{"id":104119,"date":"2017-09-27T06:30:23","date_gmt":"2017-09-26T22:30:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=104119"},"modified":"2017-09-26T19:09:14","modified_gmt":"2017-09-26T11:09:14","slug":"%e6%ad%a6%e6%b1%89%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6materials-horizons%e7%bb%bc%e8%bf%b0%ef%bc%9a%e5%8d%8a%e5%af%bc%e4%bd%93%e5%85%89%e5%82%ac%e5%8c%96%e5%9b%ba%e6%b0%ae%e5%90%88%e6%88%90%e6%b0%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=104119","title":{"rendered":"\u6b66\u6c49\u7406\u5de5\u5927\u5b66Materials Horizons\u7efc\u8ff0\uff1a\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u56fa\u6c2e\u5408\u6210\u6c28"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

\u4e00\u767e\u591a\u5e74\u4ee5\u6765\uff0c\u201c\u54c8\u4f2f\uff0d\u535a\u65bd\u201d\uff08Haber-Bosch\uff09\u56fa\u6c2e\u6cd5\u4f5c\u4e3a\u5de5\u4e1a\u4e0a\u5e94\u7528\u6700\u4e3a\u5e7f\u6cdb\u7684\u5408\u6210\u6c28\u5de5\u827a\uff0c\u4e3a\u793e\u4f1a\u53d1\u5c55\u548c\u79d1\u6280\u8fdb\u6b65\u4f5c\u51fa\u4e86\u5de8\u5927\u8d21\u732e\u3002\u7136\u800c\uff0c\u6b64\u5de5\u827a\u9700\u8981\u4e25\u82db\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u4e3a\u5b9e\u73b0\u53cd\u5e94\u6240\u9700\u8981\u7684\u9ad8\u6e29\u9ad8\u538b\u73af\u5883\u6bcf\u5e74\u90fd\u4f1a\u5bf9\u5168\u7403\u80fd\u6e90\u4ea7\u751f\u5de8\u5927\u7684\u8017\u8d39\u3002\u4f5c\u4e3a\u53cd\u5e94\u539f\u6599\uff0c\u5929\u7136\u6c14\u4e5f\u662f\u4eba\u7c7b\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u8d56\u4ee5\u751f\u5b58\u7684\u91cd\u8981\u80fd\u6e90\uff0c\u540c\u65f6\u5927\u91cf\u53cd\u5e94\u4ea7\u7269\u5305\u62ec\u6e29\u5ba4\u6c14\u4f53\u7684\u6392\u653e\u4e5f\u4f1a\u5a01\u80c1\u5730\u7403\u73af\u5883\u3002\u56e0\u6b64\uff0c\u6539\u8fdb\u4f20\u7edf\u7684\u5de5\u4e1a\u56fa\u6c2e\u6280\u672f\uff0c\u5bfb\u6c42\u9ad8\u6548\u3001\u4f4e\u8017\u3001\u6e05\u6d01\u7684\u56fa\u6c2e\u5408\u6210\u6c28\u65b9\u6cd5\u5df2\u6210\u4e3a\u8fd1\u51e0\u5e74\u7684\u7814\u7a76\u70ed\u70b9\u3002\u8fd1\u5e74\u6765\uff0c\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5b9e\u73b0\u8fd8\u539f\u6c2e\u6c14\u3001\u5236\u5907\u6c28\u6c14\u56e0\u5176\u9ad8\u6548\u6e05\u6d01\u800c\u5f15\u8d77\u5168\u4e16\u754c\u7684\u6781\u5927\u5173\u6ce8\u3002\u8fd1\u65e5\uff0cMaterials Horizons<\/strong>\u671f\u520a\u5728\u7ebf\u53d1\u8868<\/strong>\u4e86\u7531\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u674e\u80fd\u6559\u6388\u4e0e\u65b0\u52a0\u5761<\/strong>A*STAR<\/strong>\u7684Wee-Jun Ong<\/strong>\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u64b0\u5199\u7684\u7efc\u8ff0\u8bba\u6587 \u201cPhotocatalytic Fixation of Nitrogen to Ammonia: State-of-the-Art Advancement and Future Prospects<\/strong>\u201d<\/strong>\u3002\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u535a\u58eb\u4e00\u5e74\u7ea7\u5b66\u751f\u9648\u661f\u7af9\u3002\u6587\u7ae0\u5bf9\u534a\u5bfc\u4f53\u53ca\u5176\u590d\u5408\u7ed3\u6784\u5149\u50ac\u5316\u56fa\u6c2e\u4ea7\u6c28\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u603b\u7ed3\u6982\u62ec\uff0c\u5e76\u5bf9\u672a\u6765\u7814\u7a76\u65b9\u5411\u8fdb\u884c\u4e86\u63a2\u8ba8\u548c\u5c55\u671b\u3002<\/strong><\/p>\n

