{"id":102225,"date":"2017-09-21T06:30:10","date_gmt":"2017-09-20T22:30:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=102225"},"modified":"2017-09-17T17:28:47","modified_gmt":"2017-09-17T09:28:47","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6%e5%8c%96%e5%ad%a6%e5%8c%96%e5%b7%a5%e5%ad%a6%e9%99%a2%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%a2%b3%e9%be%99%e5%8c%96%e5%ad%a6%e7%9a%84%e5%8d%95%e5%88%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=102225","title":{"rendered":"\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\uff1a\u57fa\u4e8e\u201c\u78b3\u9f99\u5316\u5b66\u201d\u7684\u5355\u5206\u5b50\u7535\u5b50\u5b66\u7814\u7a76\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"
\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u6d2a\u6587\u6676\u6559\u6388\u8bfe\u9898\u7ec4\u548c\u590f\u6d77\u5e73\u6559\u6388\u8bfe\u9898\u7ec4\u5bc6\u5207\u5408\u4f5c\uff0c\u9996\u6b21\u5728\u5355\u5206\u5b50\u5c3a\u5ea6\u4e0a\u7814\u7a76\u4e86\u91d1\u5c5e\u6742\u82b3\u73af\u4f53\u7cfb\u7684\u7535\u8377\u8f93\u8fd0\u6027\u8d28\uff0c\u5e76\u4ee5\u6b64\u63d0\u51fa\u4e86\u57fa\u4e8e\u79bb\u57df\u6548\u5e94\u53d8\u5316\u7684\u7535\u8f93\u8fd0\u8c03\u63a7\u65b0\u65b9\u6cd5\uff0c\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cSwitching of Charge Transport Pathways via Delocalization Changes in Single-molecule Metallacycles Junctions\u201d\u4e3a\u9898\u5728\u7ebf\u53d1\u8868\u4e8eJ. Am. Chem. Soc.\u4e0a\u3002\u8be5\u5de5\u4f5c\u662f\u53a6\u95e8\u5927\u5b66\u539f\u521b\u7684\u201c\u78b3\u9f99\u5316\u5b66\uff08Carbolong Chemistry\uff09\u201d\u5728\u6027\u80fd\u7814\u7a76\u65b9\u9762\u7684\u91cd\u8981\u8fdb\u5c55\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong>1 MCBJ<\/strong>\u88c5\u7f6e\u793a\u610f\u56fe<\/strong><\/p>\n \u56fe<\/strong>2 <\/strong>\u590d\u5408\u7269<\/strong>2<\/strong>\u3001<\/strong>3<\/strong>\u3001<\/strong>4<\/strong>\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n \u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n \u82b3\u9999\u65cf\u9aa8\u67b6\u662f\u5206\u5b50\u7535\u5b50\u5b66\u7814\u7a76\u7684\u91cd\u8981\u7ed3\u6784\u57fa\u5143\uff0c\u91d1\u5c5e\u82b3\u9999\u4f53\u56e0\u5d4c\u5165\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u800c\u5177\u6709\u72ec\u7279\u7684\u7535\u5b66\u6027\u8d28\uff0c\u9884\u793a\u5176\u5728\u7535\u5b50\u5b66\u9886\u57df\u5177\u6709\u6f5c\u5728\u7684\u91cd\u8981\u5e94\u7528\u3002\u672c\u6b21\u7814\u7a76\u7ed3\u5408\u590f\u6d77\u5e73\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u78b3\u9f99\u5316\u5b66\u9886\u57df\u7684\u7814\u7a76\u57fa\u7840\u548c\u6d2a\u6587\u6676\u6559\u6388\u8bfe\u9898\u7ec4\u53d1\u5c55\u7684\u9ad8\u7075\u654f\u5ea6\u5355\u5206\u5b50\u7535\u8f93\u8fd0\u8868\u5f81\u6280\u672f\uff0c\u9996\u5148\u5408\u6210\u4e86\u4e09\u4e2a\u4ee5\u8fc7\u6e21\u91d1\u5c5e\u9507\u4e3a\u6865\u5934\u7684\u91d1\u5c5e\u6742\u82b3\u9999\u5316\u5408\u7269\uff0c\u5355\u5206\u5b50\u7535\u5b66\u7814\u7a76\u53d1\u73b0\u8fde\u63a5\u5728\u91d1\u5c5e\u6742\u82b3\u9999\u73af\u4e0a\u7684\u5b63\u78f7\uff08phosphonium\uff09\u53d6\u4ee3\u57