{"id":104022,"date":"2017-09-30T06:30:35","date_gmt":"2017-09-29T22:30:35","guid":{"rendered":"\/\/m.iemloyee.com\/?p=104022"},"modified":"2017-09-28T13:20:21","modified_gmt":"2017-09-28T05:20:21","slug":"j-am-chem-soc-mof%e5%82%ac%e5%8c%96%e5%89%82%e5%9c%a8%e9%97%b4%e6%ad%87%e5%92%8c%e6%b5%81%e5%8a%a8%e5%8f%8d%e5%ba%94%e4%b8%ad%e4%bc%98%e5%bc%82%e7%9a%84%e5%8c%96%e5%ad%a6%e7%a8%b3%e5%ae%9a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=104022","title":{"rendered":"J. Am. Chem. Soc. : MOF\u50ac\u5316\u5242\u5728\u95f4\u6b47\u548c\u6d41\u52a8\u53cd\u5e94\u4e2d\u4f18\u5f02\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u5bf9\u6620\u9009\u62e9\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u591a\u76f8\u50ac\u5316\u4e2d\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u5f88\u5927\u7a0b\u5ea6\u4e0a\u7531\u6d3b\u6027\u4f4d\u70b9\u6240\u5904\u73af\u5883\u4ee5\u53ca\u7535\u5b50\u7ed3\u6784\u6240\u51b3\u5b9a\u3002\u8fd1\u5e74\u6765\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u4f5c\u4e3a\u4e00\u7c7b\u65b0\u578b\u591a\u5b54\u6676\u4f53\u6750\u6599\uff0c\u5176\u5353\u8d8a\u7684\u7406\u5316\u6027\u8d28\u5f15\u53d1\u4e86\u7814\u7a76\u4eba\u5458\u6d53\u539a\u7684\u7814\u7a76\u5174\u8da3\u3002\u6839\u636eMOF\u5b54\u9699\u5ea6\u9ad8\u7684\u53ef\u8c03\u7ed3\u6784\uff0c\u53ef\u5c06\u5176\u8bbe\u8ba1\u4e3a\u7528\u4e8e\u6709\u673a\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\u7684\u5355\u4f4d\u70b9\u56fa\u6001\u50ac\u5316\u5242\u3002\u4f46\u8c03\u8282MOF\u7684\u6d3b\u6027\u4f4d\u70b9\u624b\u6027\u73af\u5883\u548c\u5316\u5b66\u6027\u8d28\u4ee5\u63a7\u5236\u53cd\u5e94\u548c\u7acb\u4f53\u9009\u62e9\u6027\u4ecd\u5177\u6709\u4e00\u5b9a\u6311\u6218\u6027\u3002\u6b64\u5916\uff0cMOF\u50ac\u5316\u5242\u9762\u4e34\u7684\u53e6\u4e00\u4e2a\u4e3b\u8981\u95ee\u9898\u662f\u5728\u6f6e\u6e7f\u548c\u82db\u523b\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u4f4e\u7a33\u5b9a\u6027\uff0c\u9650\u5236\u5176\u5728\u5b9e\u9645\u50ac\u5316\u8fc7\u7a0b(\u5728\u5de5\u4e1a\u4e2d\u666e\u904d\u91c7\u7528\u7684\u6d41\u52a8\u53cd\u5e94\u7cfb\u7edf)\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u5d14\u52c7\u6559\u6388\u548c\u5218\u71d5\u7814\u7a76\u5458<\/strong>(<\/strong>\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>)<\/strong>\u7b49\u9996\u6b21\u8bc1\u5b9e\u53ef\u901a\u8fc7\u8c03\u8282MOF\u7684\u914d\u4f53\u7ed3\u6784\u8fdb\u800c\u63d0\u5347\u5176\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u50ac\u5316\u6d3b\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u5e76\u5728J. Am. Chem. Soc.<\/em><\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cBoosting Chemical Stability, Catalytic Activity and Enantioselectivity of Metal-Organic Frameworks for Batch and Flow Reactions<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u76f8\u6bd4\u542b\u6709-F\u548c-Me\u57fa\u56e2\u7684MOF\uff0c\u542b\u6709-CF3<\/sub>\u57fa\u56e2\u7684MOF\u5c55\u54c1\u8010\u6c34\u3001\u5f31\u9178\u78b1\u7684\u6027\u80fd\u6709\u6240\u589e\u5f3a\u3002\u5728\u95f4\u6b47\u548c\u6d41\u52a8\u53cd\u5e94\u7cfb\u7edf\u4e0b\uff0c\u542b-CF3<\/sub>\u7684MOF\u5c55\u793a\u51fa\u826f\u597d\u7684\u53cd\u5e94\u6d3b\u6027\u3001\u9009\u62e9\u6027\u548c\u53ef\u56de\u6536\u6027\uff0c\u5728\u4e00\u7cfb\u5217\u916e\u9178\u916f\u6216\u785d\u57fa\u70ef\u5b58\u5728\u4e0b\u5432\u54da\u548c\u5421\u54af\u7684\u70f7\u57fa\u5316\u53cd\u5e94\u8868\u73b0\u51fa\u8f83\u9ad8\u6536\u7387\u548c\u5bf9\u6620\u9009\u62e9\u6027\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u76f8\u5e94\u7684\u5747\u76f8\u50ac\u5316\u5242\u5728\u6d4b\u8bd5\u6027\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u5bf9\u6620\u9009\u62e9\u6027\u8f83\u4f4e\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u914d\u4f53\u53ca<\/strong>MOF<\/strong>\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

a) \u6709\u673a\u914d\u4f53H5<\/sub>L1<\/sup><\/strong>-H5<\/sub>L3<\/sup><\/strong>\u7684\u7ed3\u6784\uff1b<\/p>\n

b) MOFs 1-3\u7684\u4e09\u7ef4\u62d3\u6251\u7ed3\u6784\uff1b<\/p>\n

c) MOFs 1\u548c2\u7684\u9aa8\u67b6\u89c6\u56fe(\u9530\u5143\u7d20\u4e3a\u7eff\u8272\u591a\u9762\u4f53\uff1b\u6c27\u5143\u7d20\u4e3a\u7ea2\u8272\uff1b\u78f7\u5143\u7d20\u4e3a\u9ec4\u8272\uff1b\u78b3\u5143\u7d20\u4e3a\u9ed1\u8272\uff1b\u6c1f\u5143\u7d20\u4e3a\u6d45\u84dd\u8272\u3002\u6c22\u539f\u5b50\u672a\u6807\u51fa)\u3002<\/p>\n

