{"id":104463,"date":"2017-09-29T06:30:39","date_gmt":"2017-09-28T22:30:39","guid":{"rendered":"\/\/m.iemloyee.com\/?p=104463"},"modified":"2017-09-28T21:26:15","modified_gmt":"2017-09-28T13:26:15","slug":"j-am-chem-soc-%ef%bc%9a%e9%80%9a%e8%bf%87%e7%a6%bb%e6%95%a3%e7%9a%84%e6%9c%89%e6%9c%ba%e4%ba%8c%e4%bb%b7%e9%93%82%e9%87%91%e5%b1%9e%e6%9d%82%e7%8e%af%e4%bd%bfco2%e5%88%ba%e6%bf%80%e5%93%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=104463","title":{"rendered":"J. Am. Chem. Soc.\uff1a\u901a\u8fc7\u79bb\u6563\u7684\u6709\u673a\u4e8c\u4ef7\u94c2\u91d1\u5c5e\u6742\u73af\u4f7fCO2\u523a\u6fc0\u54cd\u5e94\u7684\u53ef\u6ce8\u5c04\u5d4c\u6bb5\u5171\u805a\u7269\u6c34\u51dd\u80f6\u53d1\u751f\u4ea4\u8054"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u56fe2\uff1aDLS\u53caTEM\u8868\u5f81\u7ed3\u679c\u3002<\/strong><\/p>\n

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\uff08a\uff09\u6c34\u6eb6\u6db2\u4e2dSBCP 5<\/strong>\uff08\u89c1\u56fe1\uff09\u5c3a\u5bf8\u53d8\u5316\u7684DLS\u6570\u636e\uff081.0 mg\/mL\uff09\uff1a\u6ca1\u6709\u523a\u6fc0\u7269\uff08\u7eff\u7ebf\uff09\uff0cCO2<\/sub>\u9f13\u6ce11\u5206\u949f\uff08\u7ea2\u7ebf\uff09\uff0cCO2<\/sub>\u9f13\u6ce11\u5206\u949f\u540eN2<\/sub>\u9f13\u6ce110\u5206\u949f\uff08\u84dd\u7ebf\uff09\uff1b<\/p>\n

\uff08b-d\uff09SBCP 5<\/strong>\u5728\u6c34\u6eb6\u6db2\uff081.0 mg\/mL\uff09\u4e2d\u7684TEM\u56fe\uff1a\u56fe\uff08b\uff09\u6ca1\u6709\u52a0\u5165\u523a\u6fc0\u7269\uff0c\u56fe\uff08c\uff09CO2<\/sub>\u9f13\u6ce11\u5206\u949f\uff0c\u56fe\uff08d\uff09CO2<\/sub>\u9f13\u6ce11\u5206\u949f\u540eN2<\/sub>\u9f13\u6ce110\u5206\u949f\u3002<\/p>\n

\u56fe3\uff1a\u661f\u5f62\u5d4c\u6bb5\u5171\u805a\u72695\u5728\u6c34\u6eb6\u6db2\u4e2d\u53d7CO2<\/sub>\u523a\u6fc0\u53d1\u751f\u5f62\u6001\u8f6c\u53d8\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

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\u56fe4\uff1a\u6c34\u6eb6\u6db2\u4e2dSBCP 5\u7684\u900f\u8fc7\u7387\u66f2\u7ebf\u53ca\u6d41\u4f53\u52a8\u529b\u5b66\u76f4\u5f84\u968f\u6e29\u5ea6\u7684\u53d8\u5316\u3002<\/strong><\/p>\n

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\uff08a\uff09\u4e0d\u540c\u6761\u4ef6\u4e0b\uff0c\u6c34\u6eb6\u6db2\u4e2dSBCP 5<\/strong>\uff083.0 mg\/mL\uff09\u7684\u900f\u8fc7\u7387\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u4e0d\u540c\u6761\u4ef6\u4e0b\uff0c\u6c34\u6eb6\u6db2\u4e2dSBCP 5<\/strong>\uff083.0 mg\/mL\uff09\u7684\u6d41\u4f53\u52a8\u529b\u5b66\u76f4\u5f84\uff08Dh<\/sub>\uff09\u968f\u6e29\u5ea6\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe5\uff1a\u7531CO2<\/sub>\/N2<\/sub>\u548c\u6e29\u5ea6\u5f15\u53d1\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\u51dd\u80f65\uff083.0 wt%\uff09\u7684\u53ef\u9006\u51dd\u80f6-\u6eb6\u80f6\u8f6c\u53d8\u3002<\/strong><\/p>\n

