{"id":100408,"date":"2017-09-12T06:30:45","date_gmt":"2017-09-11T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=100408"},"modified":"2017-09-11T20:52:06","modified_gmt":"2017-09-11T12:52:06","slug":"energy-environ-sci-%e4%bc%a0%e7%bb%9f%e9%ab%98%e5%88%86%e5%ad%90%e8%be%85%e5%8a%a9%e6%96%b9%e6%b3%95%e5%88%b6%e5%a4%87%e9%ab%98%e6%95%88%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e5%a4%8d%e5%90%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=100408","title":{"rendered":"Energy Environ. Sci.:\u4f20\u7edf\u9ad8\u5206\u5b50\u8f85\u52a9\u65b9\u6cd5\u5236\u5907\u9ad8\u6548\u78b3\u7eb3\u7c73\u7ba1\u590d\u5408\u975e\u91d1\u5c5e\u57faOER\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

OER\u5bf9\u4e8e\u8bb8\u591a\u53ef\u518d\u751f\u80fd\u6e90\u7cfb\u7edf\u662f\u4e00\u4e2a\u5173\u952e\u7684\u8fc7\u7a0b\u3002\u7136\u800c\uff0cOER\u7ecf\u5e38\u56e0\u4e3a\u9633\u6781\u4e0a\u8fdf\u6ede\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u800c\u5728\u5e94\u7528\u9886\u57df\u6401\u6d45\u3002\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u9700\u8981\u964d\u4f4e\u9633\u6781\u6c27\u5316\u53cd\u5e94\u7684\u8fc7\u7535\u4f4d\u3002\u4f20\u7edfOER\u7535\u50ac\u5316\u5242\u662f\u57fa\u4e8e\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\u7684\uff0c\u4f8b\u5982IrO2<\/sub>\u548cRuO2<\/sub>\u3002\u4f46\u662f\u4ed6\u4eec\u7684\u4e0d\u8db3\u4ee5\u53ca\u6602\u8d35\u7684\u6210\u672c\u9650\u5236\u4e86\u81ea\u8eab\u5728\u53ef\u518d\u751f\u80fd\u6e90\u6280\u672f\u9886\u57df\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u81f4\u529b\u4e8e\u53d1\u5c55\u4f4e\u6210\u672c\u9ad8\u6548\u7684\u53ef\u66ff\u4ee3\u6027OER\u50ac\u5316\u5242\uff0c\u4f8b\u5982\u8fc7\u6e21\u91d1\u5c5e\/\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u9499\u949b\u77ff\uff0c\u5c42\u72b6\u6c22\u6c27\u5316\u7269\u4ee5\u53ca\u78b3\u57fa\u6750\u6599\u3002\u5c3d\u7ba1\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u6b65\uff0c\u4f46\u662f\u91d1\u5c5e\u57faOER\u50ac\u5316\u5242\u901a\u5e38\u662f\u4f4e\u7535\u5bfc\u7387\u4ee5\u53ca\u9700\u8981\u590d\u6742\u7684\u5236\u5907\u8fc7\u7a0b\u3002\u8fdb\u4e00\u6b65\uff0c\u4e3a\u4e86\u80fd\u591f\u6301\u7eed\u4ea7\u6c27\u540c\u65f6\u964d\u4f4e\u5bf9\u73af\u5883\u7684\u5f71\u54cd\uff0c\u964d\u4f4e\u91d1\u5c5e\u7684\u4f7f\u7528\u4ee5\u53ca\u63a2\u7d22\u5c11\u91cf\u6216\u8005\u6ca1\u6709\u91d1\u5c5e\u7684\u65b0\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u57fa\u4e8e\u8fd9\u4e00\u89c2\u70b9\uff0c\u975e\u91d1\u5c5e\u57fa\u78b3\u50ac\u5316\u5242\uff0c\u4f8b\u5982\u78b3\u7eb3\u7c73\u7ba1\uff08CNTs\uff09\u4ee5\u53ca\u77f3\u58a8\u70ef\u56e0\u5176\u4f4e\u6210\u672c\uff0c\u9ad8\u7535\u5bfc\u7387\uff0c\u9ad8\u6d3b\u6027\uff0c\u9ad8\u7a33\u5b9a\u6027\uff0c\u5236\u5907\u7b80\u5355\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7b49\u4f18\u52bf\u5728\u7535\u89e3\u6c34\u6c27\u5316\u9886\u57df\u5f88\u6709\u6f5c\u529b\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u51ef\u65af\u897f\u50a8\u5927\u5b66\u6234\u9ece\u660e\u6559\u6388\u548c\u4e2d\u56fd\u4e2d\u5c71\u5927\u5b66\u7ae0\u81ea\u5bff\u526f\u6559\u6388\u3001\u4f59\u4e01\u5c71\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Energy & Environmental Science<\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cA general polymer-assisted strategy enables unexpected efficient metal-free oxygen-evolution catalysis on pure carbon nanotubes<\/strong>\u201d\u3002\u7814\u7a76\u4eba\u5458\u91c7\u7528\u4e86\u4e00\u79cd\u9ad8\u6548\uff0c\u7eff\u8272\u5e76\u4e14\u7b80\u5355\u7684\u65b9\u6cd5\u6765\u5236\u5907\u6750\u6599\u3002\u5728\u91c7\u7528\u5e26\u6709\u6781\u6027\u542b\u6c27\u57fa\u56e2\u7684\u7535\u5316\u5b66\u60f0\u6027\u7684\u9ad8\u5206\u5b50\u901a\u8fc7\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5305\u88f9\u7eafCNTs\u540e\uff0c\u5f97\u5230\u4e00\u7cfb\u5217\u5148\u8fdb\u975e\u91d1\u5c5e\u57fa\u5316\u5408\u7269\u819c\u50ac\u5316\u5242\uff0c\u8fd9\u4e9b\u50ac\u5316\u5242\u4ea7\u7387\u96be\u4ee5\u60f3\u8c61\uff0c\u7279\u522b\u662fOER\u7684\u9ad8\u6d3b\u6027\uff0c\u80fd\u591f\u8fbe\u5230\u5546\u4e1a\u8d35\u91d1\u5c5eRuO2<\/sub>\u50ac\u5316\u5242\u540c\u7ea7\u6c34\u5e73\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.\u5236\u5907\u6d41\u7a0b\u56fe\uff0c\u7ed3\u6784\u56fe\u50cf\uff0c\u5143\u7d20\u5206\u6790\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u57fa\u4e8e\u9ad8\u5206\u5b50@CNT\u590d\u5408\u819c\u7684\u67d4\u6027OER\u7535\u50ac\u5316\u5242\u5236\u5907\u6d41\u7a0b\u56fe\uff1b<\/p>\n

