{"id":102921,"date":"2017-09-25T06:30:04","date_gmt":"2017-09-24T22:30:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=102921"},"modified":"2017-09-25T08:57:47","modified_gmt":"2017-09-25T00:57:47","slug":"%e8%a7%82%e7%82%b9%e7%94%b5%e5%8c%96%e5%ad%a6%e5%b7%a5%e4%bd%9c%e7%ab%99%e7%9a%84%e5%8e%9f%e7%90%86%e4%b8%8e%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=102921","title":{"rendered":"\u89c2\u70b9|\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u7684\u539f\u7406\u4e0e\u5e94\u7528"},"content":{"rendered":"

1 <\/b><\/strong>\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u7684\u57fa\u672c\u6982\u8ff0<\/b><\/strong><\/p>\n

\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u5728\u7535\u6c60\u68c0\u6d4b\u4e2d\u5360\u6709\u91cd\u8981\u5730\u4f4d\uff0c\u5b83\u5c06\u6052\u7535\u4f4d\u4eea\u3001\u6052\u7535\u6d41\u4eea\u548c\u7535\u5316\u5b66\u4ea4\u6d41\u963b\u6297\u5206\u6790\u4eea\u6709\u673a\u5730\u7ed3\u5408\uff0c\u65e2\u53ef\u4ee5\u505a\u4e09\u79cd\u57fa\u672c\u529f\u80fd\u7684\u5e38\u89c4\u8bd5\u9a8c\uff0c\u4e5f\u53ef\u4ee5\u505a\u57fa\u4e8e\u8fd9\u4e09\u79cd\u57fa\u672c\u529f\u80fd\u7684\u7a0b\u5f0f\u5316\u8bd5\u9a8c\u3002<\/b><\/strong>\u5728\u8bd5\u9a8c\u4e2d\uff0c\u65e2\u80fd\u68c0\u6d4b\u7535\u6c60\u7535\u538b\u3001\u7535\u6d41\u3001\u5bb9\u91cf\u7b49\u57fa\u672c\u53c2\u6570\uff0c\u53c8\u80fd\u68c0\u6d4b\u4f53\u73b0\u7535\u6c60\u53cd\u5e94\u673a\u7406\u7684\u4ea4\u6d41\u963b\u6297\u53c2\u6570\uff0c\u4ece\u800c\u5b8c\u6210\u5bf9\u591a\u79cd\u72b6\u6001\u4e0b\u7535\u6c60\u53c2\u6570\u7684\u8ddf\u8e2a\u548c\u5206\u6790\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 \u90e8\u5206\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u5217\u8868<\/p>\n

\"\"<\/p>\n

\u56fe2 1\u4e3a\u5de5\u4f5c\u7535\u6781\uff0c2\u4e3a\u53c2\u6bd4\u7535\u6781\uff0c3\u4e3a\u5bf9\u7535\u6781<\/p>\n

1.1 \u4e09\u7535\u6781\u4f53\u7cfb<\/b><\/strong><\/p>\n

\u7814\u7a76\u7535\u6781\u4e0a\u7535\u5b50\u7684\u8fd0\u52a8\u662f\u7535\u5316\u5b66\u53cd\u5e94\u7684\u57fa\u7840\uff0c\u4e3a\u4e86\u5206\u522b\u5bf9\u7535\u6c60\u6216\u7535\u89e3\u6c60\u7684\u9634\u6781\uff0c\u9633\u6781\u53d1\u751f\u7684\u53cd\u5e94\u8fdb\u884c\u89c2\u5bdf\u9700\u7528\u5230\u4e09\u7535\u6781\u4f53\u7cfb\u3002<\/p>\n

\u52a0\u5165\u7684\u7535\u6781\u53eb\u505a\u53c2\u6bd4\u7535\u6781\uff0c\u5b83\u7684\u4f5c\u7528\u662f\u4e3a\u4e86\u6d4b\u91cf\u8fdb\u884c\u8fd9\u4e9b\u53cd\u5e94\u7684\u7535\u6781\u7535\u4f4d\u7684\u4e00\u4e2a\u57fa\u51c6\u7535\u6781\u3002\u88ab\u6d4b\u5b9a\u7684\u7535\u6781\u53eb\u505a\u5de5\u4f5c\u7535\u6781\uff0c\u4e0e\u5de5\u4f5c\u7535\u6781\u76f8\u5bf9\u7684\u7535\u6781\u53eb\u505a\u8f85\u52a9\u7535\u6781\u3002<\/p>\n

