{"id":103275,"date":"2017-09-23T14:00:13","date_gmt":"2017-09-23T06:00:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=103275"},"modified":"2017-09-21T20:10:11","modified_gmt":"2017-09-21T12:10:11","slug":"%e6%ad%a6%e6%b1%89%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6nano-energy-%e8%87%aa%e9%80%82%e5%ba%94%e4%bb%8b%e5%ad%94cos-%e5%b0%8f%e6%b3%a1%e7%8a%b6%e7%a2%b3%e5%a3%b3%e8%9b%8b%e9%bb%84-%e8%9b%8b%e5%a3%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=103275","title":{"rendered":"\u6b66\u6c49\u7406\u5de5\u5927\u5b66Nano Energy : \u81ea\u9002\u5e94\u4ecb\u5b54CoS-\u5c0f\u6ce1\u72b6\u78b3\u58f3\u86cb\u9ec4-\u86cb\u58f3\u5fae\u7403\u7528\u4e8e\u78b1\u91d1\u5c5e\u79bb\u5b50\u50a8\u5b58"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u76f8\u6bd4\u63d2\u5165\u5f0f\u9633\u6781\u6750\u6599\uff0c\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\uff08TMCs\uff09\u5177\u6709\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\u3002\u8fd1\u6765\uff0c\u7531\u4e8e\u786b\u5316\u94b4\u8f83\u4f4e\u7684\u6210\u672c\u548c\u8f83\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u88ab\u7528\u4e8eLi+<\/sup>\u548cNa+<\/sup>\u4e3b\u4f53\u6750\u6599\u3002\u7136\u800c\uff0c\u4e25\u91cd\u7684\u4f53\u79ef\u53d8\u5316\u5e26\u6765\u7684\u4e0d\u5229\u5f71\u54cd\u4f7f\u5176\u96be\u4ee5\u6ee1\u8db3\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u8981\u6c42\uff0c\u5c24\u5176\u662f\u5faa\u73af\u6027\u80fd\u3002\u6784\u7b51\u5fae\u7eb3\u5206\u7ea7\u7ed3\u6784\uff08\u5982\u7a7a\u5fc3\u7ed3\u6784CoSx<\/sub>\uff09\u4ee5\u53ca\u590d\u5408\u78b3\u6750\u6599\uff08\u5982\u5939\u5c42\u578b\u786b\u5316\u94b4-\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\uff09\u53ef\u4ee5\u6539\u5584\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u7136\u800c\uff0c\u81ea\u8eab\u7ed3\u6784\u7684\u6539\u53d8\u4ee5\u53ca\u5f00\u653e\u78b3\u4f53\u7cfb\u4fee\u9970\u65e0\u6cd5\u5b8c\u5168\u514b\u670d\u4e25\u91cd\u7684\u4f53\u79ef\u53d8\u5316\u3002\u7ecf\u8fc7\u7814\u7a76\u5df2\u8bc1\u5b9e\u5982\u86cb\u9ec4-\u86cb\u58f3\u78b3\u6d82\u8986\u7ed3\u6784\u7684\u9650\u5236\u6027\u7ed3\u6784\u53ef\u6709\u6548\u5730\u6539\u5584\u7535\u6781\u7684\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u53ef\u63a7\u9ec4-\u58f3\u7ed3\u6784\u6709\u671b\u6539\u5584\u786b\u5316\u94b4\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5728\u4fc3\u8fdb\u5927\u4f53\u79ef\u53d8\u5316\u9633\u6781\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u4e2d\u5177\u6709\u91cd\u5927\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u3001\u9b4f\u6e6b\u9f99\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u6784\u7b51\u4e86\u4e00\u79cd\u72ec\u7279\u7684\u7531\u4ecb\u5b54\u786b\u5316\u94b4\u86cb\u9ec4\u548c\u5c0f\u6ce1\u72b6\u78b3\u58f3\u7ec4\u6210\u7684\u9ec4-\u58f3\u5fae\u7403\u4f53(M-CoS@C)\uff0c\u5e76\u5728Nano Energy<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cSelf-adaptive mesoporous CoS@alveolus-like carbon yolk-shell microsphere for alkali cations storage\u201d<\/strong>\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ecb\u5b54CoS\u86cb\u9ec4\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0846.3 m2<\/sup>\u00b7g-1<\/sup>\uff09\u4ee5\u53ca\u76f8\u4e92\u8fde\u63a5\u7684\u4ecb\u5b54\u7ed3\u6784\uff0c\u53ef\u4fc3\u8fdb\u7535\u89e3\u6db2\u7684\u6e17\u900f\u4ee5\u53ca\u7f29\u77ed\u79bb\u5b50\u6269\u6563\u8def\u5f84\u3002\u5c0f\u6ce1\u72b6\u78b3\u58f3\u63d0\u4f9b\u4e86\u8db3\u591f\u7684\u7a7a\u9699\u548c\u9ad8\u5ea6\u81ea\u9002\u5e94\u7ed3\u6784\uff0c\u786e\u4fdd\u4e86\u7535\u6781\u7684\u9ad8\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u8be5\u72ec\u7279\u7ed3\u6784\u7684\u591a\u529f\u80fd\u6027\uff0cM-CoS@C\u7535\u6781\u663e\u793a\u51fa\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u50a8\u95021 A\u00b7g-1<\/sup> 500\u5708\u540e790 mAh\u00b7g-1<\/sup>\uff0c\u50a8\u94a00.2 A\u00b7g-1<\/sup> 100\u5708\u540e532 mAh\u00b7g-1<\/sup>\uff09\u548c\u4f18\u79c0\u7684\u500d\u7387\u5bb9\u91cf\uff08\u50a8\u950220 A\u00b7g-1<\/sup>\u65f6330 mAh\u00b7g-1<\/sup>\uff0c\u50a8\u94a020 A\u00b7g-1<\/sup>\u65f6190 mAh\u00b7g-1<\/sup>\uff09\u3002\u4e0a\u8ff0\u72ec\u7279\u7684\u4ecb\u5b54\u86cb\u9ec4-\u5c0f\u6ce1\u72b6\u78b3\u58f3\u7ed3\u6784\u548c\u81ea\u727a\u7272\u7684\u5408\u6210\u65b9\u6cd5\u4e3a\u52a0\u5feb\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u5728\u5b9e\u9645\u4e2d\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u7b56\u7565\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 M-CoS@C\u7684\u5236\u5907\u53ca\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n