(b)\u65e0\u652f\u6491PEMAc@CNTs90\u819c\u7167\u7247\uff1b<\/p>\n

(c, d)\u7eafCNTs\u548cPEMAc@CNTs90\u7684HRTEM\u56fe;\u63d2\u56fe\u4e3a\u6837\u54c1\u6c34\u63a5\u89e6\u89d2\uff1b<\/p>\n

(e)\u539f\u59cb\u7684\u548c\u51c0\u5316\u7684CNTs\u7684\u9ad8\u5206\u8fa8XPS C1s\u56fe\u8c31\uff1b<\/p>\n

(f)\u51c0\u5316\u7684CNTs, PEMAc@CNTs80, PEMAc@CNTs90, \u4ee5\u53caPEMAc@CNTs95\u62c9\u66fc\u56fe\u8c31\u3002<\/p>\n

\u56fe2.\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)PEMAc@CNTs90, PEMAc@CNTs80, PEMAc@CNTs95, \u539f\u59cb\u7684CNTs,\u51c0\u5316\u7684CNTs, \u4ee5\u53caRuO2<\/sub>\u57281 M KOH\u6eb6\u6db2\u4e2d\u7684OER\u7684LSV\u6807\u51c6\u66f2\u7ebf\uff1b<\/p>\n

(b)\u76f8\u5e94\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b<\/p>\n

(c)\u57281M KOH\u6eb6\u6db2\u4e2d\uff0c\u591a\u79cd\u975e\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242OER\u8fc7\u7535\u4f4d\u6bd4\u8f83\uff1b<\/p>\n

(d)\u9633\u6781\u7535\u5bb9\u7535\u6d41\u4e0e\u626b\u901f\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

(e)\u91c7\u7528RRDE\u6d4b\u8bd5\u4ecePEMAc@CNTs90\u4ea7\u751f\u7684O2<\/sub>\uff1b<\/p>\n

(f)\u5728\u7535\u89e3\u8fc7\u7a0b\u4e2d\u6c27\u6c14\u4ea7\u751f\u91cf\u4e0e\u7535\u5b50\u6570\u91cf\u7684\u6bd4\u8f83\u3002<\/p>\n