\u4e00\u3001 N2<\/sub><\/strong>\u5149\u50ac\u5316\u8f6c\u5316\u6982\u8ff0<\/strong><\/p>\n

N2<\/sub>\u5206\u5b50\u7531\u4e8e\u6c2e\u6c2e\u4e09\u952e\u76f8\u5bf9\u7a33\u5b9a\u96be\u4ee5\u89e3\u79bb\uff0c\u8868\u73b0\u4e3a\u5316\u5b66\u53cd\u5e94\u60f0\u6027\uff0c\u4e14\u5176\u8d28\u5b50\u4eb2\u548c\u80fd\u529b\u5f88\u5dee\uff0c\u4f7f\u5f97\u7535\u5b50\u4f20\u8f93\u548cLewis\u9178\u78b1\u53cd\u5e94\u53d7\u963b\u3002\u6b64\u5916\uff0cN2<\/sub>\u5206\u5b50\u6700\u9ad8\u5360\u636e\u8f68\u9053(HOMO)\u548c\u6700\u4f4e\u5360\u636e\u8f68\u9053(LUMO)\u4e4b\u95f4\u5b58\u5728\u8f83\u5927\u7684\u80fd\u9699(10.82eV)\uff0c\u4e5f\u5f15\u8d77\u6c2e\u6c14\u53cd\u5e94\u56f0\u96be\u3002\u56fe1\u5c55\u793a\u4e86\u5728\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u7684\u4f5c\u7528\u4e0b\uff0cN2<\/sub>\u5206\u5b50\u88ab\u5149\u50ac\u5316\u6750\u6599\u6355\u83b7\u8fdb\u800c\u88ab\u8fd8\u539f\u5b9e\u73b0N2<\/sub>\u2192NH3<\/sub>\u7684\u8f6c\u5316\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 \u5149\u50ac\u5316\u56fa\u6c2e\u5408\u6210\u6c28\u673a\u7406\u6982\u8ff0\u56fe<\/strong><\/p>\n

\u4e8c\u3001\u5149\u50ac\u5316\u56fa\u6c2e\u7684\u5206\u7c7b<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2. \u5404\u79cd\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u56fa\u6c2e\u4f53\u7cfb\u6982\u8ff0\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe3. \u4e94\u79cdN2<\/sub>\u7684\u5149\u50ac\u5316\u8f6c\u5316\u8def\u5f84<\/strong><\/p>\n