b,f) \u524d\u9a71\u4f53\u7684SEM\u548cTEM\u56fe\uff1b<\/p>\n

c,g) \u524d\u9a71\u4f53@SiO2<\/sub>@RF\u7684SEM\u548cTEM\u56fe\uff1b<\/p>\n

d,h) M-CoS@SiO2<\/sub>@C\u7684SEM\u548cTEM\u56fe\uff1b<\/p>\n

e,i) \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684SEM\u548cTEM\u56fe\u3002<\/p>\n

\u56fe2 \u6837\u54c1\u7684\u7269\u7406\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-c) \u524d\u9a71\u4f53\u3001M-CoS\u548c\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684XRD\u8c31\u56fe\u3001Raman\u5149\u8c31\u548cN2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

d) M-CoS\u548c\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\uff1b<\/p>\n

e) \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684STEM\u548cHRTEM\uff1b<\/p>\n

f-h) \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684\u5143\u7d20\u5206\u5e03\u3002<\/p>\n

\u56fe3 \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u9633\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a,b) 0.01-3 V\u533a\u95f40.2 mV\u00b7s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u548cM-CoS\u6837\u54c1\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

c) 1 A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u548cM-CoS\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

d) \u4e0d\u540c\u7535\u6d41\u500d\u7387\u4e0b\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u548cM-CoS\u7684\u500d\u7387\u5bb9\u91cf\uff1b<\/p>\n

e) \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u5728\u4e0d\u540c\u7535\u6d41\u500d\u7387\u4e0b\u76f8\u5e94\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fe4 \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u9633\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 0.01-3 V\u533a\u95f40.2 mV\u00b7s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u6837\u54c1\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