fa\u6240\u5e26\u6765\u7684\u79bb\u57df\u6548\u5e94\u53d8\u5316\u53ef\u4ee5\u663e\u8457\u589e\u5f3a\u91d1\u5c5e\u6742\u82b3\u9999\u5316\u5408\u7269\u7684\u7535\u8f93\u8fd0\u6027\u8d28\uff0c\u4ece\u800c\u4f7f\u57fa\u4e8e\u91d1\u5c5e\u6742\u82b3\u9999\u9aa8\u67b6\u7684\u5355\u5206\u5b50\u5668\u4ef6\u7535\u5bfc\u63d0\u5347\u8d85\u8fc7\u4e00\u4e2a\u6570\u91cf\u7ea7\u3002\u8fd9\u4e00\u7814\u7a76\u5de5\u4f5c\u8bc1\u660e\u91d1\u5c5e\u6742\u82b3\u9999\u9aa8\u67b6\u6709\u671b\u6210\u4e3a\u672a\u6765\u5206\u5b50\u7535\u5b50\u5b66\u4e2d\u5177\u6709\u91cd\u8981\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u7684\u7ed3\u6784\u57fa\u5143\uff0c\u8be5\u4f53\u7cfb\u7535\u5b50\u79bb\u57df\u6548\u5e94\u7684\u8c03\u63a7\u53ef\u4e3a\u5c06\u6765\u5206\u5b50\u5668\u4ef6\u548c\u5206\u5b50\u6750\u6599\u7684\u5236\u5907\u63d0\u4f9b\u4e00\u79cd\u5168\u65b0\u7684\u8bbe\u8ba1\u601d\u8def\u3002<\/p>\n \u8be5\u7814\u7a76\u5de5\u4f5c\u662f\u5728\u590f\u6d77\u5e73\u6559\u6388\u3001\u6d2a\u6587\u6676\u6559\u6388\u7684\u5171\u540c\u6307\u5bfc\u4e0b\u5408\u4f5c\u5b8c\u6210\u7684\uff0c\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5316\u5de5\u7cfb\u7855\u58eb\u7814\u7a76\u751f\u674e\u745e\u8c6a\u548c\u5316\u5b66\u7cfb\u535a\u58eb\u7814\u7a76\u751f\u8def\u6b63\u5b87\u4f5c\u4e3a\u672c\u8bba\u6587\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u7814\u7a76\u751f\u8521\u6c85\u5ef7\u3001\u848b\u67ab\u3001\u9648\u5fd7\u6615\u3001\u5510\u6df3\u3001\u90d1\u73cf\u5a77\u3001\u76ae\u4e5d\u7985\u3001\u5f20\u854a\u7b49\u5171\u540c\u5b8c\u6210\uff0c\u5e08\u4f73\u526f\u6559\u6388\u3001\u9648\u62db\u658c\u9ad8\u7ea7\u5de5\u7a0b\u5e08\u3001\u6768\u626c\u52a9\u7406\u6559\u6388\u548c\u5218\u4fca\u626c\u535a\u58eb\u4e5f\u53c2\u4e0e\u4e86\u90e8\u5206\u7814\u7a76\u5de5\u4f5c\uff0c\u8fd9\u4e00\u4ea4\u53c9\u7814\u7a76\u5145\u5206\u4f53\u73b0\u4e86\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5316\u5b66\u3001\u5316\u5de5\u5b66\u79d1\u878d\u5408\u521b\u65b0\u7684\u7814\u7a76\u7279\u8272\u3002<\/p>\n \u8fd9\u4e00\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\uff082017YFA0204902\uff09\u3001\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\uff0821673195\uff0c21503179\uff0c21490573\uff09\u3001\u5343\u4eba\u8ba1\u5212\u9752\u5e74\u9879\u76ee\u3001\u56fa\u4f53\u8868\u9762\u7269\u7406\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u3001\u80fd\u6e90\u6750\u6599\u5316\u5b66\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\uff082011-iChEM\uff09\u4ee5\u53ca\u77f3\u58a8\u70ef\u5de5\u7a0b\u4e0e\u4ea7\u4e1a\u7814\u7a76\u9662\u7684\u652f\u6301\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttp:\/\/chem.xmu.edu.cn\/show.asp?id=2269<\/a>\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aSwitching of Charge Transport Pathways via Delocalization Changes in Single-molecule Metallacycles Junctions<\/a>\uff08J. Am. Chem. Soc.\uff0c2017\uff0cDOI\uff1a 10.1021\/jacs.7b06400\uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u738b\u51b0\u7f16\u8f91\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n
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