\u5728\u4e09\u7535\u6781\u6cd5\u4e2d\u4e3a\u4e86\u80fd\u591f\u5728\u6d4b\u5b9a\u7814\u7a76\u7535\u6781\u548c\u53c2\u6bd4\u7535\u6781\u4e4b\u95f4\u7535\u538b\u540c\u65f6\uff0c\u53c8\u80fd\u4efb\u610f\u8c03\u8282\u7814\u7a76\u7535\u6781\u7684\u7535\u4f4d<\/b><\/strong>\uff0c\u6700\u7406\u60f3\u7684\u8bbe\u5907\u4e3a\u5177\u6709\u81ea\u52a8\u8c03\u8282\u529f\u80fd\u7684\u6052\u7535\u4f4d\u4eea\u3002<\/p>\n

1.2 \u6052\u7535\u4f4d\u4eea\u7684\u57fa\u672c\u6982\u5ff5<\/b><\/strong><\/p>\n

\u6052\u7535\u4f4d\u4eea\u662f\u7535\u5316\u5b66\u6d4b\u8bd5\u4e2d\u6700\u91cd\u8981\u7684\u4eea\u5668\uff0c\u5176\u6027\u80fd\u7684\u4f18\u826f\u76f4\u63a5\u5f71\u54cd\u7535\u5316\u5b66\u6d4b\u8bd5\u7ed3\u679c\u7684\u51c6\u786e\u5ea6\u3002\u7531\u5b83\u63a7\u5236\u7535\u6781\u7535\u4f4d\u4e3a\u6307\u5b9a\u503c\uff0c\u4ee5\u8fbe\u5230\u6052\u7535\u4f4d\u6781\u5316\u7684\u76ee\u7684\u3002\u82e5\u7ed9\u4ee5\u6307\u4ee4\u4fe1\u53f7\uff0c\u5219\u53ef\u4f7f\u7535\u6781\u7535\u4f4d\u81ea\u52a8\u8ddf\u8e2a\u6307\u4ee4\u4fe1\u53f7\u800c\u53d8\u5316\u3002<\/b><\/strong><\/p>\n

2 \u7535\u5316\u5b66\u6d4b\u8bd5\u7b80\u8ff0<\/b><\/strong><\/p>\n

\u7535\u5316\u5b66\u6d4b\u5b9a\u65b9\u6cd5\u662f\u5c06\u5316\u5b66\u7269\u8d28\u7684\u53d8\u5316\u5f52\u7ed3\u4e3a\u7535\u5316\u5b66\u53cd\u5e94\uff0c<\/b><\/strong>\u4e5f\u5c31\u662f\u4ee5\u4f53\u7cfb\u4e2d\u7684\u7535\u4f4d\u3001\u7535\u6d41\u6216\u8005\u7535\u91cf\u4f5c\u4e3a\u4f53\u7cfb\u4e2d\u53d1\u751f\u5316\u5b66\u53cd\u5e94\u7684\u91cf\u5ea6\u8fdb\u884c\u6d4b\u5b9a\u7684\u65b9\u6cd5\u3002\u5305\u62ec\u7535\u6d41-\u7535\u4f4d\u66f2\u7ebf\u7684\u6d4b\u5b9a\uff1b\u7535\u6781\u5316\u5b66\u53cd\u5e94\u7684\u7535\u4f4d\u5206\u6790\uff0c\u7535\u6781\u5316\u5b66\u53cd\u5e94\u7684\u7535\u91cf\u5206\u6790\uff1b\u5bf9\u88ab\u6d4b\u5bf9\u8c61\u8fdb\u884c\u5fae\u91cf\u6d4b\u5b9a\u7684\u6781\u8c31\u5206\u6790\uff1b\u4ea4\u6d41\u963b\u6297\u6d4b\u8bd5\u7b49\u3002<\/p>\n

2.1 \u5e38\u7528\u7684\u7535\u5316\u5b66\u6d4b\u8bd5\u65b9\u6cd5\u6280\u672f<\/b><\/strong><\/p>\n

\u7535\u6d41\u5206\u6790\u6cd5(\u4e5f\u79f0\u4e3a\u8ba1\u65f6\u5b89\u57f9\u6cd5)\u3001\u5dee\u5206\u8109\u51b2\u5b89\u57f9\u6cd5(DPA)\u3001\u5dee\u5206\u8109\u51b2\u4f0f\u5b89\u6cd5(DPV)\u3001\u5faa\u73af\u4f0f\u5b89\u6cd5(CV)\u3001\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5(LSV)\u3001\u5e38\u89c4\u8109\u51b2\u4f0f\u5b89\u6cd5(NPV)\u3001\u65b9\u6ce2\u4f0f\u5b89\u6cd5(SWV)\u7b49\u3002<\/p>\n

2.2 \u7535\u5316\u5b66\u6d4b\u8bd5\u65b9\u6cd5\u7684\u4f18\u70b9<\/b><\/strong><\/p>\n

