{"id":103427,"date":"2017-09-27T14:00:40","date_gmt":"2017-09-27T06:00:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=103427"},"modified":"2017-09-27T14:12:40","modified_gmt":"2017-09-27T06:12:40","slug":"%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e5%b7%a5%e5%ad%a6%e9%99%a2%e7%8e%8b%e5%89%8d%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e5%9c%a8%e5%a4%9a%e7%94%b5%e8%8d%b7%e9%98%b4%e7%a6%bb%e5%ad%90%e5%9b%a2%e7%b0%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=103427","title":{"rendered":"\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u738b\u524d\u8bfe\u9898\u7ec4\uff1a\u5728\u591a\u7535\u8377\u9634\u79bb\u5b50\u56e2\u7c07\u7814\u7a76\u4e2d\u53d6\u5f97\u65b0\u8fdb\u5c55"},"content":{"rendered":"
\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u56fd\u9645\u77e5\u540d\u5b66\u672f\u671f\u520aAngew. Chem. Int. Ed.\uff08\u300a\u5fb7\u56fd\u5e94\u7528\u5316\u5b66\u300b\uff09\u4ee5VIP\uff08Very Important Paper\uff09\u548c\u5c01\u9762\u8bba\u6587\u5f62\u5f0f\uff0c\u5728\u7ebf\u53d1\u8868\u4e86\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u5e94\u7528\u7269\u7406\u4e0e\u6280\u672f\u7814\u7a76\u4e2d\u5fc3\u738b\u524d\u6559\u6388\u8bfe\u9898\u7ec4\u4e0e\u5176\u5408\u4f5c\u8005\u5173\u4e8e\u6c14\u76f8\u591a\u7535\u8377\u9634\u79bb\u5b50\u56e2\u7c07\u7814\u7a76\u7684\u65b0\u8fdb\u5c55\uff1a\u201cColossal Stability of Gas Phase Tri-anions: The Concept of Super-pnictogens\u201d\uff0c\u62a5\u9053\u4e86\u4ed6\u4eec\u901a\u8fc7\u6a21\u62df\u8ba1\u7b97\u8bbe\u8ba1\u51fa\u4e00\u7c7b\u8fc4\u4eca\u4e3a\u6b62\u6700\u7a33\u5b9a\u7684\u4e09\u4ef7\u9634\u79bb\u5b50\u56e2\u7c07\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong>1 <\/strong>\u4e09\u4ef7\u9634\u79bb\u5b50\u56e2\u7c07\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n \u00a0 \u56fe<\/strong>2 Al 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SCN)\u7684\u914d\u4f4d\u4fee\u9970\uff0c\u9996\u6b21\u53d1\u73b0\u4e86\u4e00\u7c7b\u4ee5BeB11<\/sub>(CN)12<\/sub>\u3001BeB11<\/sub>(SCN)12<\/sub>\u548cBeB11<\/sub>(BO)12<\/sub>\u4e3a\u4ee3\u8868\u7684\u7a33\u5b9a\u7684\u6c14\u6001\u4e09\u4ef7\u9634\u79bb\u5b50\u56e2\u7c07\u3002\u901a\u8fc7\u8fdb\u4e00\u6b65\u7814\u7a76\u8fd9\u7c7b\u56e2\u7c07\u4e0eAl\u5143\u7d20\u7684\u6700\u4f18\u7ed3\u5408\uff0c\u8bfe\u9898\u7ec4\u4ece\u7406\u8bba\u4e0a\u8bc1\u5b9e\u4e86\u5c06\u8fd9\u7c7b\u56e2\u7c07\u7528\u4e8e\u94dd\u79bb\u5b50\u7535\u6c60\u7535\u89e3\u6db2\u7684\u4f18\u8d8a\u6027\u3002\u6b64\u5916\uff0c\u8bfe\u9898\u7ec4\u8fd8\u53d1\u73b0\u8fd9\u7c7b\u56e2\u7c07\u5bf9\u60f0\u6027\u539f\u5b50\u6c29(Ar)\u548c\u6c2a(Kr)\u8868\u73b0\u51fa\u8d85\u6c27\u5316\u6027\u3002\u8fd9\u4e9b\u53d1\u73b0\u5c06\u6709\u529b\u63a8\u52a8\u56e2\u7c07\u79d1\u5b66\u7684\u53d1\u5c55\u548c\u65b0\u578b\u7535\u6c60\u6750\u6599\u7684\u7814\u53d1\u3002<\/p>\n \u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u738b\u524d\u8bfe\u9898\u7ec4\u7684\u535a\u58eb\u7814\u7a76\u751f\u8d75\u5929\u5c71\uff0c\u8bba\u6587\u5408\u4f5c\u8005\u5305\u62ec\u7f8e\u56fd\u5f17\u5409\u5c3c\u4e9a\u8054\u90a6\u5927\u5b66\u7269\u7406\u7cfb\u5468\u5065\u535a\u58eb\u548cPuru Jena\u6559\u6388\uff1b\u738b\u524d\u6559\u6388\u548cJena\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u79d1\u6280\u90e8\u56fd\u9645\u79d1\u6280\u5408\u4f5c\u91cd\u70b9\u4e13\u9879\u7684\u8d44\u52a9\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1a<\/strong>http:\/\/pkunews.pku.edu.cn\/xxfz\/2017-09\/20\/content_299267.htm<\/a><\/strong><\/p>\n \u6587\u732e\u94fe\u63a5\uff1aColossal Stability of Gas-Phase Trianions: Super-Pnictogens<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed.,2017,DIO:<\/strong> 10.1002\/anie.201706764)<\/strong><\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8deer\u7f16\u8f91\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<\/strong><\/p>\n
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