{"id":104036,"date":"2017-09-28T06:30:40","date_gmt":"2017-09-27T22:30:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=104036"},"modified":"2017-09-26T18:48:28","modified_gmt":"2017-09-26T10:48:28","slug":"%e6%9d%8e%e6%b0%b8%e8%88%ab%e9%99%a2%e5%a3%abangew-chem-int-ed-%ef%bc%9a%e4%b8%ba%e9%ab%98%e6%80%a7%e8%83%bd%e5%85%a8%e8%81%9a%e5%90%88%e7%89%a9%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=104036","title":{"rendered":"\u674e\u6c38\u822b\u9662\u58ebAngew. Chem. Int. Ed.\uff1a\u4e3a\u9ad8\u6027\u80fd\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6784\u5efa\u5f3a\u5438\u6536\u7a84\u5e26\u9699\u805a\u5408\u7269\u53d7\u4f53"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u53ef\u6eb6\u6db2\u52a0\u5de5\u7684\u5171\u8f6d\u805a\u5408\u7269\u7531\u4e8e\u5176\u5728\u65b0\u4e00\u4ee3\u4f4e\u6210\u672c\uff0c\u67d4\u6027\u548c\u5370\u5237\u7535\u5b50\u4ea7\u54c1\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\u800c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\uff08all-PSCs\uff09\u4e3a\u67d4\u6027\u5668\u4ef6\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u72ec\u7279\u7684\u5f62\u6001\u7a33\u5b9a\u6027\uff0c\u4f46\u7f3a\u4e4f\u9ad8\u6027\u80fd\u805a\u5408\u7269\u53d7\u4f53\u4f7f\u5176\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u4f4e\u4e8e\u57fa\u4e8e\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u6216\u6709\u673a\u5c0f\u5206\u5b50\u53d7\u4f53\u7684PSCs\u7684\u6548\u7387\u3002\u8bbe\u8ba1\u5408\u6210\u5f3a\u5438\u6536\u7a84\u5e26\u9699\u805a\u5408\u7269\u53d7\u4f53\u662f\u63d0\u9ad8\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u6362\u6548\u7387\u7684\u5173\u952e\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u674e\u6c38\u822b\u9662\u58eb\u548c\u5f20\u5fd7\u56fd\u526f\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u5c55\u793a\u4e86\u5c06\u5177\u6709\u53d7\u4f53-\u7ed9\u4f53-\u53d7\u4f53\uff08A-D-A\uff09\u7ed3\u6784\u7684\u5f3a\u5438\u6536\u7a84\u5e26\u9699\u5c0f\u5206\u5b50\u53d7\u4f53\u7ed3\u6784\u5355\u5143\u3001\u901a\u8fc7\u4e0e\u567b\u5429\u5355\u5143\u5171\u805a\u5408\u6210\u9ad8\u6027\u80fd\u805a\u5408\u7269\u53d7\u4f53PZ1\u7684\u7b56\u7565\u3002PZ1\u5177\u67091.55eV\u7684\u7a84\u5e26\u9699\u548c\u9ad8\u5438\u6536\u7cfb\u6570\uff081.3\u00d710<sup>5<\/sup>cm<sup>-1<\/sup>\uff09\u7684\u5bbd\u5438\u6536\u3002\u4f7f\u7528\u5bbd\u5e26\u9699\u805a\u5408\u7269PBDB-T\u4f5c\u4e3a\u7ed9\u4f53\u548cPZ1\u4e3a\u53d7\u4f53\u7684\u5168\u805a\u5408\u7269PSCs\u5177\u67099.19\uff05\u7684\u9ad8PCE\uff0c\u8fd9\u662f\u5168\u805a\u5408\u7269PSCs\u6548\u7387\u76ee\u524d\u7684\u6700\u9ad8\u503c\u3002\u53e6\u5916\u4f5c\u8005\u5c06\u5149\u8bf1\u5bfc\u529b\u663e\u5fae\u955c-\u7eb3\u7c73\u7ea2\u5916\u5149\u8c31\u6280\u672f\uff08PIFM\uff09\u9996\u6b21\u7528\u4e8e\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u5f62\u8c8c\u89c2\u6d4b\u4e2d\uff0c\u8fd9\u79cd\u6280\u672f\u80fd\u591f\u6839\u636e\u7ed9\u53d7\u4f53\u7684\u5b98\u80fd\u56e2\u7684\u4e0d\u540c\uff0c\u4ece\u7eb3\u7c73\u5c3a\u5ea6\u9610\u91ca\u6d3b\u6027\u5c42\u5f62\u8c8c\u4e0e\u5668\u4ef6\u6027\u80fd\u7684\u5173\u8054\uff0c\u4e3aPSCs\u5f62\u8c8c\u4f18\u5316\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Constructing a Strongly Absorbing Low-Bandgap Polymer Acceptor for High-Performance All-Polymer Solar Cells<\/strong>\u201d\u53d1\u8868\u5728\u4e86<strong>Angewandte Chemie International Edition<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u7528\u4e8e\u5168\u805a\u5408\u7269PSCs\u7684\u6709\u4ee3\u8868\u6027\u805a\u5408\u7269\u53d7\u4f53\u4ee5\u53ca\u805a\u5408\u7269\u53d7\u4f53PZ1\u548c\u805a\u5408\u7269\u7ed9\u4f53PBDB-T\u7684\u5206\u5b50\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-104037\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/1-50.png\" alt=\"\" width=\"600\" height=\"315\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/1-50.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/1-50-300x158.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2 \u5438\u6536\u5149\u8c31\u548c\u5faa\u73af\u4f0f\u5b89\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-104038\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/2-50.png\" alt=\"\" width=\"600\" height=\"279\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/2-50.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/2-50-300x140.