{"id":100444,"date":"2017-09-08T14:00:55","date_gmt":"2017-09-08T06:00:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=100444"},"modified":"2017-09-07T22:46:05","modified_gmt":"2017-09-07T14:46:05","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6science-advances%ef%bc%9a%e8%b6%85%e7%bb%86pt-mo-ni%e7%ba%b3%e7%b1%b3%e7%ba%bf%e5%82%ac%e5%8c%96%e5%89%82%e7%94%a8%e4%ba%8e%e4%b9%99%e9%86%87%e7%94%b5%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=100444","title":{"rendered":"\u6e05\u534e\u5927\u5b66Science Advances\uff1a\u8d85\u7ec6Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u50ac\u5316\u5242\u7528\u4e8e\u4e59\u9187\u7535\u6c27\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u8fc7\u53bb\u51e0\u5341\u5e74\uff0c\u7814\u7a76\u4eba\u5458\u6781\u5927\u7684\u5173\u6ce8\u7740\u9ad8\u6027\u80fd\u71c3\u6599\u7535\u6c60\u3002\u5728\u4f17\u591a\u71c3\u6599\u7535\u6c60\u4e2d\uff0c\u4e59\u9187\u71c3\u6599\u7535\u6c60\uff08DEFCs\uff09\u7531\u4e8e\u5176\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u8f6c\u6362\u6548\u7387\u3001\u8f7b\u4fbf\u4ee5\u53ca\u76f8\u5bf9\u8f83\u4f4e\u7684\u5de5\u4f5c\u6e29\u5ea6\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c \u9633\u6781\u6c27\u5316\u7684\u8fdf\u6ede\u4ee5\u53ca\u6613\u53d7CO\u6bd2\u5316\u7b49\u539f\u56e0\u9650\u5236\u5b83\u5728\u5b9e\u9645\u71c3\u6599\u7535\u6c60\u5e94\u7528\u7684\u53d1\u5c55\u3002Pt\u662f\u4e00\u79cd\u6700\u5e38\u7528\u7684\u7535\u50ac\u5316\u5242\u3002\u4e3a\u4e86\u63d0\u9ad8\u71c3\u6599\u7535\u6c60\u7684\u5927\u89c4\u6a21\u5546\u4e1a\u5316\u8fdb\u7a0b\uff0c\u7814\u7a76\u4eba\u5458\u81f4\u529b\u4e8e\u63d0\u9ad8Pt-\u57fa\u6750\u6599\u6765\u5b9e\u73b0\u4f4e\u6210\u672c\u9ad8\u6548\u3001\u9ad8\u6d3b\u6027\u4ee5\u53ca\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u5242\u3002\u4ecePt\u539f\u5b50\u6548\u7387\u89d2\u5ea6\u51fa\u53d1\uff0c\u964d\u4f4e\u7535\u50ac\u5316\u5242\u6210\u672c\u7684\u4e00\u4e2a\u6709\u6548\u7684\u65b9\u6cd5\u662f\u5236\u5907\u5177\u6709\u5185\u90e8\u5404\u5411\u5f02\u6027\u5f62\u8c8c\u4ee5\u53ca\u5e26\u6709\u5927\u91cf\u8868\u9762\u539f\u5b50\u7684\u4e00\u7ef4\u8d85\u7ec6\u7eb3\u7c73\u7ebf\uff0c\u8fdb\u800c\u63d0\u9ad8Pt\u7684\u5229\u7528\u6548\u7387\u3002\u4ece\u50ac\u5316\u5242\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u89d2\u5ea6\u6765\u8bf4\uff0c\u63d2\u5165\u7b2c\u4e8c\u79cd\u91d1\u5c5e\u5230Pt\u7684\u6676\u683c\u4e2d\u6765\u5f62\u6210\u53cc\u91d1\u5c5e\u7eb3\u7c73\u6676\u662f\u4e00\u79cd\u6709\u6548\u7684\u9014\u5f84\u6765\u4fee\u9970Pt\u7684\u7535\u5b50\u7ed3\u6784\u5e76\u4e14\u56e0\u6b64\u8c03\u8282\u7535\u50ac\u5316\u5242\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u5230\u76ee\u524d\uff0cPt-\u57fa\u7eb3\u7c73\u7ebf\u7535\u50ac\u5316\u5242\u5df2\u7ecf\u80fd\u591f\u901a\u8fc7\u591a\u79cd\u65b9\u6cd5\u5236\u5907\u3002\u7136\u800c\uff0c\u8d85\u9ad8\u7eb5\u6a2a\u6bd4\u7684\u591a\u91d1\u5c5ePt-\u57fa\u8d85\u7ec6\u7eb3\u7c73\u7ebf\u96be\u4e8e\u5408\u6210\u800c\u4e14\u7a33\u5b9a\u6027\u4e0d\u4f73\u3002\u8fd9\u662f\u56e0\u4e3a\u4e00\u65b9\u9762\uff0cPt\u539f\u5b50\u5728\u6676\u4f53\u751f\u957f\u8fc7\u7a0b\u4e2d\u503e\u5411\u4e8e\u5f62\u6210\u9762\u5fc3\u7acb\u65b9\u5bc6\u5806\u79ef\u6676\u4f53\u7ed3\u6784\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7531\u4e8e\u4e0d\u540c\u7684\u8fd8\u539f\u7535\u4f4d\uff0c\u540c\u65f6\u63a7\u5236\u591a\u91d1\u5c5e\u524d\u9a71\u4f53\u8fd8\u539f\u548c\u6210\u6838\u8fc7\u7a0b\u4ecd\u7136\u975e\u5e38\u56f0\u96be\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u6e05\u534e\u5927\u5b66\u7684\u738b\u5b9a\u80dc\u6559\u6388\u548c\u674e\u4e9a\u680b\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Science Advances<\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cDesign of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation\u201d<\/strong>\u3002\u5728\u71c3\u6599\u7535\u6c60\u5546\u4e1a\u5316\u7684\u9053\u8def\u4e0a\uff0c\u53d1\u5c55\u4f4e\u6210\u672c\u9ad8\u6548\u3001\u9ad8\u6d3b\u6027\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u5242\u662f\u4e00\u9879\u975e\u5e38\u91cd\u8981\u7684\u8bfe\u9898\u3002\u76f4\u5f84~2.5nm\uff0c\u957f\u51e0\u5fae\u7c73\u7684\u8d85\u7ec6Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u901a\u8fc7H2<\/sub>\u8f85\u52a9\u7684\u65b9\u5f0f\uff08HASR\uff09\u5f97\u5230\u6210\u529f\u5236\u5907\u3002\u8fd9\u79cd\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u57fa\u4e8e\u4ee5\u4e0b\u4e09\u70b9\uff1a<\/p>\n