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\u56fe6\uff1a\u7528\u4e8e\u51dd\u80f6\u5316\u6d4b\u8bd5\u7684\u51e0\u79cd\u5178\u578b\u805a\u5408\u7269\u7684\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

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\u56fe7\uff1aCO2<\/sub>\u523a\u6fc0\u54cd\u5e94\u6c34\u51dd\u80f6SBCP 5\u7684\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

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\u56fe8\uff1a\u52a8\u6001\u526a\u5207\u6a21\u91cf\u3001\u7c98\u5ea6\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u3002<\/strong><\/p>\n

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\uff08a\uff09SBCP 5<\/strong>\uff083.0 wt\uff05\uff09\u6c34\u51dd\u80f6\u7684\u52a8\u6001\u526a\u5207\u6a21\u91cf\uff08\u03c3=1 Pa\uff0c\u03c9=1 rad\/s\uff09\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08b\uff09\u7ecf\u8fc7CO2<\/sub>\/\u672a\u7ecfCO2<\/sub>\u5904\u7406\u7684SBCP 5<\/strong>\u7684\u7c98\u5ea6\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u3002<\/p>\n

\u53e6\uff0c\u6570\u7801\u7167\u7247\u663e\u793a\u76f8\u5e94\u6837\u54c1\u7684\u5916\u89c2\u3002<\/p>\n

\u56fe9\uff1a\u805a\u5408\u7269\u6c34\u51dd\u80f6\u7684\u7167\u7247\u53ca\u76f8\u5e94\u5e72\u51dd\u80f6\u7684SEM\u56fe\u3002<\/strong><\/p>\n

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\uff08a\uff09\u7ecfCO2<\/sub>\u9f13\u6ce1\u7684SBCP 5<\/strong>\uff1b<\/p>\n

\uff08b\uff09\u7ecfN2<\/sub>\u9f13\u6ce1\u7684SBCP 5<\/strong>\u3002<\/p>\n

\u56fe10\uff1a\u53ef\u6ce8\u5c04\u6c34\u51dd\u80f6\u572834\u2103\u4e0b\u7ecf\u8fc7\u4e00\u5b9a\u65f6\u95f4\u7684\u7167\u7247\u3002<\/strong><\/p>\n

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\u56fe11\uff1a\u7528\u4e0d\u540c\u6d53\u5ea6SBCP 5\u5904\u7406\u8fc7\u7684MC-3T3\u3002<\/strong><\/p>\n

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\uff08a\uff09\u7528\u4e0d\u540c\u6d53\u5ea6SBCP 5<\/strong>\u5904\u7406\u8fc7\u7684MC-3T3\u7684\u7ec6\u80de\u6d3b\u6027\uff1b<\/p>\n

\uff08b\uff0dd\uff09MC-3T3\u5206\u522b\u57280\uff08\u56fe\uff08b\uff09\uff09\u300150\uff08\u56fe\uff08c\uff09\uff09\u3001125\u03bcL\uff08\u56fe\uff08d\uff09\uff09SBCP 5<\/strong>\u6c34\u51dd\u80f6\u4e2d\u57f9\u517b24\u5c0f\u65f6\u540e\u7684\u8367\u5149\u663e\u5fae\u955c\u56fe\u50cf\uff08\u6bd4\u4f8b\u5c3a=100 \u03bcm\uff09\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>CO2<\/sub> Stimuli-Responsive, Injectable Block Copolymer Hydrogels Cross-Linked by Discrete Organoplatinum(II) Metallacycles via Stepwise Post-Assembly Polymerization<\/a>\uff08J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b07303\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u6750\u6599\u7ec4arrinal_Ding\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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