\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u4ee5\u50ac\u5316\u5242\u7684\u5316\u5408\u7269\u6210\u5206\u4e3a\u5206\u7c7b\u6807\u51c6\uff0c\u5c06\u62a5\u9053\u7684\u50ac\u5316\u5242\u5206\u4e3a\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u91d1\u5c5e\u786b\u5316\u7269\u3001\u6c27\u5364\u5316\u94cb\u3001\u78b3\u7cfb\u5316\u5408\u7269\u548c\u5176\u4ed6\u5316\u5408\u7269\u7b49\u51e0\u7c7b\uff0c\u5e76\u5bf9\u6240\u6d89\u53ca\u7684\u6bcf\u79cd\u5206\u7c7b\u8fdb\u884c\u4e86\u8be6\u7ec6\u4ecb\u7ecd\u3002\u56fe2\u548c3\u5c55\u793a\u5404\u7c7b\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5242\u4ee5\u53ca\u5149\u50ac\u5316\u56fa\u6c2e\u5408\u6210\u6c28\u7684\u4e94\u79cd\u5178\u578b\u7684\u53cd\u5e94\u8def\u5f84\u3002<\/p>\n

\u4e09\u3001\u4e3b\u8981\u51e0\u7c7b\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u4f53\u7cfb\u56fa\u6c2e\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4. TiO2<\/sub> \u8868\u9762\u56fa\u6c2e\u5e76\u8fd8\u539f\u6210\u6c28\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe5. \u786b\u7cfb\u91d1\u5c5e\u7eb3\u7c73\u4f53\u7cfb\u56fa\u6c2e\u5e76\u8fd8\u539f\u6210\u6c28\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe6. Bi-\u7cfb\u7eb3\u7c73\u4f53\u7cfb\u56fa\u6c2e\u5e76\u8fd8\u539f\u6210\u6c28\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe7. Metal-free\u78b3\u7cfb\u5316\u5408\u7269\u50ac\u5316\u56fa\u6c2e\u673a\u7406\u56fe<\/strong><\/p>\n

\u56db\u3001 \u5149\u50ac\u5316\u56fa\u6c2e\u7684\u8c03\u63a7<\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u7ae0\u8fd8\u5f3a\u8c03\u4e86\u5149\u50ac\u5316\u8fc7\u7a0b\u4e2d\uff0c\u63ba\u6742\u3001\u5f15\u5165\u7a7a\u4f4d\u3001\u7b49\u79bb\u5b50\u5171\u632f\u3001\u8868\u9762\u88c1\u526a\u548c\u5f02\u8d28\u7ed3\u7ec4\u88c5\u7b49\u4fee\u9970\u50ac\u5316\u5242\u7684\u624b\u6bb5\u4ee5\u53ca\u727a\u7272\u5242\u7684\u5b58\u5728\uff0c\u5bf9\u5176\u50ac\u5316\u6d3b\u6027\u548c\u50ac\u5316\u7279\u5f02\u6027\u7684\u5f71\u54cd\u3002\u56fe8\u4e2d\uff0c\u901a\u8fc7\u5f15\u5165\u57fa\u4f53\u4e2d\u7684\u6c27\u539f\u5b50\u7a7a\u4f4d(OV<\/sub>)\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u63d0\u5347\u5149\u50ac\u5316\u50ac\u5316\u5242\u5b8c\u6210\u56fa\u6c2e\u5408\u6210\u6c28\u7684\u6548\u7387\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8 \u6c27\u539f\u5b50\u7a7a\u4f4d\u5bf9\u4e8e\u50ac\u5316\u53cd\u5e94\u7684\u589e\u5f3a\u4f5c\u7528\u793a\u610f\u56fe<\/strong><\/p>\n