(i)\u5e26\u6709\u5927\u6279\u8868\u9762\u539f\u5b50\u7684\u8d85\u7ec6\u7eb3\u7c73\u7ebf\u80fd\u591f\u63d0\u9ad8Pt\u539f\u5b50\u6548\u7387\u5e76\u4e14\u56e0\u6b64\u964d\u4f4e\u50ac\u5316\u6210\u672c\u3002<\/p>\n

(ii)Ni\u7684\u63d2\u5165\u80fd\u591f\u9694\u79bb\u8868\u9762\u7684Pt\u539f\u5b50\u5e76\u4e14\u4ea7\u751f\u8868\u9762\u7f3a\u9677\uff0c\u9020\u6210\u9ad8\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

(iii)Mo\u7684\u63d2\u5165\u80fd\u591f\u7a33\u5b9aNi\u548cPt\u539f\u5b50\uff0c\u9020\u6210\u9ad8\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u3002<\/p>\n

\u8fdb\u4e00\u6b65\uff0c\u5148\u8fdb\u7684HASR\u6cd5\u540c\u6837\u80fd\u591f\u5e94\u7528\u5728\u4e00\u7cfb\u5217Pt-Mo-M (M= Fe, Co,Mn, Ru, \u7b49.)\u7eb3\u7c73\u7ebf\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\u8fd9\u9879\u5de5\u4f5c\u5c06\u4f1a\u5bf9\u8bbe\u8ba1\u548c\u5408\u6210\u4f4e\u6210\u672c\uff0c\u9ad8\u6548\uff0c\u9ad8\u6d3b\u6027\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u65b0\u7684\u89d2\u5ea6\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u7684\u7ed3\u6784\u8868\u5f81<\/p>\n

\"\"<\/p>\n

(A)\u4f4e\u500d\u7387TEM\u56fe\uff1b<\/p>\n

(B)\u9ad8\u500d\u7387TEM\u56fe\uff1b<\/p>\n

(C) HAADF-STEM\u56fe\uff1b\u63d2\u56fe\uff1a\u653e\u5927\u56fe\uff1b<\/p>\n

(D) Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u539f\u5b50\u7ea7\u5206\u8fa8\u7387\u8272\u5dee\u6821\u6b63HAADF-STEM\u56fe\uff1b\u63d2\u56fe\uff1aFFT\u56fe\u6848\uff1b<\/p>\n

(E) Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u76843D HAADF-STEM\u5f3a\u5ea6\u5256\u9762\uff1b<\/p>\n

(F) Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u7684EDX\u56fe\uff1b<\/p>\n

\u56fe2. Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u7684\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

(A) Pt L3<\/sub>– edge\u7684XANES\u5206\u6790\uff1b<\/p>\n

(B) Pt L3<\/sub>– edge\u7684EXAFS\u5206\u6790\uff1b<\/p>\n

(C) Ni K- edge\u7684XANES\u5206\u6790\uff1b<\/p>\n

(D) Ni K- edge\u7684EXAFS\u5206\u6790\uff1b<\/p>\n

(E) Mo K-edge\u7684XANES\u5206\u6790\uff1b<\/p>\n

(F) Mo K-edge\u7684EXAFS\u5206\u6790\uff1b<\/p>\n

\u56fe3. Pt-Mo-Ni\u7eb3\u7c73\u7ebf\uff0c\u94c2\u9ed1\u4ee5\u53ca\u94c2\u78b3\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u7279\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(A)\u94c2\u9ed1\u548c\u94c2\u78b3\u50ac\u5316\u5242\u4ee5\u53caPt-Mo-N\u7eb3\u7c73\u7ebf\u57280.5M H2<\/sub>SO4<\/sub>+2M CH3<\/sub>CH2<\/sub>OH \u6eb6\u6db2\u4e2d\u626b\u901f50mV s\u2212<\/sup>1<\/sup>\u4e0b\u7684\u6bd4\u6d3b\u6027\uff1b<\/p>\n

