4e2d\uff0c\u4ed6\u4eec\u9488\u5bf9\u9ad8\u6548\u53d1\u5c55\u9ad8\u6027\u80fd\u6709\u673a\u70ed\u7535\u6750\u6599\u8fd9\u4e00\u9886\u57df\u6027\u96be\u9898\uff0c\u7cfb\u7edf\u5f00\u5c55\u4e86\u9ad8\u8fc1\u79fb\u7387\u6709\u673a\u534a\u5bfc\u4f53\u7684\u70ed\u7535\u6027\u8d28\u573a\u8c03\u63a7\u7814\u7a76\u3002\u4ece\u5b9e\u9a8c\u4e0a\u8bc1\u660e\u6709\u673a\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u53ef\u4ee5\u4f5c\u4e3a\u6709\u673a\u534a\u5bfc\u4f53\u70ed\u7535\u6027\u8d28\u7684\u573a\u8c03\u63a7\u5e73\u53f0\uff0c\u83b7\u5f97\u76f8\u5173\u53c2\u6570\u7684\u5236\u7ea6\u5173\u7cfb\u5e76\u63a8\u6d4b\u6027\u80fd\u4f18\u5316\u6761\u4ef6\uff0c\u4e3a\u6709\u673a\u534a\u5bfc\u4f53\u70ed\u7535\u6750\u6599\u7684\u9ad8\u6548\u9074\u9009\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\uff08Adv. Funct. Mater.\u20022015, 25, 3004\uff09\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201709\/t20170926_4615950.shtml\" target=\"_blank\" rel=\"noopener\">http:\/\/www.cas.cn\/syky\/201709\/t20170926_4615950.shtml<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.7b05344\" target=\"_blank\" rel=\"noopener\">Conjugated-Backbone Effect of Organic Small Molecules for n-Type Thermoelectric Materials with ZT over 0.2 <\/a>(J. Am. Chem. Soc., 2017, DOI:10.1021\/jacs.7b05344)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u5728\u6709\u673a\u70ed\u7535\u6750\u6599\u4f53\u7cfb\u7684\u7814\u7a76\u4e2d\uff0cn\u578b\u6750\u6599\u7684\u5f00\u53d1\u957f\u671f\u9762\u4e34\u4f53\u7cfb\u5c11\u3001\u6027\u80fd\u4f4e\u548c\u63ba\u6742\u56f0\u96be\u7b49\u96be\u9898\u3002\u5728\u79d1\u6280\u90e8\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3001\u4e2d\u79d1\u9662\u6218\u7565\u6027\u5148\u5bfc\u79d1\u6280\u4e13\u9879\u548c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66&#8230;<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-104904","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104904"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=104904"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104904\/revisions"}],"predecessor-version":[{"id":105577,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104904\/revisions\/105577"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=104904"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=104904"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=104904"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}