{"id":100025,"date":"2017-09-07T14:00:05","date_gmt":"2017-09-07T06:00:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=100025"},"modified":"2017-09-06T23:00:57","modified_gmt":"2017-09-06T15:00:57","slug":"%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%ef%bc%9a%e5%85%b7%e6%9c%89%e6%a2%af%e5%ba%a6%e7%83%ad%e5%a1%91%e6%80%a7%e7%9a%84%e9%87%91%e5%b1%9e%e9%85%8d%e4%bd%8d%e8%b6%85%e5%88%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=100025","title":{"rendered":"\u6d59\u6c5f\u5927\u5b66Angew. Chem. Int. Ed.\uff1a\u5177\u6709\u68af\u5ea6\u70ed\u5851\u6027\u7684\u91d1\u5c5e\u914d\u4f4d\u8d85\u5206\u5b50\u5f62\u72b6\u8bb0\u5fc6\u805a\u5408\u7269"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u91d1\u5c5e\u914d\u4f4d\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u91d1\u5c5e\u914d\u4f4d\u8d85\u5206\u5b50\u7f51\u7edc\u7ed3\u6784\u7684\u5408\u6210\uff1b<\/p>\n

(b) \u68af\u5ea6\u7f51\u7edc\u7ed3\u6784\u7684\u7a7a\u95f4\u5206\u5e03\u3002<\/p>\n

\u56fe2 \u4e0d\u540c\u7f51\u7edc\u7ed3\u6784\u6837\u54c1\u7684\u70ed\u673a\u68b0\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u63ba\u6742Ni\u79bb\u5b50\u7684\u6837\u54c1\u5728100\u2103\u6761\u4ef6\u4e0b\u7684\u5e94\u529b\u677e\u5f1b\uff1b<\/p>\n

(b) \u63ba\u6742\u4e0d\u540c\u91d1\u5c5e\u79bb\u5b50(Ni\uff0cFe\u548cZn)\u7684\u6837\u54c1\u572890\u2103\u4e0b\u7684\u5e94\u529b\u677e\u5f1b\uff1b<\/p>\n

c-f CP2-Ni\u6837\u54c1\u7684\u6d4b\u8bd5\u66f2\u7ebf\uff0c\u5305\u62ec\uff1a<\/p>\n

(c) \u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5e94\u529b\u677e\u5f1b\uff1b<\/p>\n

(d) \u6d4b\u8bd5\u5f97\u5230\u7684Arrhenius\u66f2\u7ebf\uff1b<\/p>\n

(e) \u5f62\u72b6\u8bb0\u5fc6\u5faa\u73af\u66f2\u7ebf\uff1b<\/p>\n

(f) \u5851\u6027\u548c\u5f39\u6027\u76f8\u7ed3\u5408\u7684\u5faa\u73af\u66f2\u7ebf\u3002<\/p>\n

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\"\"<\/p>\n

(a) \u68af\u5ea6\u5f62\u72b6\u8bb0\u5fc6\u805a\u5408\u7269\u7684\u5f62\u6210\u8fc7\u7a0b\uff1b<\/p>\n

(b) \u91d1\u5c5e\u79bb\u5b50\u7684\u68af\u5ea6\u5206\u5e03\u548c\u5176\u5728100\u2103\u4e0b\u7684\u5e94\u529b\u677e\u5f1b\u884c\u4e3a\uff1b<\/p>\n

(c) \u7531\u5f39\u6027\u548c\u68af\u5ea6\u5851\u6027\u5f15\u8d77\u7684\u591a\u529f\u80fd\u5f62\u72b6\u53d8\u5316\u884c\u4e3a\u7684\u53ef\u89c6\u56fe\u7247\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong>\uff1a\u8c22\u6d9b\u6559\u6388<\/a><\/strong>\uff0c\u4ece\u4e8b\u591a\u529f\u80fd\u667a\u80fd\u9ad8\u5206\u5b50\u6750\u6599\u57fa\u7840\u53ca\u5e94\u7528\u7814\u7a76\uff0c\u5728\u5f62\u72b6\u8bb0\u5fc6\u9ad8\u5206\u5b50\u3001\u8d28\u5b50\u4ea4\u6362\u819c\u3001\u4eff\u751f\u667a\u80fd\u9ad8\u5206\u5b50\u7b49\u65b9\u5411\u53d6\u5f97\u4e86\u591a\u9879\u91cd\u8981\u7814\u7a76\u6210\u679c\u3002\u8fd1\u5e74\u6765\u4f5c\u4e3a\u901a\u8baf\u4f5c\u8005\u5728\u5305\u62ecNature\uff0cSci. Adv.\uff0cAdv. Mater.\uff0cAngew. Chem. Int. Ed.\uff0cAdv. Funct. Mater.\u7b49\u671f\u520a\u53d1\u8868\u591a\u7bc7\u5b66\u672f\u8bba\u6587\u3002\u62e5\u6709\u8d85\u8fc770\u9879\u7f8e\u56fd\uff0c\u5fb7\u56fd\uff0c\u65e5\u672c\uff0c\u4e2d\u56fd\u53ca\u4e16\u754c\u4e13\u5229\u3002\u7814\u7a76\u6210\u679c\u591a\u6b21\u88ab\u56fd\u9645\u6743\u5a01\u79d1\u5b66\u5a92\u4f53\u5e7f\u6cdb\u62a5\u9053\u3002<\/p>\n

\u8d75\u9a9e\u526f\u6559\u6388<\/strong><\/a>\uff0c\u6d59\u6c5f\u5927\u5b66\u5316\u5de5\u5b66\u9662\u526f\u6559\u6388\uff0c\u4e3b\u8981\u4ece\u4e8b\u529f\u80fd\u6027\u6c34\u51dd\u80f6\u6750\u6599\u7684\u5236\u5907\u4e0e\u5e94\u7528\uff0c\u590d\u6742\u5f62\u53d8\u9ad8\u5206\u5b50\u6750\u6599\u548c\u57fa\u4e8e\u523a\u6fc0\uff0d\u54cd\u5e94\u9ad8\u5206\u5b50\u6750\u6599\u7684\u4f20\u611f\u5668\u4e0e\u6267\u884c\u5668\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5: A Metallosupramolecular Shape-Memory Polymer with Gradient Thermal Plasticity<\/a><\/strong> (Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/ange.201706949)<\/p>\n

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\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n

<\/p>\n

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