(B)\u6240\u6709\u50ac\u5316\u5242\u6bd4\u6d3b\u6027\u548c\u8d28\u91cf\u6d3b\u6027\u7684\u56fe\u8868\u6bd4\u8f83\uff1b<\/p>\n

(C)\u4e09\u79cd\u50ac\u5316\u5242\u7684CA\u7ed3\u679c\u3002Pt-Mo-Ni\u6837\u54c1\u5728\u4e0d\u540c\u7535\u538b\u4e0b\u7684FT-EXAFS\u66f2\u7ebf\uff1a(D) Pt L3<\/sub>-edge\uff1b (E) Ni K-edge\uff1b(F) Mo K-edge\uff1b<\/p>\n

\u56fe 4.\u57fa\u4e8eHASR\u6cd5\u5236\u5907\u8d85\u8584\u4e09\u5143Pt-Mo-M (M = Fe, Co, Mn, Ru, \u7b49)\u7eb3\u7c73\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(A) Pt-Mo-Fe\u7eb3\u7c73\u7ebfHAADF-STEM\u56fe\uff1b<\/p>\n

(B) Pt-Mo-Fe\u7eb3\u7c73\u7ebfEDX\u56fe\uff1b<\/p>\n

(C) Pt-Mo-Co\u7eb3\u7c73\u7ebf\u7684HAADF-STEM\u56fe\uff1b<\/p>\n

(D) Pt-Mo-Co\u7eb3\u7c73\u7ebf\u7684EDX\u56fe\uff1b<\/p>\n

(E) Pt-Mo-Mn\u7eb3\u7c73\u7ebf\u7684HAADF-STEM\u56fe\uff1b<\/p>\n

(F) Pt-Mo-Mn\u7eb3\u7c73\u7ebf\u7684EDX\u56fe\uff1b<\/p>\n

(G)\u7eb3\u7c73\u7ebf\u7684HAADF-STEM\u56fe\uff1b<\/p>\n

(H) Pt-Mo-Ru\u7eb3\u7c73\u7ebf\u7684EDX\u56fe\uff1b<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u6210\u529f\u7684\u91c7\u7528HASR\u6280\u672f\u5236\u5907\u4e86\u8d85\u7ec6 Pt-Mo-Ni\u4e09\u91d1\u5c5e\u7eb3\u7c73\u7ebf\u5e76\u4e14\u5df2\u7ecf\u8bc1\u660eH2<\/sub>\u80fd\u591f\u5f88\u597d\u7684\u63a7\u5236\u5236\u5907\u8d85\u7ec6\u4e09\u5143\u91d1\u5c5e\u7eb3\u7c73\u7ebf\u3002 \u7ed3\u5408\u7403\u5dee\u7535\u955c\u548cXAFS\u6d4b\u8bd5\u8bc1\u5b9e\u4e86\u8d85\u7ec6\u7eb3\u7c73\u7ebf\u7684\u7cbe\u7ec6\u7ed3\u6784\u3002Ni\u53ef\u4ee5\u5728\u8868\u9762\u9694\u79bbPt\u539f\u5b50\u5e76\u4e14\u4ea7\u751f\u8868\u9762\u7f3a\u9677\uff0c\u800cMo\u53ef\u4ee5\u7a33\u5b9a\u8fd9\u4e9b\u6d3b\u6027\u4f4d\u70b9\u3002\u56e0\u6b64\uff0c\u8d85\u7ec6Pt-Mo-Ni\u7eb3\u7c73\u7ebf\u5c55\u73b0\u4e86\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u5927\u5e45\u5ea6\u63d0\u9ad8\u7684\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u5148\u8fdb\u7684HASR\u6cd5\u540c\u6837\u80fd\u591f\u5e94\u7528\u5728\u4e00\u7cfb\u5217Pt-Mo-M (M= Fe, Co,Mn, Ru, \u7b49.)\u7eb3\u7c73\u7ebf\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\u8fd9\u9879\u5de5\u4f5c\u5c06\u4f1a\u5bf9\u8bbe\u8ba1\u548c\u5408\u6210\u4f4e\u6210\u672c\uff0c\u9ad8\u6548\uff0c\u9ad8\u6d3b\u6027\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u65b0\u7684\u89d2\u5ea6\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation <\/a>(Science Advances, 2017, DOI:\u00a010.1126\/sciadv.1603068)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u524d\u7ebfZ. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n

 <\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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