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09PZ1\uff08\u7ea2\u7ebf\uff09\u548cIDIC-C16\uff08\u84dd\u7ebf\uff09\u7684\u6eb6\u6db2\u548c\u819c\u5438\u6536\u5149\u8c31<\/p>\n<p>\uff08b\uff09PZ1\uff08\u7ea2\u7ebf\uff09\u548cIDIC-C16\uff08\u84dd\u7ebf\uff09\u7684\u5faa\u73af\u4f0f\u5b89\u56fe<\/p>\n<p><strong>\u56fe3<\/strong> <strong>\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf\u53caIPCE\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-104039\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/3-39.png\" alt=\"\" width=\"600\" height=\"322\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/3-39.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/3-39-300x161.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5728AM 1.5G\uff0c100mW \/ cm <sup>2<\/sup>\u7684\u5149\u7167\u4e0b\uff0c\u57fa\u4e8ePBDB-T\uff1a\u53d7\u4f53\uff081.5:1\uff0cw \/ w\uff09\u7684\u5168\u805a\u5408\u7269PSCs\u7684J-V\u66f2\u7ebf<\/p>\n<p>\uff08b\uff09\u76f8\u5e94PSCs\u7684IPCE\u968f\u6ce2\u957f\u7684\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe4 \u5149\u8bf1\u5bfc\u529b\u663e\u5fae\u955c-\u7eb3\u7c73\u7ea2\u5916\u5149\u8c31\uff08PIFM\uff09\u56fe\u50cf\u548c\u63a0\u5165\u5c04\u5c0f\u89d2X\u5c04\u7ebf\u6563\u5c04\uff08GIWAXS\uff09\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-104040\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/4-40.png\" alt=\"\" width=\"600\" height=\"506\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/4-40.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/09\/4-40-300x253.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff0cb\uff09\u57281649cm <sup>-1<\/sup>\u5904\u68c0\u6d4bPBDB-T\u548c1700cm <sup>-1<\/sup>\u5904\u68c0\u6d4bPZ1\u7684\uff08a\uff09\u672a\u7ecf\u4f18\u5316\u5904\u7406\u548c\uff08b\uff09\u4f18\u5316\u5904\u7406\u7684PBDB-T\uff1aPZ1\u6df7\u5408\u819c\u7684PIFM\u56fe\u50cf<\/p>\n<p>\uff08c\uff0cd\uff09\uff08c\uff09\u672a\u7ecf\u4f18\u5316\u5904\u7406\u548c\uff08d\uff09\u4f18\u5316\u5904\u7406\u7684PBDB-T\uff1aPZ1\u6df7\u5408\u819c\u7684GIWAXS\u56fe\u50cf<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u8be5\u56e2\u961f\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4ee5A-D-A\u7ed3\u6784\u5f3a\u5438\u6536\u7a84\u5e26\u9699\u5c0f\u5206\u5b50\u53d7\u4f53\u4e3a\u6784\u7b51\u5355\u5143\u7684\u65b0\u578b\u03c0-\u5171\u8f6d\u805a\u5408\u7269\u53d7\u4f53PZ1\uff0c\u8be5\u805a\u5408\u7269\u4ee5n-\u578b\u6709\u673a\u534a\u5bfc\u4f53 IDIC-C16\u4f5c\u4e3a\u5173\u952e\u7ed3\u6784\u5355\u5143\u548c\u567b\u5429\u4f5c\u4e3a\u03c0\u6865\u3002\u65b0\u7684\u805a\u5408\u7b56\u7565\u4fdd\u7559\u4e86\u5c0f\u5206\u5b50\u53d7\u4f53\u7684\u5f3a\u5438\u6536\uff08\u5438\u6536\u7cfb\u6570\u8fbe\u52301.3\u00d710<sup>5<\/sup> cm <sup>-1<\/sup>\uff09\u3001\u5e76\u6709\u6548\u5ef6\u4f38\u4e86\u5176\u03c0\u5171\u8f6d\u4f7f\u5438\u6536\u5149\u8c31\u7ea2\u79fb\u4ee5\u83b7\u5f97\u66f4\u597d\u7684\u5149\u5438\u6536\u3002\u8fd9\u79cd\u805a\u5408\u7b56\u7565\u7684\u6210\u529f\u4e3a\u5168\u805a\u5408\u7269PSCs\u5f00\u53d1\u9ad8\u6548\u7684\u805a\u5408\u7269\u53d7\u4f53\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201707678\/full\" target=\"_blank\" rel=\"noopener\">Constructing a Strongly Absorbing Low-Bandgap Polymer Acceptor for High-Performance All-Polymer Solar Cells<\/a>\uff08Angew. Chem. Int. Ed. ,2017,DOI:DOI: 10.1002\/anie.201707678\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u524d\u7ebfAllen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1axiaofire-18\uff0c\u5434\u73ab\uff0c\u6211\u4eec\u4f1a\u62c9\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n<p><strong><b>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong><strong><b>\u4e0a<\/b><\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><b>\u6d4b\u8bd5\u8c37<\/b><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u53ef\u6eb6\u6db2\u52a0\u5de5\u7684\u5171\u8f6d\u805a\u5408\u7269\u7531\u4e8e\u5176\u5728\u65b0\u4e00\u4ee3\u4f4e\u6210\u672c\uff0c\u67d4\u6027\u548c\u5370\u5237\u7535\u5b50\u4ea7\u54c1\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\u800c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\uff08all-PSCs\uff09\u4e3a\u67d4\u6027\u5668\u4ef6\u7684\u5e94&#8230;<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-104036","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104036"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=104036"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104036\/revisions"}],"predecessor-version":[{"id":104214,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/104036\/revisions\/104214"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=104036"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=104036"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=104036"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}