{"id":102152,"date":"2017-09-20T06:30:28","date_gmt":"2017-09-19T22:30:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=102152"},"modified":"2017-09-20T10:59:10","modified_gmt":"2017-09-20T02:59:10","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e5%85%b0%e5%b7%9e%e5%8c%96%e7%89%a9%e6%89%80%e8%8b%8f%e6%af%85%e8%bf%9b%e5%9b%a2%e9%98%9f%ef%bc%9a%e5%8f%af%e8%a7%81%e5%85%89%e4%bf%83%e8%bf%9b%e7%be%b0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=102152","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u7269\u6240\u82cf\u6bc5\u8fdb\u56e2\u961f\uff1a\u53ef\u89c1\u5149\u4fc3\u8fdb\u7fb0\u57fa\u5408\u6210\u7814\u7a76\u53d6\u5f97\u8fdb\u5c55"},"content":{"rendered":"

\u3010<\/b><\/strong>\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u7fb0\u57fa\u5408\u6210\u5316\u5b66\u662f\u628a\u77f3\u6cb9\u5316\u5de5\u57fa\u7840\u5206\u5b50\u8f6c\u5316\u6210\u5927\u5b97\u5316\u5b66\u54c1\u7684\u652f\u67f1\u6027\u6280\u672f\uff0c\u662f\u8d44\u6e90\u3001\u80fd\u6e90\u548c\u73af\u5883\u9886\u57df\u7684\u91cd\u8981\u7814\u7a76\u8bfe\u9898\u3002\u4ee5\u7eff\u8272\u5408\u6210\u4e0e\u6e05\u6d01\u8f6c\u5316\u4e3a\u5bfc\u5411\uff0c\u53d1\u5c55\u542b\u7fb0\u57fa\u5316\u5408\u7269\u9ad8\u503c\u5316\u8f6c\u5316\u7684\u65b0\u4f53\u7cfb\u662f\u5b9e\u73b0\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u9700\u8981\u3002<\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7fb0\u57fa\u5408\u6210\u4e0e\u9009\u62e9\u6c27\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u82cf\u6bc5\u8fdb\u56e2\u961f\u5e0c\u671b\u901a\u8fc7\u5206\u5b50\u5185\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u4ea7\u751f\u6d3b\u6027\u6709\u673a\u53cc\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\uff0c\u7528\u4e8e\u4ecb\u5bfc\u65b0\u578b\u7fb0\u57fa\u5408\u6210\u53cd\u5e94\u3002\u7814\u7a76\u56e2\u961f\u4f7f\u7528N-\u82b3\u57fa\u7532\u9170\u7532\u57fa\u6eb4\u5316\u5421\u5576\u5b63\u94f5\u76d0\u4f5c\u4e3a\u76ee\u6807\u542b\u7fb0\u57fa\u5316\u5408\u7269\uff0c\u901a\u8fc7\u7ed3\u5408\u53bb\u8d28\u5b50\u548c\u5206\u5b50\u5185\u7535\u5b50\u8f6c\u79fb\u4e24\u79cd\u7fb0\u57fa\u6d3b\u5316\u6a21\u5f0f\uff0c\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0c\u9ad8\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u5730\u4e3a\u57fa\u7840\u5316\u5b66\u5206\u5b50\u2014\u2014\u7f3a\u7535\u5b50\u70ef\u70c3\u63d0\u4f9b\u82b3\u57fa\u4e59\u916e\u57fa\u548c2-\u5421\u5576\u57fa\u4fee\u9970\u3002\u521d\u6b65\u7684\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u539f\u4f4d\u751f\u6210\u53ef\u89c1\u5149\u654f\u7684Donor-Acceptor\u00a0Molecule\uff08\u4ee5\u5149\u654f\u76841,2-\u4e8c\u6c22\u5421\u5576\u4f5c\u4e3aDonor\uff0c\u7fb0\u57fa\u4f5c\u4e3aAcceptor\uff09\u662f\u53cd\u5e94\u5f97\u4ee5\u5b9e\u73b0\u7684\u5173\u952e\u6b65\u9aa4\u3002\u7814\u7a76\u7ed3\u679c\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201cVisible-Light-Induced Carbo-2-pyridylation of Electron-Deficient Alkenes with Pyridinium Salts\u201d\u53d1\u8868\u5728Angewandte Chemie International Edition\u4e0a\u3002<\/p>\n

\u3010<\/b><\/strong>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1 \u4f20\u7edf\u7684\u7fb0\u57fa\u6d3b\u5316\u6a21\u5f0f<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe2 \u53ef\u89c1\u5149\u4fc3\u8fdb\u7684\u7f3a\u7535\u5b50\u70ef\u70c3\u53cc\u78b3\u57fa\u5316\u53cd\u5e94<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n