1) \u7b80\u5355\u6613\u884c\u3002<\/b><\/strong>\u53ef\u5c06\u4e00\u822c\u96be\u4ee5\u6d4b\u5b9a\u7684\u5316\u5b66\u53c2\u6570\u76f4\u63a5\u53d8\u6362\u6210\u5bb9\u6613\u6d4b\u5b9a\u7684\u7535\u53c2\u6570\u52a0\u4ee5\u6d4b\u5b9a\u3002<\/p>\n

2) \u7075\u654f\u5ea6\u9ad8\u3002<\/b><\/strong>\u56e0\u4e3a\u7535\u5316\u5b66\u53cd\u5e94\u662f\u6309\u6cd5\u62c9\u7b2c\u5b9a\u5f8b\u8fdb\u884c\u7684\uff0c\u6240\u4ee5\uff0c\u5373\u4f7f\u662f\u5fae\u91cf\u7684\u7269\u8d28\u53d8\u5316\u4e5f\u53ef\u4ee5\u901a\u8fc7\u5bb9\u6613\u6d4b\u5b9a\u5230\u7684\u7535\u6d41\u6216\u7535\u91cf\u6765\u8fdb\u884c\u6d4b\u5b9a\u3002<\/p>\n

3) \u5b9e\u65f6\u6027\u597d\u3002<\/b><\/strong>\u5229\u7528\u9ad8\u7cbe\u5ea6\u7684\u7279\u70b9\uff0c\u53ef\u4ee5\u68c0\u6d4b\u51fa\u5fae\u53cd\u5e94\u91cf\uff0c\u5e76\u5bf9\u5176\u8fdb\u884c\u5b9a\u91cf\u3002<\/p>\n

3 \u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u7684\u57fa\u672c\u539f\u7406\u53ca\u5176\u5e94\u7528<\/b><\/strong><\/p>\n

3.1 \u4ea4\u6d41\u963b\u6297\u7684\u539f\u7406\u53ca\u5e94\u7528<\/b><\/strong><\/p>\n

\u4ea4\u6d41\u963b\u6297\u65b9\u6cd5\u662f\u7528\u5c0f\u5e45\u5ea6\u4ea4\u6d41\u4fe1\u53f7\u6270\u52a8\u7535\u89e3\u6c60\uff0c\u5e76\u89c2\u5bdf\u4f53\u7cfb\u5728\u7a33\u6001\u65f6\u5bf9\u6270\u52a8\u7684\u8ddf\u968f\u7684\u60c5\u51b5\uff0c\u540c\u65f6\u6d4b\u91cf\u7535\u6781\u7684\u4ea4\u6d41\u963b\u6297\uff0c\u8fdb\u800c\u8ba1\u7b97\u7535\u6781\u7684\u7535\u5316\u5b66\u53c2\u6570\u3002\u4ece\u539f\u7406\u4e0a\u6765\u8bf4\uff0c\u963b\u6297\u6d4b\u91cf\u53ef\u5e94\u7528\u4e0e\u4efb\u4f55\u7269\u7406\u6750\u6599\uff0c\u4efb\u4f55\u4f53\u7cfb\uff0c\u53ea\u8981\u8be5\u4f53\u7cfb\u5177\u6709\u53cc\u7535\u6781\uff0c\u5e76\u5728\u8be5\u53cc\u7535\u6781\u4e0a\u5bf9\u4ea4\u6d41\u7535\u538b\u5177\u6709\u77ac\u65f6\u7684\u4ea4\u6d41\u7535\u6d41\u76f8\u5e94\u7279\u6027\u5373\u53ef\u3002<\/b><\/strong><\/p>\n

\u4ea4\u6d41\u963b\u6297\u8c31(EIS)\u5728\u91d1\u5c5e\u8868\u9762\u949d\u5316\u65b9\u9762\u7684\u5e94\u7528\uff1a<\/b><\/strong>\u8981\u786e\u5b9a\u67d0\u949d\u5316\u5de5\u827a\u4e2dFe2+<\/sup>\u6d53\u5ea6\u5bf9\u949d\u5316\u6548\u679c\u7684\u5f71\u54cd\uff0c\u53ef\u4ee5\u5728\u4e0d\u540c\u7684Fe2+<\/sup>\u6d53\u5ea6\u4e0b\u6d4b\u8bd5\u51fa\u4ea4\u6d41\u963b\u6297\u66f2\u7ebf\uff0c\u4ece\u4e2d\u7b5b\u9009\u51fa\u6700\u5408\u9002\u7684\u5de5\u51b5\u3002\u8868\u660e\u6d53\u5ea61\u6bd4\u6d53\u5ea62\u3001\u6d53\u5ea63\u7684\u6210\u819c\u5de5\u827a\u8981\u597d\uff0c\u56e0\u6b64\u53ef\u4ee5\u9009\u62e9\u6d53\u5ea61\u4f5c\u4e3a\u8be5\u53c2\u6570\u7684\u6700\u4f73\u6761\u4ef6\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u53cc\u6c27\u5316\u949d\u5316\u5de5\u827a\u4e2d\uff0c\u5728\u4e0d\u540cFe2+<\/sup>\u6d53\u5ea6\u4e0b\u7684\u4ea4\u6d41\u963b\u6297\u66f2\u7ebf<\/p>\n