b) 0.2 A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0bM-CoS\u548c\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

c) \u4e0d\u540c\u7535\u6d41\u500d\u7387\u4e0bM-CoS\u548c\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u7684\u500d\u7387\u5bb9\u91cf\uff1b<\/p>\n

d) \u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u5728\u4e0d\u540c\u7535\u6d41\u500d\u7387\u4e0b\u76f8\u5e94\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fe5 \u5faa\u73af\u8fc7\u7a0b\u4e2dM-CoS\u548c\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u6837\u54c1\u7684\u5f62\u8c8c\u53d8\u5316<\/strong><\/p>\n

\"\"<\/p>\n

a) M-CoS\u548c\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u5728\u7b2c0\uff0c10\uff0c50\u6b21\u5faa\u73af(\u6ee1\u7535\u72b6\u6001)\u7684SEM\u56fe\uff08\u6807\u5c3a\uff1a1 \u03bcm\uff09\u53ca\u51761 A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u76f8\u5e94\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

b) \u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5f62\u8c8c\u53d8\u5316\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe6 \u957f\u5faa\u73af\u540e\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u6837\u54c1\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a) 1 A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea650\u6b21\u5faa\u73af\u540e\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u6837\u54c1\u7684TEM\u56fe\uff1b<\/p>\n

b) 1 A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea650\u6b21\u5faa\u73af\u540e\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u6837\u54c1\u7684STEM\u56fe\uff1b<\/p>\n

c-e) 1 A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea650\u6b21\u5faa\u73af\u540e\u86cb\u9ec4-\u86cb\u58f3M-CoS@C\u6837\u54c1\u7684\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728\u8be5\u7814\u7a76\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u9996\u6b21\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cd\u72ec\u7279\u7684\u78b3\u58f3\u5305\u8986\u7684\u4ecb\u5b54CoS\u86cb\u9ec4-\u86cb\u58f3\u590d\u5408\u6750\u6599\uff08M-CoS@C\uff09\u3002\u5c0f\u6ce1\u72b6\u78b3\u58f3\u63d0\u4f9b\u4e86\u4e00\u79cd\u9ad8\u5ea6\u81ea\u9002\u5e94\u7ed3\u6784\uff0c\u53ef\u6709\u6548\u5305\u8986\u6d3b\u6027\u6750\u6599\u3002\u5f97\u76ca\u4e8e\u4e0a\u8ff0\u72ec\u7279\u7684\u86cb\u9ec4-\u86cb\u58f3\u7ed3\u6784\uff0cM-CoS@C\u7535\u6781\u80fd\u591f\u5b9e\u73b0\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0c\u8be5\u81ea\u727a\u7272\u7684\u9020\u5b54\u65b9\u6cd5\u53ef\u6269\u5c55\u5230\u4f4e\u542b\u786b\u91cf\u91d1\u5c5e\u786b\u5316\u7269\u4ee5\u6539\u5584\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Li Q, Li L, Owusu K A, et al. Self-adaptive mesoporous CoS@ alveolus-like carbon yolk-shell microsphere for alkali cations storage[J]. Nano Energy, 2017.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u8096\u6770\u7f16\u8bd1\uff0c\u5468\u68a6\u9752\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u76f8\u6bd4\u63d2\u5165\u5f0f\u9633\u6781\u6750\u6599\uff0c\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\uff08TMCs\uff09\u5177\u6709\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\u3002\u8fd1\u6765\uff0c\u7531\u4e8e\u786b\u5316\u94b4\u8f83\u4f4e\u7684\u6210\u672c\u548c\u8f83\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u88ab\u7528\u4e8eLi+\u548cNa+\u4e3b\u4f53\u6750\u6599\u3002\u7136\u800c\uff0c\u4e25\u91cd…<\/p>\n","protected":false},"author":230,"featured_media":103277,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[],"class_list":["post-103275","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/103275"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=103275"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/103275\/revisions"}],"predecessor-version":[{"id":103308,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/103275\/revisions\/103308"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/103277"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=103275"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=103275"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=103275"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}