{"id":102800,"date":"2017-09-22T06:30:06","date_gmt":"2017-09-21T22:30:06","guid":{"rendered":"\/\/m.iemloyee.com\/?p=102800"},"modified":"2017-09-20T20:58:09","modified_gmt":"2017-09-20T12:58:09","slug":"%e7%8e%8b%e8%bf%9e%e6%b4%b2%e6%95%99%e6%8e%88adv-energy-mater-%e8%b6%85%e8%96%84%e5%8d%95%e6%99%b6ta3n5%e7%ba%b3%e7%b1%b3%e7%bd%91%e5%8a%a9%e5%8a%9b%e5%85%89%e5%82%ac%e5%8c%96%e5%88%86%e8%a7%a3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=102800","title":{"rendered":"\u738b\u8fde\u6d32\u6559\u6388Adv. Energy Mater.:\u8d85\u8584\u5355\u6676Ta3N5\u7eb3\u7c73\u7f51\u52a9\u529b\u5149\u50ac\u5316\u5206\u89e3\u6c34\u5236\u6c22"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\n \"\"<\/p>\n

 <\/p>\n

\u56fe2. Ta3<\/sub>N5<\/sub>\u7eb3\u7c73\u7f51\u7684\u5f62\u8c8c\u53ca\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a-e) SEM\u3001TEM\u3001HRTEM\u56fe\u50cf\u3002<\/p>\n

(f) SAED\u56fe\u8c31\u3002<\/p>\n

(g-i) STEM\u548cEDX\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

(j) AFM\u56fe\u50cf\u548c\u9ad8\u5ea6\u8f6e\u5ed3\u56fe\u3002<\/p>\n

\u56fe3. Ta3<\/sub>N5<\/sub>\u7eb3\u7c73\u7f51\u7684\u6210\u5206\u53ca\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\n \"\"<\/p>\n

(a) N2<\/sub>\u5438\u9644\/\u8131\u9644\u66f2\u7ebf\u3002<\/p>\n

(b)\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

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\u56fe4. \u4e2d\u95f4\u4ea7\u7269\u7684\u8868\u5f81\u53ca\u56fa\u4f53\u6a21\u578b<\/strong><\/p>\n

\"\"<\/p>\n

(a,b) \u6c27\u5316\u77f3\u58a8\u70ef\/\u6c34\u5408\u6c22\u6c27\u5316\u94bd\u7684TEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n

(c,d)\u4e8c\u7ef4\u7247\u72b6TaOx<\/sub>\u7684TEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n

(e) \u7531\u65e0\u5b9a\u5f62Ta2<\/sub>O5<\/sub>\u8f6c\u5316\u4e3aTa3<\/sub>N5<\/sub>\u6676\u4f53\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u7070\u8272\u3001\u7ea2\u8272\u3001\u84dd\u8272\u5c0f\u70b9\u5206\u522b\u8868\u793aTa\u3001O\u3001N\u539f\u5b50\u3002<\/p>\n

\u56fe5. Ta3<\/sub>N5<\/sub>\u7eb3\u7c73\u7f51\u4e0e\u5757\u72b6Ta3<\/sub>N5<\/sub>\u7684\u6027\u80fd\u5bf9\u6bd4<\/strong><\/p>\n

\n \"\"<\/p>\n

(a) \u6a21\u62df\u592a\u9633\u5149\u8f90\u7167\u6761\u4ef6\u4e0b\uff08AM 1.5G\uff0c100 mW\/cm2<\/sup>\uff09\u7684\u5149\u89e3\u6c34\u5236\u6c22\u6d4b\u8bd5\u7ed3\u679c\uff0c\u5176\u4e2d\u7ea2\u8272\u66f2\u7ebf\u4e3a1 wt% Pt\u8d1f\u8f7d\u52300.02g Ta3<\/sub>N5<\/sub>\u7eb3\u7c73\u7f51\u4e0a\u7684\u6d4b\u8bd5\u7ed3\u679c\uff0c\u6d4b\u8bd5\u6eb6\u6db2\u4e3a\u4f53\u79ef\u5206\u6570\u4e3a10%\u7684\u7532\u9187\u6c34\u6eb6\u6db2\u3002<\/p>\n