\u56fe3.\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

(a)OER of PAA@CNTs90, PVA@CNTs90, PVAc@CNTs90 \u548cPEG@CNTs90 \u57281M KOH\u6eb6\u6db2\u4e2dOER\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

(b)\u5854\u83f2\u5c14\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u56fe4.\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u5728\u78b1\u6027\u4ecb\u8d28\u4e2dPEMAc\u2013CNT\u754c\u9762\u53cd\u5e94\u673a\u7406\uff1b<\/p>\n

(b)\u5728U = 0 V\u548cU = 1.23 V\u4e0bPEMAc@CNTs\u548c\u7eaf\u7684CNTs\u7684\u6807\u51c6\u81ea\u7531\u80fd\u7ea7\u56fe\uff1b<\/p>\n

(c)\u5e26\u6709\u4e2d\u95f4\u4f53\u5438\u9644\u7269\u7eafOH*\u6216OOH*\u7684CNTs\u548cPEMAc@CNTs\u7684\u6700\u4f18\u51e0\u4f55\u56fe\u5f62\uff1b<\/p>\n

(d)\u7eafCNTs\u7684OER\u7684\u5143\u7d20\u53cd\u5e94\u7684\u6807\u51c6\u81ea\u7531\u80fd\u7ea7\u56fe\uff1b<\/p>\n

(e)\u5728\u78b3\u7247\u4e0a\u5e26\u6709\u62d3\u6251\u7f3a\u9677\u7684PEMAc@CNTs\u4f5c\u4e3a\u6d3b\u5316\u4e2d\u5fc3\u7684\u6807\u51c6\u81ea\u7531\u80fd\u7ea7\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4e0d\u540c\u5148\u524d\u78b3\u57fa\u50ac\u5316\u5242\uff0c\u9ad8\u5206\u5b50\u5305\u9644CNT\u590d\u5408\u7269\u50ac\u5316\u5242\u5728\u975e\u91d1\u5c5e\u57faCNTs\u9886\u57df\u9996\u6b21\u6210\u529f\u4fc3\u8fdbOER\u6027\u80fd\u540c\u65f6\u6ca1\u6709\u4efb\u4f55\u6bc1\u574f\u6216\u8005\u7535\u8377\u4f20\u8f93\u5230\u5185\u90e8\u7684\u7eb3\u7c73\u7ba1\u7ed3\u6784\u3002\u5f15\u4eba\u6ce8\u76ee\u7684\u662f\u6700\u4f73\u7684PEMAc@CNT\u50ac\u5316\u5242\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u5c55\u73b0\u4e86\u4f4e\u7684298 mV\u7684\u8fc7\u7535\u4f4d\uff0c\u5854\u83f2\u5c14\u659c\u7387\u4e3a52 mV dec-1<\/sup>\u3002\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\u4e0e\u5b9e\u9a8c\u7814\u7a76\u53d1\u73b0OER\u6027\u80fd\u6781\u597d\u7684\u539f\u56e0\u662f\u78b3\u7eb3\u7c73\u7ba1\u4e2d\u56fa\u6709\u7684\u62d3\u6251\u7f3a\u9677\u4ee5\u53ca\u9ad8\u5206\u5b50\u94fe\u4e0a\u7684\u542b\u6c27\u5b98\u80fd\u56e2\u7684\u5171\u540c\u4f5c\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A general polymer-assisted strategy enables unexpected efficient metal-free oxygen-evolution catalysis on pure carbon nanotubes<\/a>.( Energy & Environmental Science, 2017, DOI: 10.1039\/c7ee01702b)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 OER\u5bf9\u4e8e\u8bb8\u591a\u53ef\u518d\u751f\u80fd\u6e90\u7cfb\u7edf\u662f\u4e00\u4e2a\u5173\u952e\u7684\u8fc7\u7a0b\u3002\u7136\u800c\uff0cOER\u7ecf\u5e38\u56e0\u4e3a\u9633\u6781\u4e0a\u8fdf\u6ede\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u800c\u5728\u5e94\u7528\u9886\u57df\u6401\u6d45\u3002\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u9700\u8981\u964d\u4f4e\u9633\u6781\u6c27\u5316\u53cd\u5e94\u7684\u8fc7\u7535\u4f4d\u3002\u4f20…<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-100408","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/100408"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=100408"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/100408\/revisions"}],"predecessor-version":[{"id":101554,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/100408\/revisions\/101554"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=100408"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=100408"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=100408"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}