\u5efa\u7acb\u542b\u7fb0\u57fa\u5316\u5408\u7269\u7684\u65b0\u578b\u8f6c\u5316\u53cd\u5e94\u7684\u5173\u952e\u662f\u57fa\u4e8e\u73b0\u4ee3\u5408\u6210\u5316\u5b66\u548c\u50ac\u5316\u5316\u5b66\u7684\u6982\u5ff5\uff0c\u8bbe\u8ba1\u51fa\u65b0\u578b\u7fb0\u57fa\u6d3b\u5316\u6a21\u5f0f\u3002\u56fe1\u5c55\u793a\u4e86\u5e38\u89c1\u7684\u7fb0\u57fa\u6d3b\u5316\u6a21\u5f0f\uff1a\uff081\uff09\u4e0e\u8d28\u5b50\u548c\u91d1\u5c5e\u9633\u79bb\u5b50\u7ed3\u5408\uff0c\u5f97\u5230\u78b3\u6b63\u79bb\u5b50\u6d3b\u6027\u4e2d\u95f4\u4f53\uff1b\uff082\uff09\u7ecf\u4eb2\u6838\u52a0\u6210\uff0c\u5f97\u5230\u6c27\u8d1f\u79bb\u5b50\u6d3b\u6027\u4e2d\u95f4\u4f53\uff1b\uff083\uff09\u7ecf\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u5f97\u5230\u78b3\u81ea\u7531\u57fa\u6d3b\u6027\u4e2d\u95f4\u4f53\uff1b\uff084\uff09\u7ecf\u53bb\u8d28\u5b50\u5316\uff0c\u5f97\u5230\u03b1-\u78b3\u8d1f\u79bb\u5b50\u6d3b\u6027\u4e2d\u95f4\u4f53\uff1b\uff085\uff09\u7ecf\u6c22\u539f\u5b50\u652b\u53d6\uff0c\u5f97\u5230\u03b1-\u78b3\u81ea\u7531\u57fa\u6d3b\u6027\u4e2d\u95f4\u4f53\uff1b\uff086\uff09\u6709\u522b\u4e8e\u4e0a\u8ff0\u4e94\u79cd\u4f20\u7edf\u7684\u7fb0\u57fa\u6d3b\u5316\u6a21\u5f0f\u3002\u5bf9\u4e0a\u8ff0\u591a\u79cd\u7fb0\u57fa\u6d3b\u5316\u6a21\u5f0f\u8fdb\u884c\u4e32\u8054\u7ed3\u5408\uff0c\u53ef\u5b9e\u73b0\u4e00\u7cfb\u5217\u7684\u6210\u952e\u548c\u65ad\u952e\u8fc7\u7a0b\uff0c\u7b80\u6d01\u5408\u6210\u51fa\u7ed3\u6784\u76f8\u5bf9\u590d\u6742\u7684\u6709\u673a\u529f\u80fd\u5206\u5b50\u3002<\/p>\n

\u4e0a\u8ff0\u65b0\u578b\u7fb0\u57fa\u5408\u6210\u53cd\u5e94\u4e3a\u65e0\u91d1\u5c5e\u53c2\u4e0e\u7684\u9ad8\u6548\u5408\u6210\u6280\u672f\u63d0\u4f9b\u4e86\u65b0\u624b\u6bb5\uff0c\u7528\u4e8e\u836f\u7269\u5206\u5b50\u7814\u53d1\u8fc7\u7a0b\u53ef\u907f\u514d\u91cd\u91d1\u5c5e\u6c61\u67d3\u95ee\u9898\u3002\u8be5\u53cd\u5e94\u9002\u7528\u4e8e\u7edd\u5927\u90e8\u5206\u7684\u7f3a\u7535\u5b50\u70ef\u70c3\u548cN-\u82b3\u57fa\u7532\u9170\u7532\u57fa\u6eb4\u5316\u5421\u5576\u5b63\u94f5\u76d0\uff0c\u53ef\u7528\u4e8e\u836f\u7269\u5206\u5b50\u7684\u591a\u6837\u5316\u884d\u751f\uff0c\u4e3a\u836f\u7269\u7814\u53d1\u7684\u9ad8\u901a\u91cf\u7b5b\u9009\u73af\u8282\u63d0\u4f9b\u7269\u8d28\u57fa\u7840\uff0c\u4f8b\u5982\u8be5\u53cd\u5e94\u53ef\u7528\u4e8e\u836f\u7269\u5206\u5b50Bisacodyl\u548c\u753e\u4f53\u7c7b\u836f\u7269\u5206\u5b50\u4e2d\u95f4\u4f5316-DPA\u7684\u540e\u671f\u9ad8\u6548\u7fb0\u57fa\u5316\u4fee\u9970\uff08\u56fe2\uff09\u3002<\/p>\n

\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u79d1\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\u3001\u5170\u5dde\u5316\u7269\u6240\u4eba\u624d\u9879\u76ee\u548c\u7fb0\u57fa\u5408\u6210\u4e0e\u9009\u62e9\u6c27\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7684\u652f\u6301\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1ahttp:\/\/www.cas.cn\/syky\/201709\/t20170912_4614204.shtml<\/a><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aVisible-Light-Induced Carbo-2-pyridylation of Electron-Deficient Alkenes with Pyridinium Salts <\/a>(Angew. Chem. Int. Ed., 2017, DOI:10.1002\/anie.201704385)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u7fb0\u57fa\u5408\u6210\u5316\u5b66\u662f\u628a\u77f3\u6cb9\u5316\u5de5\u57fa\u7840\u5206\u5b50\u8f6c\u5316\u6210\u5927\u5b97\u5316\u5b66\u54c1\u7684\u652f\u67f1\u6027\u6280\u672f\uff0c\u662f\u8d44\u6e90\u3001\u80fd\u6e90\u548c\u73af\u5883\u9886\u57df\u7684\u91cd\u8981\u7814\u7a76\u8bfe\u9898\u3002\u4ee5\u7eff\u8272\u5408\u6210\u4e0e\u6e05\u6d01\u8f6c\u5316\u4e3a\u5bfc\u5411\uff0c\u53d1\u5c55\u542b\u7fb0\u57fa\u5316\u5408\u7269\u9ad8…<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-102152","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/102152"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=102152"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/102152\/revisions"}],"predecessor-version":[{"id":102562,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/102152\/revisions\/102562"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=102152"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=102152"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=102152"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}