3.2 \u5faa\u73af\u4f0f\u5b89\u6cd5\u539f\u7406<\/strong><\/p>\n

\u5faa\u73af\u4f0f\u5b89\u6cd5\u662f\u5728\u4e00\u5b9a\u7535\u4f4d\u4e0b\u6d4b\u91cf\u4f53\u7cfb\u7684\u7535\u6d41\uff0c\u5f97\u5230\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\u3002\u6839\u636e\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\u8fdb\u884c\u5b9a\u6027\u5b9a\u91cf\u5206\u6790\u3002\u5982\u679c\u65bd\u52a0\u7684\u7535\u4f4d\u4e3a\u7b49\u8170\u4e09\u89d2\u5f62\u7684\u5f62\u5f0f\u52a0\u5728\u5de5\u4f5c\u7535\u6781\u4e0a\uff0c\u5f97\u5230\u7684\u7535\u6d41\u7535\u538b\u66f2\u7ebf\u5305\u62ec\u4e24\u4e2a\u5206\u652f\uff0c\u5982\u679c\u524d\u534a\u90e8\u5206\u7535\u4f4d\u5411\u9634\u6781\u65b9\u5411\u626b\u63cf\uff0c\u4ea7\u751f\u8fd8\u539f\u6ce2\uff0c\u90a3\u4e48\u540e\u534a\u90e8\u5206\u7535\u4f4d\u5411\u9633\u6781\u65b9\u5411\u626b\u63cf\u65f6\uff0c\u4fbf\u4ea7\u751f\u6c27\u5316\u6ce2\uff0c\u8be5\u6cd5\u79f0\u4e3a\u5faa\u73af\u4f0f\u5b89\u6cd5\u3002\u5982\u679c\u7535\u6d3b\u6027\u7269\u8d28\u53ef\u9006\u6027\u5dee\uff0c\u5219\u6c27\u5316\u6ce2\u4e0e\u8fd8\u539f\u6ce2\u7684\u9ad8\u5ea6\u5c31\u4e0d\u540c\uff0c\u5bf9\u79f0\u6027\u4e5f\u8f83\u5dee\u3002<\/b><\/strong><\/p>\n

\u4ece\u56fe4\u4e2d\u53ef\u4ee5\u770b\u51fa\u6c27\u5316\u8fd8\u539f\u5cf0\u5f88\u5bf9\u79f0\uff0c\u9634\u6781\u5cf0\u7535\u6d41\u4e0e\u9633\u6781\u5cf0\u7535\u6d41\u8fd1\u4f3c\u76f8\u7b49\uff0c\u4e14\u968f\u7740\u626b\u63cf\u901f\u7387\u7684\u589e\u52a0\uff0c\u4e24\u5cf0\u5747\u6ca1\u53d1\u751f\u4f4d\u79fb\u53ea\u662f\u5cf0\u9ad8\u589e\u5927\u3002\u8fd9\u4e9b\u8bf4\u660e[IrC16 ] 2-<\/sup>\u4e0e[IrCl6 ]3-<\/sup>\u00a0\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5c5e\u4e8e\u53ef\u9006\u53cd\u5e94\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 0.5mol\/L [IrC16 ] 2-<\/sup>\u57281.0 mol\/L HCl\u6eb6\u6db2\u4e2d\u7684CV\u66f2\u7ebf<\/p>\n

\u5728\u7535\u8def\u8868\u9762\u9540\u5c42\u7684\u5e94\u7528\uff1a\"\"<\/b><\/strong><\/p>\n

\u7535\u5076\u7535\u6d41\u66f2\u7ebf\u4e0a\u7684\u7535\u5076\u7535\u6d41\u7684\u5927\u5c0f\u5b9e\u9645\u4e0a\u53cd\u6620\u7684\u662f\u77ac\u95f4\u7684\u7535\u8def\u677f\u8868\u9762\u6240\u9540\u7684\u91d1\u5c5e\u6c89\u79ef\u7684\u901f\u5ea6\uff0c\u4e5f\u5c31\u662f\u76f4\u63a5\u53cd\u6620\u53cd\u5e94\u7684\u901f\u5ea6\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 \u94dc-\u9521\u7535\u5076\u7535\u6d41\u968f\u65f6\u95f4\u53d8\u5316\u66f2\u7ebf<\/p>\n

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