(b) \u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002<\/p>\n

(c) \u65f6\u95f4\u5206\u8fa8\u8367\u5149\u8870\u51cf\u8c31\uff0c\u6fc0\u53d1\u5149\u6e90\u4e3a337 nm\u7684\u6fc0\u5149\uff0c\u6d4b\u8bd5\u6ce2\u957f\u4e3a586 nm\u3002<\/p>\n

(d) \u5c06\u50ac\u5316\u5242\u8d1f\u8f7d\u5230\u73bb\u78b3\u7535\u6781\u4e0a\u6d4b\u5f97\u7684\u4f0f\u5b89\u66f2\u7ebf\uff0c\u626b\u63cf\u65b9\u5411\u4e3a\u7531\u8d1f\u5230\u6b63\uff0c\u626b\u63cf\u901f\u5ea6\u4e3a10 mV\/s\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u4ee5\u4e8c\u7ef4\u7247\u72b6\u6c27\u5316\u77f3\u58a8\u70ef\u4f5c\u4e3a\u6a21\u677f\uff0c\u91c7\u7528\u727a\u7272\u6a21\u677f\u6cd5\u5236\u5907\u51fa\u6bd4\u8868\u9762\u79ef\u5927\u3001\u5b54\u53c2\u6570\u53ef\u63a7\u7684\u8d85\u8584\u5355\u6676Ta3<\/sub>N5<\/sub>\u7eb3\u7c73\u7f51\u3002\u8be5\u7eb3\u7c73\u7f51\u7ed3\u6784\u6709\u5229\u4e8e\u7535\u5b50\u4f20\u8f93\uff0c\u5e76\u80fd\u63d0\u9ad8\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u6548\u7387\uff0c\u5ef6\u957f\u5149\u751f\u8f7d\u6d41\u5b50\u5bff\u547d\uff0c\u4ece\u800c\u63d0\u9ad8Ta3<\/sub>N5<\/sub>\u7684\u5149\u89e3\u6c34\u5236\u6c22\u6d3b\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5236\u5907\u9ad8\u50ac\u5316\u6d3b\u6027\u7684\u4e8c\u7ef4\u8d85\u8584\u7eb3\u7c73\u7f51\u7ed3\u6784\u63d0\u4f9b\u4e86\u4e00\u4e2a\u666e\u9002\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Single-Crystalline Nanomesh Tantalum Nitride Photocatalyst with Improved Hydrogen-Evolving Performance <\/a>(Adv. Energy Mater., 2017, DOI:\u00a010.1002\/aenm.201701605)<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u738b\u8fde\u6d32\u6559\u6388\u56e2\u961f\u4e3b\u8981\u4ece\u4e8b\u7eb3\u7c73\u534a\u5bfc\u4f53\u6750\u6599\u7684\u8bbe\u8ba1\u3001\u5236\u5907\u53ca\u5176\u5728\u592a\u9633\u80fd\u8f6c\u5316\u548c\u50a8\u5b58\u65b9\u9762\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u8fd1\u671f\u5148\u540e\u901a\u8fc7\u5bf9\u65b0\u578b\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\u7684\u5f62\u8c8c\u3001\u6676\u9762\u53ca\u7535\u5b50\u7ed3\u6784\u7b49\u8c03\u63a7\u5de5\u7a0b\uff0c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u9ad8\u6027\u80fd\u7684\u5149\u50ac\u5316\u53ca\u5149\u7535\u50ac\u5316\u4ea7\u6c22\u7684\u6750\u6599\u4f53\u7cfb\u3002\u76f8\u5173\u94fe\u63a5\uff1a<\/p>\n

(1) Advanced Materials, 2016,\u00a0DOI:10.1002\/adma.201601525<\/p>\n

http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201601525\/full<\/a>\uff1b<\/p>\n

(2) Angew Chem, 2017, DOI:10.1002\/anie.201703491<\/p>\n

http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201703491\/full<\/a><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 \u738b\u948a\u9896 \u4f9b\u7a3f\u3002<\/p>\n

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\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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