\u4e94\u3001 \u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/p>\n

\u9488\u5bf9\u76ee\u524d\u8be5\u9886\u57df\u7684\u6587\u7ae0\u56fa\u6c2e\u901f\u7387\u7684\u8868\u793a\u5b58\u5728\u5dee\u5f02\uff0c\u4f5c\u8005\u5728\u6587\u4e2d\u8fd8\u5bf9\u4e0d\u540c\u53cd\u5e94\u73af\u5883\u4e2d\u53cd\u5e94\u901f\u7387\u8fdb\u884c\u4e86\u89c4\u8303\u5316\u5904\u7406\uff0c\u540c\u65f6\u4e3a\u5149\u50ac\u5316\u56fa\u6c2e\u9886\u57df\u50ac\u5316\u901f\u7387\u7684\u6807\u51c6\u5316\u63d0\u51fa\u4e86\u5efa\u8bae\uff0c\u5b9e\u73b0\u4e86\u5bf9\u8fc7\u53bb\u7684\u7814\u7a76\u4e2d\u4e0d\u540c\u534a\u5bfc\u4f53\u56fa\u6c2e\u80fd\u529b\u7684\u5408\u7406\u6bd4\u8f83\uff0c\u4e5f\u4e3a\u540c\u9886\u57df\u4e4b\u540e\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u53c2\u8003\u3002<\/p>\n

\u968f\u7740\u7814\u7a76\u7684\u63a8\u8fdb\uff0c\u50ac\u5316\u56fa\u6c2e\u5408\u6210\u6c28\u6240\u4f7f\u7528\u7684\u6c2e\u6e90\u4e2d\u7eaf\u6c2e\u6c14\u9010\u6e10\u7531\u7a7a\u6c14\u53d6\u4ee3\uff0c\u5149\u6e90\u4e2d\u7d2b\u5916\u5149\u7ebf\u4e5f\u9010\u6e10\u7531\u53ef\u89c1\u5149\u53d6\u4ee3\uff0c\u9664\u6b64\u4e4b\u5916\uff0c\u4e0d\u5355\u5355\u662f\u5149\u50ac\u5316\uff0c\u5149\u7535\u5171\u50ac\u5316\u53cd\u5e94\u4e5f\u88ab\u5e94\u7528\u4e8e\u5b9e\u73b0\u6c2e\u6c14\u7684\u9ad8\u6548\u8fd8\u539f\u3002\u66f4\u52a0\u591a\u7684\u7814\u7a76\u65b9\u6cd5\u4f8b\u5982DFT\u4ee5\u53ca\u66f4\u5148\u8fdb\u7684\u8868\u5f81\u5de5\u827a\u4e5f\u53ef\u4ee5\u5e94\u7528\u5728\u56fa\u6c2e\u7684\u7814\u7a76\u4e2d\u3002\u8fd9\u7bc7\u7efc\u8ff0\u76f8\u4fe1\u5bf9\u4e8e\u540c\u9886\u57df\u7684\u5176\u4ed6\u7814\u7a76\u4e5f\u4f1a\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u610f\u4e49\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Photocatalytic Fixation of Nitrogen to Ammonia: State-of-the-Art Advancement and Future Prospects<\/em> <\/a>(Materials Horizons, 2017, DOI: 10.1039\/C7MH00557A)<\/p>\n

\u672c\u6587\u7531\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u674e\u80fd\u6559\u6388\u8bfe\u9898\u7ec4\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 \u4e00\u767e\u591a\u5e74\u4ee5\u6765\uff0c\u201c\u54c8\u4f2f\uff0d\u535a\u65bd\u201d\uff08Haber-Bosch\uff09\u56fa\u6c2e\u6cd5\u4f5c\u4e3a\u5de5\u4e1a\u4e0a\u5e94\u7528\u6700\u4e3a\u5e7f\u6cdb\u7684\u5408\u6210\u6c28\u5de5\u827a\uff0c\u4e3a\u793e\u4f1a\u53d1\u5c55\u548c\u79d1\u6280\u8fdb\u6b65\u4f5c\u51fa\u4e86\u5de8\u5927\u8d21\u732e\u3002\u7136\u800c\uff0c\u6b64\u5de5\u827a\u9700\u8981\u4e25…<\/p>\n","protected":false},"author":1369,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[],"class_list":["post-104119","post","type-post","status-publish","format-standard","hentry","category-zongshu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104119"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1369"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=104119"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104119\/revisions"}],"predecessor-version":[{"id":104225,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104119\/revisions\/104225"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=104119"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=104119"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=104119"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}