\u56fe<\/strong>2\u00a0 <\/strong>\u50ac\u5316\u5242\u7684\u8868\u5f81\u53ca\u6d3b\u6027\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a-c) MOFs 1-3\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

d,e) 77 K\u4e0b\u6c2e\u6c14\u5438\u9644(\u5b9e\u5fc3\u7b26\u53f7)\u548c\u8131\u9644(\u7a7a\u5fc3\u7b26\u53f7)\u7b49\u6e29\u7ebf\uff1b<\/p>\n

f) \u03b1<\/em>-\u916e\u9178\u916f\u4e0bMOF\u50ac\u5316N<\/em>-\u7532\u57fa\u5432\u54da\u70f7\u57fa\u5316\u7684\u5faa\u73af\u6d4b\u8bd5\u3002<\/p>\n

\u56fe<\/strong>3<\/strong> \u00a0MOF 1<\/strong>\u50ac\u5316\u53cd\u5e94\u5b9e\u4f8b<\/strong>1<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u5728\u8fde\u7eed\u6d41\u52a8\u4f53\u7cfb\u4e0b\uff0cMOF 1\u50ac\u5316\u7684\u03b2<\/em>,\u03b3<\/em>-\u4e0d\u9971\u548c-\u03b1<\/em>-\u916e\u9178\u916f\u4e0eN<\/em>-\u7532\u57fa\u5432\u54da\u7684\u5085-\u514b\u70f7\u57fa\u5316\u53cd\u5e94\u3002<\/p>\n

\u56fe<\/strong>4 \u00a0<\/strong>MOF 1<\/strong>\u50ac\u5316\u53cd\u5e94\u5b9e\u4f8b<\/strong>2<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

MOF 1\u50ac\u5316\u7684\u5085-\u514b\u70f7\u57fa\u5316\u53cd\u5e94\u7528\u4e8eCOX-2(\u73af\u6c27\u9176-2)\u6291\u5236\u5242\u7684\u5408\u6210\u3002<\/p>\n

\u00a0<\/strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u8bc1\u5b9e\uff0c\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u914d\u4f53\u7a7a\u95f4\u4f4d\u963b\u548c\u7535\u5b50\u6548\u5e94\u540c\u65f6\u8c03\u8282\u624b\u6027MOF\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u50ac\u5316\u6d3b\u6027\u548c\u5bf9\u6620\u9009\u62e9\u6027\u3002\u5728\u95f4\u6b47\u548c\u6d41\u52a8\u53cd\u5e94\u7cfb\u7edf\u4e0b\uff0c\u5177\u6709\u5438\u7535\u5b50\u3001\u5927\u4f4d\u963b\u6548\u5e94\u57fa\u56e2\u7684MOF 1<\/strong>\uff0c\u5728\u5432\u54da\u548c\u5421\u54af\u7684\u4e0d\u5bf9\u79f0\u5085-\u514b\u70f7\u57fa\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u9ad8\u53cd\u5e94\u6d3b\u6027\u3001\u7acb\u4f53\u9009\u62e9\u6027\u4ee5\u53ca\u826f\u597d\u7684\u7a33\u5b9a\u6027\u548c\u53ef\u56de\u6536\u6027\uff0c\u6613\u4e8e\u5236\u5907\u4e00\u7cfb\u5217\u5177\u6709\u5149\u5b66\u6d3b\u6027\u7684\u5432\u54da\u548c\u5421\u54af\u884d\u751f\u7269\u3002\u56e0\u6b64\uff0c\u8be5\u5de5\u4f5c\u4e3a\u5236\u5907\u5177\u6709\u9ad8\u50ac\u5316\u6d3b\u6027\u3001\u9009\u62e9\u6027\u548c\u8010\u7528\u6027\u7684\u591a\u76f8\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\uff0c\u4e5f\u4fc3\u8fdb\u4e86\u7528\u4e8e\u5bf9\u6620\u9009\u62e9\u6027\u8fc7\u7a0b\u7684\u65b0\u578b\u529f\u80fd\u6750\u6599\u7684\u53d1\u5c55\u3002\u4f7f\u7528MOF 1<\/strong>\u4f5c\u4e3a\u81ea\u652f\u6491\u50ac\u5316\u5242\u7528\u4e8e\u8fde\u7eed\u6d41\u52a8\u53cd\u5e94\u610f\u5473\u7740\u5411MOF\u7528\u4e8e\u5236\u836f\u548c\u7cbe\u7ec6\u5316\u5de5\u4ea7\u4e1a\u8fc8\u51fa\u4e86\u91cd\u8981\u7684\u4e00\u6b65\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Boosting Chemical Stability, Catalytic Activity and Enantioselectivity<\/strong><\/a>\u00a0of Metal-Organic Frameworks for Batch and Flow Reactions.<\/a>\u00a0<\/strong> (J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b06459)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u8096\u6770\u7f16\u8bd1\uff0c\u5218\u5b87\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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